Silane, (1,3-dioxan-2-ylethynyl)trimethyl-

Base Information

Chemical Name:Silane, (1,3-dioxan-2-ylethynyl)trimethyl-
CAS No.:86934-41-0
Molecular Formula:C9H16O2Si
Molecular Weight:184.31
Hs Code.:
DSSTox Substance ID:DTXSID30447621
Nikkaji Number:J1.242.236I

Synonyms:86934-41-0;Silane, (1,3-dioxan-2-ylethynyl)trimethyl-;DTXSID30447621;2-[(Trimethylsilyl)ethynyl]-1,3-dioxane

Suppliers and Price of Silane, (1,3-dioxan-2-ylethynyl)trimethyl-

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
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price

Total 1 raw suppliers

Chemical Property of Silane, (1,3-dioxan-2-ylethynyl)trimethyl-

Chemical Property:

Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:2
Rotatable Bond Count:1
Exact Mass:184.091956283
Heavy Atom Count:12
Complexity:200

Purity/Quality:: 99% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:C[Si](C)(C)C#CC1OCCCO1

Technology Process of Silane, (1,3-dioxan-2-ylethynyl)trimethyl-

There total 2 articles about Silane, (1,3-dioxan-2-ylethynyl)trimethyl- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 81.0%

: 2975-46-4
3-(trimethylsilyl)prop-2-yn-1-al

: 504-63-2
trimethyleneglycol

: 86934-41-0
2-(trimethylsilylethynyl)-1,3-dioxane

Guidance literature:: With toluene-4-sulfonic acid; In benzene; Heating;
DOI:10.1016/S0040-4020(01)91548-0

Reference yield:

: 1066-54-2
trimethylsilylacetylene

: 86934-41-0
2-(trimethylsilylethynyl)-1,3-dioxane

Guidance literature:: Multi-step reaction with 2 steps

1: 1.) THF, EtMgBr, RT, 1 h; 2.) diethyl ether, -25 deg C for 45 min then 1 h at RT then 15 min at 30 deg C

2: 81 percent / p-toluenesulfonic acid / benzene / Heating

With toluene-4-sulfonic acid; In benzene;
DOI:10.1016/S0040-4020(01)91548-0

Reference yield:

: 86934-41-0
2-(trimethylsilylethynyl)-1,3-dioxane

: 5930-98-3
4-trimethylsilyl-3-butyn-2-one

Guidance literature:: Multi-step reaction with 2 steps

1: 1.) BuLi / 1.) THF, -65 deg C, 30 min; 2.) THF, overnight, -65 deg C to 25 deg C

2: 63 percent / H₂SO₄ / acetone; H₂O / 5 h / Heating

With n-butyllithium; sulfuric acid; In water; acetone;
DOI:10.1016/S0040-4020(01)91548-0