3-Benzylidene-7-methylidenebicyclo[3.3.1]nonane

Base Information

Chemical Name:3-Benzylidene-7-methylidenebicyclo[3.3.1]nonane
CAS No.:85513-88-8
Molecular Formula:C17H20
Molecular Weight:224.346
Hs Code.:
DSSTox Substance ID:DTXSID20541061
Nikkaji Number:J1.420.177G

Synonyms:3-Benzylidene-7-methylidenebicyclo[3.3.1]nonane;85513-88-8;DTXSID20541061;3-methylene-7-benzylidenebicyclo[3.3.1]nonane

Suppliers and Price of 3-Benzylidene-7-methylidenebicyclo[3.3.1]nonane

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of 3-Benzylidene-7-methylidenebicyclo[3.3.1]nonane

Chemical Property:

XLogP3:4.3
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:0
Rotatable Bond Count:1
Exact Mass:224.156500638
Heavy Atom Count:17
Complexity:299

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:C=C1CC2CC(C1)CC(=CC3=CC=CC=C3)C2

Technology Process of 3-Benzylidene-7-methylidenebicyclo[3.3.1]nonane

There total 7 articles about 3-Benzylidene-7-methylidenebicyclo[3.3.1]nonane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 102516-44-9
phenyl(3-bromo-1-adamantyl)bromomethane

: 90162-34-8,90162-35-9,85513-88-8
3-methylene-7-benzylidenebicyclo<3.3.1>nonane

Guidance literature:: With zinc copper; In N,N-dimethyl-formamide; 1. stirring 30 min ; 2. reflux 1.5 min;

Reference yield:

: 21816-08-0
3-bromoadamantane-1-carboxylic acid

: 90162-34-8,90162-35-9,85513-88-8
3-methylene-7-benzylidenebicyclo<3.3.1>nonane

Guidance literature:: Multi-step reaction with 5 steps

1: SOCl₂

2: 1. CdCl₂ / 1. (C₂H₅)2O, stirring 1 h, reflux 1 h; 2. C₆H₆ reflux 3 h

3: 98 percent / LiAlH₄ / diethyl ether

4: 90 percent / 63percent aq HBr / 15 h / Heating

5: 78 percent Chromat_. / zinc-copper couple / dimethylformamide / 1. stirring 30 min ; 2. reflux 1.5 min

With lithium aluminium tetrahydride; thionyl chloride; zinc copper; hydrogen bromide; cadmium(II) chloride; In diethyl ether; N,N-dimethyl-formamide;

Reference yield:

: 39917-36-7
3-bromo-1-adamantanecarbonyl chloride

: 90162-34-8,90162-35-9,85513-88-8
3-methylene-7-benzylidenebicyclo<3.3.1>nonane

Guidance literature:: Multi-step reaction with 4 steps

1: 1. CdCl₂ / 1. (C₂H₅)2O, stirring 1 h, reflux 1 h; 2. C₆H₆ reflux 3 h

2: 98 percent / LiAlH₄ / diethyl ether

3: 90 percent / 63percent aq HBr / 15 h / Heating

4: 78 percent Chromat_. / zinc-copper couple / dimethylformamide / 1. stirring 30 min ; 2. reflux 1.5 min

With lithium aluminium tetrahydride; zinc copper; hydrogen bromide; cadmium(II) chloride; In diethyl ether; N,N-dimethyl-formamide;