Methylenebis[iodo(diphenyl)stannane]

Base Information

Chemical Name:Methylenebis[iodo(diphenyl)stannane]
CAS No.:84634-02-6
Molecular Formula:C₂₅H₂₂I₂Sn₂
Molecular Weight:813.679
Hs Code.:
DSSTox Substance ID:DTXSID90524427
Wikidata:Q82391291

Synonyms:Methylenebis[iodo(diphenyl)stannane];84634-02-6;DTXSID90524427

Suppliers and Price of Methylenebis[iodo(diphenyl)stannane]

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of Methylenebis[iodo(diphenyl)stannane]

Chemical Property:

Boiling Point:598.3±60.0 °C(Predicted)
PSA：0.00000
LogP:-2.08530
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:0
Rotatable Bond Count:6
Exact Mass:813.78491
Heavy Atom Count:29
Complexity:407

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Canonical SMILES:C1=CC=C(C=C1)[Sn](C[Sn](C2=CC=CC=C2)(C3=CC=CC=C3)I)(C4=CC=CC=C4)I

Technology Process of Methylenebis[iodo(diphenyl)stannane]

There total 1 articles about Methylenebis[iodo(diphenyl)stannane] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 75.0%

: 7553-56-2,12190-71-5,8031-47-8
iodine

: 71828-34-7
1,1-bis(triphenylstannyl)methane

: 84634-02-6
bis(iododiphenylstannyl)methane

Guidance literature:: In methanol; benzene; dropwise addn. of iodine in methanol to a soln. of bis(triphenylstannyl)methane in benzene/methanol; stirring, 2d;; evapn. of solvent; dissolving resulting residue in ether; treatment with hexane, cooling, -40°C; sepn.; elem. anal.;;
DOI:10.1016/0022-328X(84)80544-6

Reference yield: 99.0%

: 84634-02-6
bis(iododiphenylstannyl)methane

: 63123-00-2,63123-01-3,63123-02-4,63123-03-5,63123-04-6,63123-05-7,63123-09-1,67533-11-3,98330-04-2
Tetraethylammonium fluoride dihydrate

: (C₂H₅)4N⁽¹⁺⁾*Sn₂(CH₂)I₂(F)(C₆H₅)4^(1-)=[(C₂H₅)4N][Sn₂(CH₂)I₂F(C₆H₅)4]

Guidance literature:: In dichloromethane; stirring (refluxing, 5 min); filtering, crystn. on hexane addn. and concg.; elem. anal.;
DOI:10.1021/om00005a057

Reference yield: 97.0%

: 84634-02-6
bis(iododiphenylstannyl)methane

: 1310-73-2
sodium hydroxide

: 95151-58-9
bis(hydroxydiphenylstannyl)methane

Guidance literature:: In methanol; water; byproducts: NaI; aq. soln. NaOH was added to soln. Ph2(I)Sn(CH2)Sn(I)Ph2 in MeOH and stirred for 1 h at room temp.; ppt. was filtered, washed with water and MeOH and dried overnight; elem.anal.;
DOI:10.1021/om049773c