6a-Phenyl-1,1a,6,6a-tetrahydrocyclopropa[a]indene

Base Information

• Chemical Name: 6a-Phenyl-1,1a,6,6a-tetrahydrocyclopropa[a]indene
• CAS No.: 85803-91-4
• Molecular Formula: C₁₆H₁₄
• Molecular Weight: 206.287
• DSSTox Substance ID: DTXSID50519415
• Mol file: 85803-91-4.mol

Synonyms:85803-91-4;6a-Phenyl-1,1a,6,6a-tetrahydrocyclopropa[a]indene;DTXSID50519415

Chemical Property of 6a-Phenyl-1,1a,6,6a-tetrahydrocyclopropa[a]indene

Chemical Property:

• XLogP3: 4.1
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 1
• Exact Mass: 206.109550447
• Heavy Atom Count: 16
• Complexity: 276

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

• Canonical SMILES: C1C2C1(CC3=CC=CC=C23)C4=CC=CC=C4

Technology Process of 6a-Phenyl-1,1a,6,6a-tetrahydrocyclopropa[a]indene

There total 1 articles about 6a-Phenyl-1,1a,6,6a-tetrahydrocyclopropa[a]indene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 28.0%

diiodomethane (75-11-6) + 2-phenylindene (4505-48-0) → 5-phenylbenzobicyclo<3.1.0>hex-2-ene (85803-91-4)

Guidance literature:

With copper(l) chloride; zinc; In diethyl ether; Heating;

DOI:10.1021/jo00161a014

Reference yield: 44.0%

5-phenylbenzobicyclo<3.1.0>hex-2-ene (85803-91-4) → 2-benzylideneindan (23114-34-3) + 3-phenyl-1,2-dihydronaphthalene (20669-52-7) + and 2-phenyl-1,4-dihydronaphthalene (40650-73-5)

Guidance literature:

In hexane; for 4h; Irradiation;

DOI:10.1021/jo00161a014

Reference yield:

5-phenylbenzobicyclo<3.1.0>hex-2-ene (85803-91-4) → 2-benzylideneindan (23114-34-3)

Guidance literature:

Multi-step reaction with 2 steps

1: hexane / Irradiation

2: 81 percent / hexane / 1 h / Irradiation

In hexane;

DOI:10.1021/jo00161a014

upstream raw materials:

diiodomethane

2-phenylindene

Downstream raw materials:

2-benzylideneindan

3-phenyl-1,2-dihydronaphthalene

and 2-phenyl-1,4-dihydronaphthalene

2-phenyl-1,2-dihydronaphthalene