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tert-Butanol
Cas No: 75-65-0
No Data 1 Gram 1-1000 Metric Ton/Day Dayang Chem (Hangzhou) Co.,Ltd. Contact Supplier
tert-Butanol
Cas No: 75-65-0
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tert-Butanol
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High quality Tert-Butyl Alcohol supplier in China
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Cas No: 75-65-0
USD $ 3.0-10.0 / Kilogram 1 Kilogram 99999 Kilogram/Year Hangzhou Dingyan Chem Co., Ltd Contact Supplier
tert-Butanol
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USD $ 1.0-2.0 / Metric Ton 1 Metric Ton 100 Metric Ton/Week Hebei yanxi chemical co.,LTD. Contact Supplier
Tert-Butanol 99.9%
Cas No: 75-65-0
No Data 10 Metric Ton 600 Metric Ton/Month Zibo Kunran Enterprises Co. LTD Contact Supplier
Tert-butanol / tert-butyl alcohol
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USD $ 1000.0-1500.0 / Kilogram 1 Kilogram 100 Metric Ton/Month Hebei Guanlang Biotechnology Co., Ltd. Contact Supplier
Amadis Chemical offer CAS#75-65-0;CAT#A838477
Cas No: 75-65-0
No Data 10 Milligram Amadis Chemical Co., Ltd. Contact Supplier

75-65-0 Usage

Air & Water Reactions

Highly flammable. Water soluble.

General Description

Colorless oily liquid with a sharp alcohol odor. Floats and mixes with water. Produces irritating vapor. Freezing point is 78°F.

Reactivity Profile

Attacks plastics. [Handling Chemicals Safely 1980. p. 236]. Acetyl bromide reacts violently with alcohols or water [Merck 11th ed. 1989]. Mixtures of alcohols with concentrated sulfuric acid and strong hydrogen peroxide can cause explosions. Example: an explosion will occur if dimethylbenzylcarbinol is added to 90% hydrogen peroxide then acidified with concentrated sulfuric acid. Mixtures of ethyl alcohol with concentrated hydrogen peroxide form powerful explosives. Mixtures of hydrogen peroxide and 1-phenylm-2-methyl propyl alcohol tend to explode if acidified with 70% sulfuric acid [Chem. Eng. News 45(43):73 1967; J, Org. Chem. 28:1893 1963]. Alkyl hypochlorites are violently explosive. They are readily obtained by reacting hypochlorous acid and alcohols either in aqueous solution or mixed aqueous-carbon tetrachloride solutions. Chlorine plus alcohols would similarly yield alkyl hypochlorites. They decompose in the cold and explode on exposure to sunlight or heat. Tertiary hypochlorites are less unstable than secondary or primary hypochlorites [NFPA 491 M 1991]. Base-catalysed reactions of isocyanates with alcohols should be carried out in inert solvents. Such reactions in the absence of solvents often occur with explosive violence [Wischmeyer 1969].

Chemical Properties

Butyl alcohol, also known as butanol, exists in three isomeric alcohols that are toxic and soluble in most organic liquids. n-butyl alcohol, CH3(CH2)2CH20H, also known as l-butanol, propyl carbinol, and prim-butyl alcohol, is a colorless liquid. It is used in manufacturing perfumes and lacquers. sec-butyl alcohol, CH3CH2CHOHCH3, also known as 2-butanol, ethyl-methyl carbinol, butylene hydrate, and 2-hydroxy butane, is a colorless liquid. It is used in the preparation of fruit essence. tert-butyl alcohol, (CH3)3COH, also known as 2-methyl 2-propanol and trimethyl carbinol, is a colorless liquid.

Uses

Denaturant for ethanol, manufacturing flotation agents, flavors, perfumes; as solvent; in paint removers. Octane booster in gasoline.

Purification Methods

It is synthesised commercially by the hydration of 2-methylpropene in dilute H2SO4. Dry it with CaO, K2CO3, CaSO4 or MgSO4, filter and fractionally distil it. Dry further by refluxing with, and distilling from, either magnesium activated with iodine, or small amounts of calcium, sodium or potassium, under nitrogen. Passage through a column of type 4A molecular sieve is another effective method of drying; as well as refluxing with tert-butyl phthalate or succinate. (For method see Ethanol.) Other methods include refluxing with excess aluminium tert-butylate, or standing with CaH2, and distilling as needed. Further purification is achieved by fractional crystallisation by partial freezing, taking care to exclude moisture. tert-Butyl alcohol samples containing much water can be dried by adding *benzene, so that the water distils off as a tertiary azeotrope, b 67.3o. Traces of isobutylene have been removed from dry tert-butyl alcohol by bubbling dry pre-purified nitrogen through for several hours at 40-50o before using. It forms azeotropic mixtures with a large number of compounds. It has also been purified by distillation from CaH2 into Linde 4A molecular sieves which had been activated at 350o for 24hours [Jaeger et al. J Am Chem Soc 101 717 1979]. [Beilstein 1 IV 1609.] Rapid purification: Dry tert-butanol over CaH2 (5% w/v), distil and store it over 3A molecular sieves.

