iron (II) meso-tetra(alpha,alpha,alpha,alpha-o-pivalamidophenyl)porphyrin

Base Information

• Chemical Name: iron (II) meso-tetra(alpha,alpha,alpha,alpha-o-pivalamidophenyl)porphyrin
• CAS No.: 52629-13-7
• Molecular Formula: C₆₄H₆₄FeN₈O₄
• Molecular Weight: 1065.11
• Mol file: 52629-13-7.mol

Synonyms:Iron,[[N,N',N'',N'''-(21H,23H-porphine-5,10,15,20-tetrayltetra-2,1-phenylene)tetrakis[2,2-dimethylpropanamidato]](2-)-N21,N22,N23,N24]-,(SP-4-1)-; Propanamide,N,N',N'',N'''-(21H,23H-porphine-5,10,15,20-tetrayltetra-2,1-phenylene)tetrakis[2,2-dimethyl-,iron complex

Chemical Property of iron (II) meso-tetra(alpha,alpha,alpha,alpha-o-pivalamidophenyl)porphyrin

Chemical Property:

• Boiling Point: °Cat760mmHg
• Flash Point: °C
• PSA: 192.32000
• Density: g/cm³
• LogP: 13.14510

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of iron (II) meso-tetra(alpha,alpha,alpha,alpha-o-pivalamidophenyl)porphyrin

There total 2 articles about iron (II) meso-tetra(alpha,alpha,alpha,alpha-o-pivalamidophenyl)porphyrin which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

bromo[meso-tetra(α,α,α,α-pivalamidophenyl)porphyrin]iron(III) (52215-70-0,173936-95-3,1227639-02-2) → [(all-cis)-5,10,15,20-tetrakis-[2-(2,2-dimethylpropionamido)phenyl]porphyrinato(2-)]-iron(II) (52629-13-7,83198-46-3,126783-80-0)

Guidance literature:

With sodium dithionite; In dichloromethane; water; Fe-complex and sodium dithionite were dissolved in CH2Cl2 and H2O, the soln. was shaken; two layers were septd., CH2Cl2 soln. was washed with H2O, evapd., driedin vac. for 12 h, dissolved in CD2Cl2, detected by NMR (1)H;

DOI:10.1021/ja00386a027

Reference yield:

{(SO3CF3)(H2O)(α,α,α,α-tetrakis(o-pivalamidophenyl)porphinato)iron(III)} (124442-29-1) → tetra(α,α,α,α-orthopivalamide)phenylporphyrinatoiron(II) (52629-13-7,126783-80-0,83198-46-3)

Guidance literature:

With zinc amalgam; In chlorobenzene; (inert atm.); stirring (1 h); filtn.;

DOI:10.1021/ja963871a

Reference yield:

tetra(α,α,α,α-orthopivalamide)phenylporphyrinatoiron(II) (52629-13-7,126783-80-0,83198-46-3) + CH3(CH2)3S(1-)*K(1+)*(CH2CH2)6O6 = K(CH3(CH2)3S)*(CH2CH2)6O6 → Fe(C5H2NC6H4NHCOC(C3H9))4(C4H9S)(1-)*K(1+)*C12H24O6 = [Fe(C5H2NC6H4NHCOC(C3H9))4(C4H9S)][K(C12H24O6)]

Guidance literature:

With sodium dithionite; In toluene; (Ar); stirring (pH 8, borate buffer), drying by bubbling Ar (2 h);

upstream raw materials:

{(SO3CF3)(H2O)(α,α,α,α-tetrakis(o-pivalamidophenyl)porphinato)iron(III)}

bromo[meso-tetra(α,α,α,α-pivalamidophenyl)porphyrin]iron(III)

Downstream raw materials:

K⁽¹⁺⁾*C₁₈H₃₆N₂O₆*(C₅H₂N)4(C₆H₄NHCOC(CH₃)3)4FeNO₂^(1-) = [KC₁₈H₃₆N₂O₆][C₆₄H₆₄N₈O₄FeNO₂]

Fe(((CH₃)3CC(O)NH(C₆H₄))4C₂₀H₉N₄)^(1-)

bis(N-methylimidazole)[(all-cis)-5,10,15,20-tetrakis-[2-(2,2-dimethylpropionamido)phenyl]porphyrinato^(2-)]-iron(II)

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