1-{[tert-Butyl(dimethyl)silyl]oxy}cyclohexane-1-peroxol

Base Information

Chemical Name:1-{[tert-Butyl(dimethyl)silyl]oxy}cyclohexane-1-peroxol
CAS No.:87258-08-0
Molecular Formula:C12H26O3Si
Molecular Weight:246.422
Hs Code.:
DSSTox Substance ID:DTXSID50517799
Wikidata:Q82379985

Synonyms:87258-08-0;1-{[tert-Butyl(dimethyl)silyl]oxy}cyclohexane-1-peroxol;DTXSID50517799

Suppliers and Price of 1-{[tert-Butyl(dimethyl)silyl]oxy}cyclohexane-1-peroxol

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of 1-{[tert-Butyl(dimethyl)silyl]oxy}cyclohexane-1-peroxol

Chemical Property:

Hydrogen Bond Donor Count:1
Hydrogen Bond Acceptor Count:3
Rotatable Bond Count:4
Exact Mass:246.16512122
Heavy Atom Count:16
Complexity:227

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CC(C)(C)[Si](C)(C)OC1(CCCCC1)OO

Technology Process of 1-{[tert-Butyl(dimethyl)silyl]oxy}cyclohexane-1-peroxol

There total 3 articles about 1-{[tert-Butyl(dimethyl)silyl]oxy}cyclohexane-1-peroxol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 88.0%

: 62791-22-4
tert-butyl(cyclohex-1-en-1-yloxy)dimethylsilane

: 87258-08-0
1-(tert-Butyl-dimethyl-silanyloxy)-cyclohexyl-hydroperoxide

Guidance literature:: With dihydrogen peroxide; trifluoroacetic acid; In diethyl ether; for 3h; Ambient temperature;
DOI:10.1016/S0040-4039(00)81758-X

Reference yield:

: 108-94-1,11119-77-0,9003-41-2,9075-99-4
cyclohexanone

: 87258-08-0
1-(tert-Butyl-dimethyl-silanyloxy)-cyclohexyl-hydroperoxide

Guidance literature:: Multi-step reaction with 2 steps

1: LDA / tetrahydrofuran; hexamethylphosphoric acid triamide

2: 88 percent / H₂O₂, trifluoroacetic acid / diethyl ether / 3 h / Ambient temperature

With dihydrogen peroxide; trifluoroacetic acid; lithium diisopropyl amide; In tetrahydrofuran; N,N,N,N,N,N-hexamethylphosphoric triamide; diethyl ether;
DOI:10.1016/S0040-4039(00)81758-X

Reference yield:

: 18162-48-6
tert-butyldimethylsilyl chloride

: 87258-08-0
1-(tert-Butyl-dimethyl-silanyloxy)-cyclohexyl-hydroperoxide

Guidance literature:: Multi-step reaction with 2 steps

1: LDA / tetrahydrofuran; hexamethylphosphoric acid triamide

2: 88 percent / H₂O₂, trifluoroacetic acid / diethyl ether / 3 h / Ambient temperature

With dihydrogen peroxide; trifluoroacetic acid; lithium diisopropyl amide; In tetrahydrofuran; N,N,N,N,N,N-hexamethylphosphoric triamide; diethyl ether;
DOI:10.1016/S0040-4039(00)81758-X