1,3,5-Benzenetricarbonyl trichloride, 2-methoxy-

Base Information

• Chemical Name: 1,3,5-Benzenetricarbonyl trichloride, 2-methoxy-
• CAS No.: 872705-74-3
• Molecular Formula: C10H5Cl3O4
• Molecular Weight: 295.506
• Mol file: 872705-74-3.mol

Synonyms:

Chemical Property of 1,3,5-Benzenetricarbonyl trichloride, 2-methoxy-

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 1,3,5-Benzenetricarbonyl trichloride, 2-methoxy-

There total 3 articles about 1,3,5-Benzenetricarbonyl trichloride, 2-methoxy- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

1-methoxybenzene-2,4,6-tricarboxylic acid (17445-86-2) → 1-methoxy-2,4,6-benzenetricarbonyl trichloride (872705-74-3)

Guidance literature:

With thionyl chloride; N,N-dimethyl-formamide; In 1,4-dioxane; Heating / reflux;

Reference yield:

2,6-bis(hydroxymethyl)-4-methylphenol (91-04-3) → 1-methoxy-2,4,6-benzenetricarbonyl trichloride (872705-74-3)

Guidance literature:

Multi-step reaction with 3 steps

1: sodium hydroxide / water

2: potassium permanganate; sodium hydroxide / water / 20 - 90 °C

3: thionyl chloride; N,N-dimethyl-formamide / 1,4-dioxane / Reflux; Inert atmosphere

With potassium permanganate; thionyl chloride; N,N-dimethyl-formamide; sodium hydroxide; In 1,4-dioxane; water;

DOI:10.1002/anie.201106748

Reference yield:

2,6-bis(hydroxymethyl)-4-methyl-anisole (6327-85-1) → 1-methoxy-2,4,6-benzenetricarbonyl trichloride (872705-74-3)

Guidance literature:

Multi-step reaction with 2 steps

1: potassium permanganate; sodium hydroxide / water / 20 - 90 °C

2: thionyl chloride; N,N-dimethyl-formamide / 1,4-dioxane / Reflux; Inert atmosphere

With potassium permanganate; thionyl chloride; N,N-dimethyl-formamide; sodium hydroxide; In 1,4-dioxane; water;

DOI:10.1002/anie.201106748

upstream raw materials:

1-methoxybenzene-2,4,6-tricarboxylic acid

2,6-bis(hydroxymethyl)-4-methylphenol

2,6-bis(hydroxymethyl)-4-methyl-anisole

Downstream raw materials:

1-methoxy-2,4,6-tris(2-thioxo-thiazolidine-3-carbonyl)benzene

H₄H(2,2)TIAM

4-methoxy-N₁,N₃-dimethyl-5-(2-thioxothiazolidine-3-carbonyl)isophthalamide

Me₄H(2,2)TIAM