Health Hazard

Vapor is narcotic in action and irritating to respiratory passages. Liquid is irritating to skin and eyes.
InChI:InChI=1/C4H10O/c1-4(2,3)5/h5H,1-3H3

75-65-0 Well-known Company Product Price

Brand (Code)Product description CAS number Packaging Price Detail
Sigma-Aldrich (UST154)  tert-Butanol  certified reference material, 5000 μg/mL in methanol 75-65-0 UST154-1.5ML 362.70CNY Detail
Sigma-Aldrich (50621)  tert-Butanol  analytical standard 75-65-0 50621-5ML-F 993.33CNY Detail
Sigma-Aldrich (50621)  tert-Butanol  analytical standard 75-65-0 50621-1ML-F 255.06CNY Detail
Sigma-Aldrich (308250)  tert-Butanol  for HPLC, ≥99.5% 75-65-0 308250-1L 1,139.58CNY Detail
Sigma-Aldrich (308250)  tert-Butanol  for HPLC, ≥99.5% 75-65-0 308250-100ML 635.31CNY Detail
Sigma-Aldrich (24127)  tert-Butanol  ≥99% (GC) 75-65-0 24127-1L 872.82CNY Detail
Sigma-Aldrich (B85927)  tert-Butanol  TEBOL® 99, ≥99.3% 75-65-0 B85927-20L 6,622.20CNY Detail
Sigma-Aldrich (B85927)  tert-Butanol  TEBOL® 99, ≥99.3% 75-65-0 B85927-1L 920.79CNY Detail
Sigma-Aldrich (B85927)  tert-Butanol  TEBOL® 99, ≥99.3% 75-65-0 B85927-500ML 634.14CNY Detail
Sigma-Aldrich (19460)  tert-Butanol  puriss. p.a., ACS reagent, ≥99.7% (GC) 75-65-0 19460-5L 4,216.68CNY Detail
Sigma-Aldrich (19460)  tert-Butanol  puriss. p.a., ACS reagent, ≥99.7% (GC) 75-65-0 19460-2.5L 1,990.17CNY Detail
Sigma-Aldrich (19460)  tert-Butanol  puriss. p.a., ACS reagent, ≥99.7% (GC) 75-65-0 19460-1L 1,215.63CNY Detail

75-65-0SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 16, 2017

Revision Date: Aug 16, 2017

1.Identification

1.1 GHS Product identifier

Product name tert-butanol

1.2 Other means of identification

Product number -
Other names 2-Propanol, 2-methyl-

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only. Food additives -> Flavoring Agents
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:75-65-0 SDS

75-65-0Synthetic route

tertiary butyl chloride
507-20-0

tertiary butyl chloride

tert-butyl alcohol
75-65-0

tert-butyl alcohol

Conditions
ConditionsYield
With water at 20℃; for 1.5h;100%
With water
With water at 1℃; Rate constant; Thermodynamic data; solvolysis of tertiary, secondary, and primary substrates, thermodynamic data, temperature dependence;
pyridine
110-86-1

pyridine

tert-butylsulfinyl chloride
31562-43-3

tert-butylsulfinyl chloride

A

pyridine hydrochloride
628-13-7

pyridine hydrochloride

B

acetone
67-64-1

acetone

C

pyridinium tert-butylsulfonate

pyridinium tert-butylsulfonate

D

tert-butyl alcohol
75-65-0

tert-butyl alcohol

Conditions
ConditionsYield
With tert.-butylhydroperoxide In chloroform at 20℃; for 2h; Further byproducts given;A 100%
B 20%
C 40%
D 55%
2-tert-butoxytetrahydrofuran
1927-59-9

2-tert-butoxytetrahydrofuran

tert-butyl alcohol
75-65-0

tert-butyl alcohol

Conditions
ConditionsYield
With toluene-4-sulfonic acid In ethanol for 1h; Ambient temperature;100%
cyclohexane
110-82-7

cyclohexane

perpentene-4 oate de tertiobutyle
84210-61-7

perpentene-4 oate de tertiobutyle

A

cyclohexylcyclohexane
92-51-3

cyclohexylcyclohexane

B

butylcyclohexane
1678-93-9

butylcyclohexane

C

cyclohexyl-5 pentanolide-4
96009-79-9

cyclohexyl-5 pentanolide-4

D

acetone
67-64-1

acetone

E

5-methyl-dihydro-furan-2-one
108-29-2

5-methyl-dihydro-furan-2-one

F

tert-butyl alcohol
75-65-0

tert-butyl alcohol

Conditions
ConditionsYield
at 120℃; for 4h; Product distribution; Mechanism; different ratios of reactant, reactants, reaction times and temperatures;A 5%
B 5%
C 35%
D n/a
E 1%
F 100%
benzoic acid tert-butyl ester
774-65-2

benzoic acid tert-butyl ester

A

benzoic acid
65-85-0

benzoic acid

B

tert-butyl alcohol
75-65-0

tert-butyl alcohol

Conditions
ConditionsYield
With aluminum oxide; potassium hydroxide In diethyl ether for 21h; Product distribution; Ambient temperature; other solvent;A 100%
B 80%
2-(octylsulfonyl)ethyl tert-butyl peroxide
83073-73-8

