Methyl 9-oxo-9h-xanthene-1-carboxylate

Base Information

Chemical Name:Methyl 9-oxo-9h-xanthene-1-carboxylate
CAS No.:85636-86-8
Molecular Formula:C₁₅H₁₀O₄
Molecular Weight:254.242
Hs Code.:
DSSTox Substance ID:DTXSID50332868
Nikkaji Number:J970.797B
Wikidata:Q82097744
Mol file:85636-86-8.mol

Synonyms:methyl 9-oxo-9h-xanthene-1-carboxylate;85636-86-8;9-oxo-9H-Xanthene-1-carboxylic acid methyl ester;methyl 9-oxoxanthene-1-carboxylate;Methyl 9-oxoxanthenecarboxylate;SCHEMBL1321188;DTXSID50332868;AKOS015960883;AC-12522;9-oxoxanthene-1carboxylic acid methyl ester;9-oxoxanthene-1-carboxylic acid methyl ester

Suppliers and Price of Methyl 9-oxo-9h-xanthene-1-carboxylate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

American Custom Chemicals Corporation
9-OXO-9H-XANTHENE-1-CARBOXYLIC ACID METHYL ESTER 95.00%
1G
$ 945.95

Total 7 raw suppliers

Chemical Property of Methyl 9-oxo-9h-xanthene-1-carboxylate

Chemical Property:

Vapor Pressure:3.43E-07mmHg at 25°C
Boiling Point:417.9oC at 760 mmHg
Flash Point:188oC
PSA：56.51000
Density:1.327g/cm3
LogP:2.73280
XLogP3:2.8
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:4
Rotatable Bond Count:2
Exact Mass:254.05790880
Heavy Atom Count:19
Complexity:378

Purity/Quality:

99% ^*data from raw suppliers

9-OXO-9H-XANTHENE-1-CARBOXYLIC ACID METHYL ESTER 95.00% ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:COC(=O)C1=C2C(=CC=C1)OC3=CC=CC=C3C2=O

Technology Process of Methyl 9-oxo-9h-xanthene-1-carboxylate

There total 6 articles about Methyl 9-oxo-9h-xanthene-1-carboxylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.0%

: 85636-85-7
9-oxo-xanthene-1-carboxylic acid

: 80-11-5
N-methyl-N-nitrosotoluene-p-sulfonamide

: 85636-86-8
methyl 9-oxo-9H-xanthene-1-carboxylate

Guidance literature:: With potassium hydroxide; In ethanol; dichloromethane; at 0 ℃;
DOI:10.1002/(SICI)1521-4184(199805)331:5<177::AID-ARDP177>3.0.CO;2-K

Reference yield: 46.0%

: 1-(methoxycarbonyl)-10H-dibenzo[b,e]iodinin-5-ium trifluoromethanesulfonate

: 85636-86-8
methyl 9-oxo-9H-xanthene-1-carboxylate

Guidance literature:: With 2,2,6,6-Tetramethyl-1-piperidinyloxy free radical; water; copper diacetate; sodium carbonate; In N,N-dimethyl-formamide; at 100 ℃; for 12h; Inert atmosphere; Sealed tube;
DOI:10.1002/ejoc.201900745

Reference yield:

: 74302-25-3
2-(3-carboxyphenoxy)benzoic acid

: 85636-86-8
methyl 9-oxo-9H-xanthene-1-carboxylate

Guidance literature:: Multi-step reaction with 2 steps

1: 65 percent / polyphosphoric acid / 4 h / 180 - 200 °C

2: 91 percent / aq. KOH / CH₂Cl₂; ethanol / 0 °C

With potassium hydroxide; PPA; In ethanol; dichloromethane;
DOI:10.1002/(SICI)1521-4184(199805)331:5<177::AID-ARDP177>3.0.CO;2-K