1,4-Dithiaspiro[4.4]non-6-ene-6-methanol, 8-(benzoyloxy)-, (R)-

Base Information

Chemical Name:1,4-Dithiaspiro[4.4]non-6-ene-6-methanol, 8-(benzoyloxy)-, (R)-
CAS No.:86531-74-0
Molecular Formula:C15H16O3S2
Molecular Weight:308.422
Hs Code.:
DSSTox Substance ID:DTXSID40451895
Wikidata:Q82272185

Synonyms:1,4-Dithiaspiro[4.4]non-6-ene-6-methanol, 8-(benzoyloxy)-, (R)-;86531-74-0;DTXSID40451895

Suppliers and Price of 1,4-Dithiaspiro[4.4]non-6-ene-6-methanol, 8-(benzoyloxy)-, (R)-

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

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Chemical Property of 1,4-Dithiaspiro[4.4]non-6-ene-6-methanol, 8-(benzoyloxy)-, (R)-

Chemical Property:

XLogP3:2.1
Hydrogen Bond Donor Count:1
Hydrogen Bond Acceptor Count:5
Rotatable Bond Count:4
Exact Mass:308.05408672
Heavy Atom Count:20
Complexity:396

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:C1CSC2(S1)CC(C=C2CO)OC(=O)C3=CC=CC=C3
Isomeric SMILES:C1CSC2(S1)C[C@H](C=C2CO)OC(=O)C3=CC=CC=C3

Technology Process of 1,4-Dithiaspiro[4.4]non-6-ene-6-methanol, 8-(benzoyloxy)-, (R)-

There total 2 articles about 1,4-Dithiaspiro[4.4]non-6-ene-6-methanol, 8-(benzoyloxy)-, (R)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 77003-56-6
(2R)-2-benzoyloxy-4-oxo-1,6-hexanedial 4-ethylene dithioacetal

: 86531-74-0
(8R)-8-benzoyloxy-6-hydroxymethyl-1,4-dithiaspiro<4.4>non-6-ene

Guidance literature:: Multi-step reaction with 2 steps

1: pyrrolidine acetate

2: 95 percent / NaBH₄ / ethanol / 2 h / 25 °C

With sodium tetrahydroborate; pyrrolidine acetic acid; In ethanol;
DOI:10.1016/S0040-4039(00)76724-4

Reference yield:

: 77003-55-5,77058-19-6
(7R,8R,9R)-9-benzoyloxy-7,8-dihydroxy-1,4-dithiaspiro<4.5>decane

: 86531-74-0
(8R)-8-benzoyloxy-6-hydroxymethyl-1,4-dithiaspiro<4.4>non-6-ene

Guidance literature:: Multi-step reaction with 2 steps

1: 1. lead(IV) acetate 2. pyrrolidinium acetate / 1. dichloromethane 2. benzene

2: sodium cyanoborohydride / acetic acid

With lead(IV) acetate; sodium cyanoborohydride; pyrrolidine acetic acid; In acetic acid;
DOI:10.1016/S0040-4039(00)81578-6