Hydrogen peroxide;ZINC

Base Information

• Chemical Name: Hydrogen peroxide;ZINC
• CAS No.: 1314-22-3
• Deprecated CAS: 170904-51-5
• Molecular Formula: ZnO2
• Molecular Weight: 97.3888
• Hs Code.: 2817009000
• Mol file: 1314-22-3.mol

Synonyms:hydrogen peroxide;zinc;1314-22-3;Zinc peroxide, 55.0%;Zinc peroxide, 35-39%;Zinc peroxide, 50-60%;FT-0697546

Chemical Property of Hydrogen peroxide;ZINC

Chemical Property:

• Appearance/Colour: white powder
• Vapor Pressure: 24.5mmHg at 25°C
• Melting Point: 212 °C (dec.)(lit.)
• Boiling Point: 150.2 °C at 760 mmHg
• PSA: 46.12000
• Density: 1.57 g/mL at 25 °C(lit.)
• LogP: -0.24010
• Water Solubility.: Insoluble in water.
• Hydrogen Bond Donor Count: 2
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 0
• Exact Mass: 97.934621
• Heavy Atom Count: 3
• Complexity: 0

Purity/Quality:

98% min. ^*data from raw suppliers

Zinc peroxide approximately 50% ZnO2 ^*data from reagent suppliers

Safty Information:

• Pictogram(s): O
• Hazard Codes: O,N,Xi
• Statements: 9-50/53-8-36/38
• Safety Statements: 24/25-27-17-61-60-26

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: OO.[Zn]
• General Description: Zinc peroxide (ZnO2) is a crystalline inorganic compound formed under low-temperature sintering conditions (below 200 °C) via a green sol-gel photochemical synthesis method. It exhibits high purity and can transition to zinc oxide (ZnO) at higher temperatures (200–800 °C). This environmentally friendly production process minimizes energy consumption and pollution, making it industrially viable for applications requiring sustainable material synthesis.

Technology Process of Hydrogen peroxide;ZINC

There total 7 articles about Hydrogen peroxide;ZINC which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

zinc(II) chloride (7646-85-7,24359-56-6) → zinc(II) peroxide (1314-22-3)

Guidance literature:

With Na₂O₂ or BaO₂; product contains 50 to 60% ZnO2;;

Reference yield:

dihydrogen peroxide (7722-84-1) + zinc(II) oxide → zinc(II) peroxide (1314-22-3)

Guidance literature:

In neat (no solvent); using dry ZnO (free of water) and chemical pure H2O2;;

Reference yield:

dihydrogen peroxide (7722-84-1) + zinc(II) chloride (7646-85-7,24359-56-6) → zinc(II) peroxide (1314-22-3)

Guidance literature:

In not given; Electrolysis; ZnCl2soln. electrolyzed in presence of H2O2;;

upstream raw materials:

oxygen

ozone

dihydrogen peroxide

zinc(II) acetate dihydrate

Refernces

Nanocrystalline zinc peroxide mediated unprecedented nitrene transfer: An expeditious access to N-tosylaziridines

10.1039/c3ra43878c

This study presents a novel synthetic strategy for the synthesis of N-tosylaziridines from alkenes using nanocrystalline zinc peroxide (ZnO2) and N-tosylimidotriphenylphosphine (Ph3P]NTs) as nitrene transfer reagents. The key chemicals involved are ZnO2 as a mediator for nitrene transfer and Ph3P]NTs as a nitrene source. The reaction forms a zinc oxyaziridine intermediate when ZnO2 reacts with Ph3P]NTs, which then reacts with alkenes to generate N-tosylaziridines in high to excellent yields. The study highlights mild reaction conditions, the versatility of this approach towards a wide range of olefins, and the potential for stereospecific addition of the intermediate nitrene to alkenes. Nanocrystalline ZnO2 was synthesized via a hydrothermal method and characterized using various techniques. This study demonstrates an alternative approach to existing catalytic routes for aziridination of olefins, offering facile synthesis, mild conditions, and higher product yields.

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