2-PHENYLINDENE

Base Information

• Chemical Name: 2-PHENYLINDENE
• CAS No.: 4505-48-0
• Molecular Formula: C15H12
• Molecular Weight: 192.26
• Hs Code.: 2902909090
• Mol file: 4505-48-0.mol

Synonyms:Indene,2-phenyl- (7CI,8CI);2-Phenyl-1H-indene;2-Phenylindene;NSC 601810;

Chemical Property of 2-PHENYLINDENE

Chemical Property:

• Vapor Pressure: 0.0025mmHg at 25°C
• Melting Point: 157-161 °C(lit.)
• Refractive Index: 1.637
• Boiling Point: 296.7 °C at 760 mmHg
• Flash Point: 135.5 °C
• PSA: 0.00000
• Density: 1.104 g/cm³
• LogP: 3.78330
• Storage Temp.: under inert gas (nitrogen or Argon) at 2-8°C

Purity/Quality:

98%,99%, ^*data from raw suppliers

2-Phenylindene 97% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 2-PHENYLINDENE

There total 102 articles about 2-PHENYLINDENE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

bromobenzene (108-86-1,52753-63-6) + 1-indene (95-13-6) → 2-phenylindene (4505-48-0)

Guidance literature:

With triethylamine; bis(tri-o-tolylphosphine)dichloropalladium; In N,N-dimethyl-formamide; at 100 ℃; for 6h;

DOI:10.1039/b703437g

Reference yield: 89.0%

2-bromoindene (10485-09-3) + phenylboronic acid (98-80-6) → 2-phenylindene (4505-48-0)

Guidance literature:

With palladium diacetate; caesium carbonate; tris-(o-tolyl)phosphine; In water; toluene; at 100 ℃; for 20h; Inert atmosphere;

DOI:10.1002/anie.202000943

Reference yield: 89.0%

C12H5F5I(1+)*C7H7O3S(1-) + 1-indene (95-13-6) → 2-phenylindene (4505-48-0)

Guidance literature:

With palladium diacetate; potassium carbonate; In N,N-dimethyl-formamide; at 60 - 80 ℃; Inert atmosphere;

upstream raw materials:

2-hydroxy-2-phenylindan

2-phenyl-indan-1-one

2,2-diphenyl-1,3-propanediol

2-indanone

Downstream raw materials:

2-Phenyl-3-<3-dimethylamino-propyl>-inden

2,3-diphenyl-1H-indene

1,2,3-triphenylindene

1,1,2-triphenyl-1H-indene

Refernces

• 1、 Akhmetov, Vladimir,Amsharov, Konstantin,Feofanov, Mikhail,Sharapa, Dmitry I.. "Alumina-Mediated π-Activation of Alkynes". supporting information. p. 15420 - 15426. Retrieved 2021/09/30.
• 2、 Echavarren, Antonio M.,Mato, Mauro,Montesinos-Magraner, Marc,Sugranyes, Arnau R.. "Rh(II)-Catalyzed Alkynylcyclopropanation of Alkenes by Decarbenation of Alkynylcycloheptatrienes". supporting information. p. 10760 - 10769. Retrieved 2021/07/28.