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tert-Butanol
Cas No: 75-65-0
No Data 155 Kilogram 20000 Metric Ton/Day QINGDAO ON-BILLION INDUSTRAIL CO.,LTD Contact Supplier
tert-Butanol
Cas No: 75-65-0
No Data 1 Gram 1-1000 Metric Ton/Day Hangzhou Dayangchem Co., Ltd. Contact Supplier
tert-Butanol
Cas No: 75-65-0
No Data 1 Kilogram 500 Metric Ton/Month Kunshan Yalong Trading Co,.Ltd Contact Supplier
tert-Butanol
Cas No: 75-65-0
USD $ 1.0-2.0 / Metric Ton 1 Metric Ton 100 Metric Ton/Week Hebei yanxi chemical co.,LTD. Contact Supplier
Top purity tert-Butanol with high quality and best price cas:75-65-0
Cas No: 75-65-0
USD $ 3.0-10.0 / Kilogram 1 Kilogram 99999 Kilogram/Year Hangzhou Dingyan Chem Co., Ltd Contact Supplier
Fresh In Stock:2-Methyl-2-propanol with BEST PRICE
Cas No: 75-65-0
USD $ 1.0-1.0 / Metric Ton 1 Metric Ton 1000 Metric Ton/Day Scale Chemical Corporation Contact Supplier
Tert-Butanol 99.9%
Cas No: 75-65-0
No Data 10 Metric Ton 600 Metric Ton/Month Zibo Kunran Enterprises Co. LTD Contact Supplier
High quality Tert-Butyl Alcohol supplier in China
Cas No: 75-65-0
No Data No Data No Data Simagchem Corporation Contact Supplier
CAS NO:75-65-0 tert-Butanol
Cas No: 75-65-0
No Data 1 Kilogram 300 Kilogram/Day HENAN SUNLAKE ENTERPRISE CORPORATION Contact Supplier
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No Data 10 Gram 200 Kilogram/Month Hubei Jusheng Technology Co., Ltd., Contact Supplier

75-65-0 Usage

Air & Water Reactions

Highly flammable. Water soluble.

General Description

Colorless oily liquid with a sharp alcohol odor. Floats and mixes with water. Produces irritating vapor. Freezing point is 78°F.

Reactivity Profile

Attacks plastics. [Handling Chemicals Safely 1980. p. 236]. Acetyl bromide reacts violently with alcohols or water [Merck 11th ed. 1989]. Mixtures of alcohols with concentrated sulfuric acid and strong hydrogen peroxide can cause explosions. Example: an explosion will occur if dimethylbenzylcarbinol is added to 90% hydrogen peroxide then acidified with concentrated sulfuric acid. Mixtures of ethyl alcohol with concentrated hydrogen peroxide form powerful explosives. Mixtures of hydrogen peroxide and 1-phenylm-2-methyl propyl alcohol tend to explode if acidified with 70% sulfuric acid [Chem. Eng. News 45(43):73 1967; J, Org. Chem. 28:1893 1963]. Alkyl hypochlorites are violently explosive. They are readily obtained by reacting hypochlorous acid and alcohols either in aqueous solution or mixed aqueous-carbon tetrachloride solutions. Chlorine plus alcohols would similarly yield alkyl hypochlorites. They decompose in the cold and explode on exposure to sunlight or heat. Tertiary hypochlorites are less unstable than secondary or primary hypochlorites [NFPA 491 M 1991]. Base-catalysed reactions of isocyanates with alcohols should be carried out in inert solvents. Such reactions in the absence of solvents often occur with explosive violence [Wischmeyer 1969].

Chemical Properties

Butyl alcohol, also known as butanol, exists in three isomeric alcohols that are toxic and soluble in most organic liquids. n-butyl alcohol, CH3(CH2)2CH20H, also known as l-butanol, propyl carbinol, and prim-butyl alcohol, is a colorless liquid. It is used in manufacturing perfumes and lacquers. sec-butyl alcohol, CH3CH2CHOHCH3, also known as 2-butanol, ethyl-methyl carbinol, butylene hydrate, and 2-hydroxy butane, is a colorless liquid. It is used in the preparation of fruit essence. tert-butyl alcohol, (CH3)3COH, also known as 2-methyl 2-propanol and trimethyl carbinol, is a colorless liquid.

