Chlorotriethylsilane

Base Information

• Chemical Name: Chlorotriethylsilane
• CAS No.: 994-30-9
• Molecular Formula: C6H15ClSi
• Molecular Weight: 150.724
• Hs Code.: 29310095
• European Community (EC) Number: 213-615-6
• UNII: Q1A687M1PY
• DSSTox Substance ID: DTXSID6061361
• Nikkaji Number: J47.877F
• Wikidata: Q20054508
• Mol file: 994-30-9.mol

Synonyms:CHLOROTRIETHYLSILANE;994-30-9;Triethylchlorosilane;Silane, chlorotriethyl-;chloro(triethyl)silane;Triethylsilyl Chloride;Et3SiCl;TESCl;chloro-triethyl-silane;UNII-Q1A687M1PY;Q1A687M1PY;EINECS 213-615-6;triethyl silyl chloride;MFCD00000507;triethychlorosilane;Chlorotrietylsilane;ClSiEt3;triethylsilylchloride;chloro triethylsilane;chlorotriethyl silane;chlorotriethyl-silane;triethyl chlorosilane;triethyl-chlorosilane;Triethylchloro-silane;Triethysilyl Chloride;chloranyl(triethyl)silane;Chlorotriethylsilane, 99%;SCHEMBL25704;DTXSID6061361;CHLOROTRIETHYLSILANE [MI];AMY42238;CT2520;AKOS006220949;BP-20176;FT-0623700;T0589;EN300-82376;H10691;A846019;J-520040;Q20054508;Chlorotriethylsilane, for GC derivatization, >=97.0% (GC);Chlorotriethylsilane, produced by Wacker Chemie AG, Burghausen, Germany, >=99.0%

Chemical Property of Chlorotriethylsilane

Chemical Property:

• Appearance/Colour: Clear transparent liquid
• Vapor Pressure: 6.39mmHg at 25°C
• Melting Point: -50 °C
• Refractive Index: n20/D 1.43(lit.)
• Boiling Point: 144.5 °C at 760 mmHg
• Flash Point: 29.4 °C
• PSA: 0.00000
• Density: 0.862 g/cm³
• LogP: 3.23040
• Storage Temp.: Flammables area
• Sensitive.: Moisture Sensitive
• Solubility.: Soluble in aprotic organic solvents.
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 3
• Exact Mass: 150.0631547
• Heavy Atom Count: 8
• Complexity: 51.3

Purity/Quality:

99% ^*data from raw suppliers

TESC ^*data from reagent suppliers

Safty Information:

• Pictogram(s): C,F
• Hazard Codes: C,F
• Statements: 11-14-19-35-34-10-22-36/37-40-37
• Safety Statements: 26-36/37/39-43-45-25-16-33

MSDS Files:

SDS file from LookChem

Useful:

• Chemical Classes: Toxic Gases & Vapors -> Chlorosilanes
• Canonical SMILES: CC[Si](CC)(CC)Cl
• Uses: Chlorotriethylsilane is used in the preparation of potent silylating agent and lewis acid catalyst. Chlorotriethylsilane derivatived ethers have been shown to be more stable towards hydrolysis than ar e trimethyl ethers. Chlorotriethylsilane is used in laboratory chemicals. It is used for preparing silylating agent and acts as a catalyst for lewis acid. It is used for executing chemical reactions for silicon oil, silicon resin and polysiloxane. It is also used for eradicating robe agent, and used as protective agent and leather surface treating agent. Chlorotriethylsilane may be used as a derivatizing reagent for the determination of fluoride, in toothpaste samples using headspace solid-phase microextraction and gas chromatography–flame ionization detection.

Technology Process of Chlorotriethylsilane

There total 115 articles about Chlorotriethylsilane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

triethylsilane (617-86-7) + vanadium(V) oxychloride (7727-18-6) → vanadyl(IV) chloride + vanadium(III) oxide chloride + triethylsilyl chloride (994-30-9) + hydrogen (1333-74-0)

Guidance literature:

DOI:10.1021/ja01552a022

Reference yield: 74.0%

ruthenium(II) chloride + triethylsilane (617-86-7) → triethylsilyl chloride (994-30-9) + hydrogen (1333-74-0) + ruthenium (7440-18-8)

Guidance literature:

In not given; react. with boiling (C2H5)3SiH after 12 min;;

DOI:10.1021/ja01552a022

Reference yield: 60.0%

triethylsilane (617-86-7) + benzoyl chloride (98-88-4) → triethylsilyl chloride (994-30-9) + triethylsilyl benzoate (1018-20-8) + benzoic acid benzyl ester (120-51-4) + benzaldehyde (100-52-7) + benzoic acid (65-85-0,8013-63-6)

Guidance literature:

iron(III)-acetylacetonate; at 20 ℃; for 0.5h; Product distribution; other catalysts, other substrates;

upstream raw materials:

triethylsilane

1-Chlorohexane

dichloromethylpropylsilane

ethyl bromide

Downstream raw materials:

trimethylsilylethane

1,1,1-triethyl-3,3,3-trimethyl-disiloxane

hexaethyl disiloxane

triethyl-(3-isopropyl-phenyl)-silane

Refernces

• 1、 Alsobrook,Collins,Wells. "The preparation of tetrakis(triethylsilylamino)diborane(4)". . p. 253 - 254. Retrieved 1965.
• 2、 Fan, Xuanzi,Xiao, Pin,Jiao, Zeqing,Yang, Tingting,Dai, Xiaojuan,Xu, Wengang,Tan, Jin Da,Cui, Ganglong,Su, Hongmei,Fang, Weihai,Wu, Jie. "Neutral-Eosin-Y-Photocatalyzed Silane Chlorination Using Dichloromethane". supporting information. p. 12580 - 12584. Retrieved 2019/08/16.
• 3、 Suzuki, Yuko,Ishida, Shintaro,Sato, Sota,Isobe, Hiroyuki,Iwamoto, Takeaki. "An Isolable Potassium Salt of a Borasilene–Chloride Adduct". supporting information. p. 4593 - 4597. Retrieved 2017/04/11.