(Butane-1,4-diyl)bis[(4-chlorobutyl)(diphenyl)stannane]

Base Information

Chemical Name:(Butane-1,4-diyl)bis[(4-chlorobutyl)(diphenyl)stannane]
CAS No.:83815-92-3
Molecular Formula:C36H44Cl2Sn2
Molecular Weight:785.071
Hs Code.:
DSSTox Substance ID:DTXSID90517394
Wikidata:Q82379371

Synonyms:83815-92-3;(Butane-1,4-diyl)bis[(4-chlorobutyl)(diphenyl)stannane];DTXSID90517394

Suppliers and Price of (Butane-1,4-diyl)bis[(4-chlorobutyl)(diphenyl)stannane]

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of (Butane-1,4-diyl)bis[(4-chlorobutyl)(diphenyl)stannane]

Chemical Property:

Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:0
Rotatable Bond Count:17
Exact Mass:784.08582
Heavy Atom Count:40
Complexity:553

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Canonical SMILES:C1=CC=C(C=C1)[Sn](CCCCCl)(CCCC[Sn](CCCCCl)(C2=CC=CC=C2)C3=CC=CC=C3)C4=CC=CC=C4

Technology Process of (Butane-1,4-diyl)bis[(4-chlorobutyl)(diphenyl)stannane]

There total 1 articles about (Butane-1,4-diyl)bis[(4-chlorobutyl)(diphenyl)stannane] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 62.0%

: 83815-91-2
1,4-bis(bromodiphenylstannyl)butane

: 86517-04-6
4-chlorobutylmagnesium bromide

: 83815-92-3
1,14-dichloro-5,5,10,10-tetraphenyl-5,10-distannatetradecane

Guidance literature:: In tetrahydrofuran; (Ar or N2); Sn compd. treated with excess of Mg compd. in THF at -10°C for 1.5 h, warmed to room temp. for 7 h; treated with satd. aq. NH4Cl, aq. phase extd. (ether), combined org. phases washed with satd. aq. NaCl, dried (MgSO4), evapd. (vac.), purified by reverse-phase chromy. (MeOH);
DOI:10.1021/om00073a039

Reference yield: 43.0%

: 83815-91-2
1,4-bis(bromodiphenylstannyl)butane

: 83815-92-3
1,14-dichloro-5,5,10,10-tetraphenyl-5,10-distannatetradecane

: 83802-01-1
1,1,6,6,11,11,16,16-octaphenyl-1,6,11,16-tetrastannaeicosane

Guidance literature:: With lithium; In tetrahydrofuran; (Ar or N2); ((C6H5)2Sn(Br)C2H4)2 added to excess Li in THF, dild. with THF, added for 2 h to THF soln. of (Cl(CH2)4Sn(C6H5)2C2H4)2 (1 molar equiv) at 0°C, warmed to room temp. for 12 h; treated with satd. aq. NH4Cl, aq. phase extd. (ether), combined org. phases washed with satd. aq. NaCl, dried (MgSO4), evapd. (vac.), purified by reverse-phase chromy. (THF/MeCN);
DOI:10.1021/om00073a039

Reference yield: 43.0%

: 83802-02-2
(C₆H₅)2Sn(Li)(CH₂)4Sn(Li)(C₆H₅)2

: 83815-92-3
1,14-dichloro-5,5,10,10-tetraphenyl-5,10-distannatetradecane

: 83802-01-1
1,1,6,6,11,11,16,16-octaphenyl-1,6,11,16-tetrastannaeicosane

Guidance literature:: In tetrahydrofuran; (N2); soln. of dilithium compd. added over 2 h to soln. of dichloro-compd. at 0°C, allowed to warm to room temp., stirred for 18 h; satd. aq. NH4Cl added at 0°C, aq. layer extd. (ether), combined ethereal solns. washed (satd. aq. NaCl), dried (MgSO4), filtered, concd., chromd., recrystd. (hexane/ether); elem. anal.;
DOI:10.1021/om00079a003