Silane, [[(1R,2S)-4,4-dibromo-1-[[(4-methoxyphenyl)methoxy]methyl]-2-methyl- 3-butenyl]oxy]triethyl-

Base Information

Chemical Name:Silane, [[(1R,2S)-4,4-dibromo-1-[[(4-methoxyphenyl)methoxy]methyl]-2-methyl- 3-butenyl]oxy]triethyl-
CAS No.:872591-85-0
Molecular Formula:C20H32Br2O3Si
Molecular Weight:508.366
Hs Code.:

Synonyms:

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Chemical Property of Silane, [[(1R,2S)-4,4-dibromo-1-[[(4-methoxyphenyl)methoxy]methyl]-2-methyl- 3-butenyl]oxy]triethyl-

Chemical Property:

Purity/Quality:

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Technology Process of Silane, [[(1R,2S)-4,4-dibromo-1-[[(4-methoxyphenyl)methoxy]methyl]-2-methyl- 3-butenyl]oxy]triethyl-

There total 14 articles about Silane, [[(1R,2S)-4,4-dibromo-1-[[(4-methoxyphenyl)methoxy]methyl]-2-methyl- 3-butenyl]oxy]triethyl- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 109786-74-5,109786-77-8,13807-95-9
(±)-3-(4-methoxybenzyloxy)propane-1,2-diol

: 872591-85-0
[(1R,2S)-4,4-Dibromo-1-(4-methoxy-benzyloxymethyl)-2-methyl-but-3-enyloxy]-triethyl-silane

Guidance literature:: Multi-step reaction with 12 steps

1: Pb(OAc)4 / toluene / 3 h / 20 °C

2: tetrahydrofuran / 24 h / 20 °C

3: 92 percent / DIBAH / diethyl ether / 0.25 h / 20 °C

4: 84 percent / TBHP; (+)-DET; MS 4 Angstroem / Ti(O-iPr)4 / CH₂Cl₂ / 24 h / -25 °C

5: (COCl)2; DMSO; triethylamine / CH₂Cl₂ / 1 h / -78 °C

6: benzene / 1 h / 20 °C

7: 96 percent / n-Bu₃P; HCO₂H; triethylamine / Pd₂(dba)3*CHCl₃ / dioxane / 5 h / 20 °C

8: 100 percent / imidazole / dimethylformamide / 4 h / 20 °C

9: NMO; OsO₄ / acetone; H₂O / 144 h / 20 °C

10: Pb(OAc)4 / toluene / 3 h / 20 °C

11: Ph₃P; triethylamine / CH₂Cl₂ / 24 h / 0 °C

12: imidazole / dimethylformamide / 24 h / 20 °C

With 1H-imidazole; lead(IV) acetate; tert.-butylhydroperoxide; osmium(VIII) oxide; formic acid; N-methyl-2-indolinone; oxalyl dichloride; diethyl (2R,3R)-tartrate; tributylphosphine; MS 4 Angstroem; diisobutylaluminium hydride; dimethyl sulfoxide; triethylamine; triphenylphosphine; titanium(IV) isopropylate; tris(dibenzylideneacetone)dipalladium⁽⁰⁾ chloroform complex; In tetrahydrofuran; 1,4-dioxane; diethyl ether; dichloromethane; water; N,N-dimethyl-formamide; acetone; toluene; benzene;
DOI:10.1021/ol052039k

Reference yield:

: 14289-62-4
1-(allyloxymethyl)-4-methoxybenzene

: 872591-85-0
[(1R,2S)-4,4-Dibromo-1-(4-methoxy-benzyloxymethyl)-2-methyl-but-3-enyloxy]-triethyl-silane

Guidance literature:: Multi-step reaction with 13 steps

1: OsO₄; NMO / acetone; H₂O; 2-methyl-propan-2-ol / 72 h / 20 °C

2: Pb(OAc)4 / toluene / 3 h / 20 °C

3: tetrahydrofuran / 24 h / 20 °C

4: 92 percent / DIBAH / diethyl ether / 0.25 h / 20 °C

5: 84 percent / TBHP; (+)-DET; MS 4 Angstroem / Ti(O-iPr)4 / CH₂Cl₂ / 24 h / -25 °C

6: (COCl)2; DMSO; triethylamine / CH₂Cl₂ / 1 h / -78 °C

7: benzene / 1 h / 20 °C

8: 96 percent / n-Bu₃P; HCO₂H; triethylamine / Pd₂(dba)3*CHCl₃ / dioxane / 5 h / 20 °C

9: 100 percent / imidazole / dimethylformamide / 4 h / 20 °C

10: NMO; OsO₄ / acetone; H₂O / 144 h / 20 °C

11: Pb(OAc)4 / toluene / 3 h / 20 °C

12: Ph₃P; triethylamine / CH₂Cl₂ / 24 h / 0 °C

13: imidazole / dimethylformamide / 24 h / 20 °C

With 1H-imidazole; lead(IV) acetate; tert.-butylhydroperoxide; osmium(VIII) oxide; formic acid; N-methyl-2-indolinone; oxalyl dichloride; diethyl (2R,3R)-tartrate; tributylphosphine; MS 4 Angstroem; diisobutylaluminium hydride; dimethyl sulfoxide; triethylamine; triphenylphosphine; titanium(IV) isopropylate; tris(dibenzylideneacetone)dipalladium⁽⁰⁾ chloroform complex; In tetrahydrofuran; 1,4-dioxane; diethyl ether; dichloromethane; water; N,N-dimethyl-formamide; acetone; toluene; tert-butyl alcohol; benzene;
DOI:10.1021/ol052039k

Reference yield:

: 121289-23-4
p-methoxybenzyloxyacetaldehyde

: 872591-85-0
[(1R,2S)-4,4-Dibromo-1-(4-methoxy-benzyloxymethyl)-2-methyl-but-3-enyloxy]-triethyl-silane

Guidance literature:: Multi-step reaction with 11 steps

1: tetrahydrofuran / 24 h / 20 °C

2: 92 percent / DIBAH / diethyl ether / 0.25 h / 20 °C

3: 84 percent / TBHP; (+)-DET; MS 4 Angstroem / Ti(O-iPr)4 / CH₂Cl₂ / 24 h / -25 °C

4: (COCl)2; DMSO; triethylamine / CH₂Cl₂ / 1 h / -78 °C

5: benzene / 1 h / 20 °C

6: 96 percent / n-Bu₃P; HCO₂H; triethylamine / Pd₂(dba)3*CHCl₃ / dioxane / 5 h / 20 °C

7: 100 percent / imidazole / dimethylformamide / 4 h / 20 °C

8: NMO; OsO₄ / acetone; H₂O / 144 h / 20 °C

9: Pb(OAc)4 / toluene / 3 h / 20 °C

10: Ph₃P; triethylamine / CH₂Cl₂ / 24 h / 0 °C

11: imidazole / dimethylformamide / 24 h / 20 °C

With 1H-imidazole; lead(IV) acetate; tert.-butylhydroperoxide; osmium(VIII) oxide; formic acid; N-methyl-2-indolinone; oxalyl dichloride; diethyl (2R,3R)-tartrate; tributylphosphine; MS 4 Angstroem; diisobutylaluminium hydride; dimethyl sulfoxide; triethylamine; triphenylphosphine; titanium(IV) isopropylate; tris(dibenzylideneacetone)dipalladium⁽⁰⁾ chloroform complex; In tetrahydrofuran; 1,4-dioxane; diethyl ether; dichloromethane; water; N,N-dimethyl-formamide; acetone; toluene; benzene;
DOI:10.1021/ol052039k