Uses

Denaturant for ethanol, manufacturing flotation agents, flavors, perfumes; as solvent; in paint removers. Octane booster in gasoline.

Purification Methods

It is synthesised commercially by the hydration of 2-methylpropene in dilute H2SO4. Dry it with CaO, K2CO3, CaSO4 or MgSO4, filter and fractionally distil it. Dry further by refluxing with, and distilling from, either magnesium activated with iodine, or small amounts of calcium, sodium or potassium, under nitrogen. Passage through a column of type 4A molecular sieve is another effective method of drying; as well as refluxing with tert-butyl phthalate or succinate. (For method see Ethanol.) Other methods include refluxing with excess aluminium tert-butylate, or standing with CaH2, and distilling as needed. Further purification is achieved by fractional crystallisation by partial freezing, taking care to exclude moisture. tert-Butyl alcohol samples containing much water can be dried by adding *benzene, so that the water distils off as a tertiary azeotrope, b 67.3o. Traces of isobutylene have been removed from dry tert-butyl alcohol by bubbling dry pre-purified nitrogen through for several hours at 40-50o before using. It forms azeotropic mixtures with a large number of compounds. It has also been purified by distillation from CaH2 into Linde 4A molecular sieves which had been activated at 350o for 24hours [Jaeger et al. J Am Chem Soc 101 717 1979]. [Beilstein 1 IV 1609.] Rapid purification: Dry tert-butanol over CaH2 (5% w/v), distil and store it over 3A molecular sieves.

Health Hazard

Vapor is narcotic in action and irritating to respiratory passages. Liquid is irritating to skin and eyes.
InChI:InChI=1/C4H10O/c1-4(2,3)5/h5H,1-3H3

75-65-0 Well-known Company Product Price

Brand (Code)Product description CAS number Packaging Price Detail
Sigma-Aldrich (UST154)  tert-Butanol  certified reference material, 5000 μg/mL in methanol 75-65-0 UST154-1.5ML 362.70CNY Detail
Sigma-Aldrich (50621)  tert-Butanol  analytical standard 75-65-0 50621-5ML-F 993.33CNY Detail
Sigma-Aldrich (50621)  tert-Butanol  analytical standard 75-65-0 50621-1ML-F 255.06CNY Detail
Sigma-Aldrich (308250)  tert-Butanol  for HPLC, ≥99.5% 75-65-0 308250-1L 1,139.58CNY Detail
Sigma-Aldrich (308250)  tert-Butanol  for HPLC, ≥99.5% 75-65-0 308250-100ML 635.31CNY Detail
Sigma-Aldrich (24127)  tert-Butanol  ≥99% (GC) 75-65-0 24127-1L 872.82CNY Detail
Sigma-Aldrich (B85927)  tert-Butanol  TEBOL® 99, ≥99.3% 75-65-0 B85927-20L 6,622.20CNY Detail
Sigma-Aldrich (B85927)  tert-Butanol  TEBOL® 99, ≥99.3% 75-65-0 B85927-1L 920.79CNY Detail
Sigma-Aldrich (B85927)  tert-Butanol  TEBOL® 99, ≥99.3% 75-65-0 B85927-500ML 634.14CNY Detail
Sigma-Aldrich (19460)  tert-Butanol  puriss. p.a., ACS reagent, ≥99.7% (GC) 75-65-0 19460-5L 4,216.68CNY Detail
Sigma-Aldrich (19460)  tert-Butanol  puriss. p.a., ACS reagent, ≥99.7% (GC) 75-65-0 19460-2.5L 1,990.17CNY Detail
Sigma-Aldrich (19460)  tert-Butanol  puriss. p.a., ACS reagent, ≥99.7% (GC) 75-65-0 19460-1L 1,215.63CNY Detail

75-65-0SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 16, 2017

Revision Date: Aug 16, 2017

1.Identification

1.1 GHS Product identifier

Product name tert-butanol

1.2 Other means of identification

Product number -
Other names 2-Propanol, 2-methyl-

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only. Food additives -> Flavoring Agents
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:75-65-0 SDS

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