Dimethylvinylethynylhydroperoxide

Base Information

• Chemical Name: Dimethylvinylethynylhydroperoxide
• CAS No.: 14906-26-4
• Molecular Formula: C7H10 O2
• Molecular Weight: 126.155
• Hs Code.: 2909600000
• DSSTox Substance ID: DTXSID30933539
• Nikkaji Number: J794.552C
• Wikidata: Q82909359
• Mol file: 14906-26-4.mol

Synonyms:Dimethylvinylethynylhydroperoxide;14906-26-4;5-hydroperoxy-5-methylhex-1-en-3-yne;SCHEMBL21066063;DTXSID30933539;2-Methylhex-5-en-3-yne-2-peroxol

Chemical Property of Dimethylvinylethynylhydroperoxide

Chemical Property:

• Vapor Pressure: 0.0554mmHg at 25°C
• Boiling Point: 206.6°Cat760mmHg
• PKA: 11.25±0.30(Predicted)
• Flash Point: 78.8°C
• PSA: 29.46000
• Density: 0.998g/cm³
• LogP: 1.40310
• XLogP3: 1.2
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 2
• Exact Mass: 126.068079557
• Heavy Atom Count: 9
• Complexity: 156

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC(C)(C#CC=C)OO

Technology Process of Dimethylvinylethynylhydroperoxide

There total 1 articles about Dimethylvinylethynylhydroperoxide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

dimethyl(vinylethynyl)carbinol (690-94-8) → 2-methyl-2-hydroperoxy-5-hexen-3-yne (14906-26-4)

Guidance literature:

With sulfuric acid; dihydrogen peroxide;

Reference yield:

2-methyl-4-(trimethylsilyl)but-3-yn-2-ol (5272-33-3) + 2-methyl-2-hydroperoxy-5-hexen-3-yne (14906-26-4) → [3-(1,1-Dimethyl-pent-4-en-2-ynylperoxy)-3-methyl-but-1-ynyl]-trimethyl-silane

Guidance literature:

With sulfuric acid;

Reference yield:

2-methyl-2-hydroperoxy-5-hexen-3-yne (14906-26-4) + tert-butyl alcohol (75-65-0) → 2-tert-butylperoxy-2-methyl-5-hexene-3-ine (14906-32-2)

Guidance literature:

With sulfuric acid;

upstream raw materials:

dimethyl(vinylethynyl)carbinol

Downstream raw materials:

<2-Carboxy-benzoyl>-<1,1-dimethyl-penten-(4)-in-(2)-yl>peroxid

2-tert-butylperoxy-2-methyl-5-hexene-3-ine

2-methyl-2-(p-bromo-α,α-dimethylbenzylperoxy)-5-hexen-3-yne