2-(octylsulfonyl)ethyl tert-butyl peroxide

A

methane
34557-54-5

methane

B

2-hydroxyethyl octyl sulfone
20466-47-1

2-hydroxyethyl octyl sulfone

C

acetone
67-64-1

acetone

D

tert-butyl alcohol
75-65-0

tert-butyl alcohol

Conditions
ConditionsYield
In various solvent(s) at 145℃; Rate constant; Thermodynamic data; E(act.);A n/a
B 100%
C n/a
D n/a
9-t-butyl-10-methyl-9,10-endotrioxy-9,10-dihydroanthracene
86543-48-8

9-t-butyl-10-methyl-9,10-endotrioxy-9,10-dihydroanthracene

A

10-hydroxy-10-methylanthracen-9(10H)-one
17104-31-3

10-hydroxy-10-methylanthracen-9(10H)-one

B

tert-butyl alcohol
75-65-0

tert-butyl alcohol

C

VO(acac)2OH

VO(acac)2OH

Conditions
ConditionsYield
With bis(acetylacetonate)oxovanadium for 1h; Ambient temperature; 4 equiv. reagents;A 100%
B 61%
C n/a
9-tert-butyl-10-methyl-9,10-dihydroacridine
123525-58-6

9-tert-butyl-10-methyl-9,10-dihydroacridine

A

tert.-butylhydroperoxide
75-91-2

tert.-butylhydroperoxide

B

10-methylacridanium

10-methylacridanium

C

tert-butyl alcohol
75-65-0

tert-butyl alcohol

Conditions
ConditionsYield
With 9,10-Dicyanoanthracene; oxygen; trifluoroacetic acid; scandium tris(trifluoromethanesulfonate) In [D3]acetonitrile at 24.85℃; for 1h; Irradiation;A n/a
B 100%
C n/a
methanol
67-56-1

methanol

acetic acid tert-butyl ester
540-88-5

acetic acid tert-butyl ester

A

acetic acid methyl ester
79-20-9

acetic acid methyl ester

B

tert-butyl alcohol
75-65-0

tert-butyl alcohol

Conditions
ConditionsYield
With triethylamine at 20℃; under 8250660 Torr; for 2h; Product distribution;A 100%
B n/a
methanol
67-56-1

methanol

benzoic acid tert-butyl ester
774-65-2

benzoic acid tert-butyl ester

A

benzoic acid methyl ester
93-58-3

benzoic acid methyl ester

B

tert-butyl alcohol
75-65-0

tert-butyl alcohol

Conditions
ConditionsYield
With triethylamine at 20℃; under 8250660 Torr; for 2h; Product distribution;A 100%
B n/a
titanium(IV) tetrabutoxide

titanium(IV) tetrabutoxide

A

titanium(IV) oxide

titanium(IV) oxide

B

tert-butyl alcohol
75-65-0

tert-butyl alcohol

Conditions
ConditionsYield
In gas byproducts: (CH3)2CCH2; decomposition at a pressure of ca. 0.01 mm of Hg at 700°C; org. compounds collected in a liquid-N2 trap; NMR; GC; mass spectra;A n/a
B 100%
In gas byproducts: (CH3)2CCH2; decomposition at a pressure of ca. 0.01 mm of Hg at 550°C; org. compounds collected in a liquid-N2 trap; NMR; GC; mass spectra;A n/a
B 100%
titanium isopropoxide
872802-13-6

titanium isopropoxide

A

2,2-dimethyl-propanol-1
75-84-3

2,2-dimethyl-propanol-1

B

titanium(IV) oxide

titanium(IV) oxide

C

tert-butyl alcohol
75-65-0

tert-butyl alcohol

Conditions
ConditionsYield
In gas byproducts: (CH3)2CCHCH3, CH3CH2C(CH3)CH2; decomposition at a pressure of ca. 0.01 mm of Hg at 550°C; further compound: H2 was obtained with a yield of <0.5%; dineopentane, neopentane and/or 1,1-dimethylcyclopropane were not obtained; org. compounds collected in a liquid-N2 trap; NMR; GC; mass spectra;A 100%
B n/a
C <1
(p-cymene)osmium bis(t-butyloxide)
134654-70-9

(p-cymene)osmium bis(t-butyloxide)

2-methylpropan-2-thiol
75-66-1

2-methylpropan-2-thiol

A

(p-cymene)osmium bis(t-butylthiolate)
134654-72-1

(p-cymene)osmium bis(t-butylthiolate)

B

tert-butyl alcohol
75-65-0

tert-butyl alcohol

Conditions
ConditionsYield
In benzene-d6 soln. of CymOs(O-t-Bu)2 in C6D6 is degassed, t-BuSH is added at -196°C; (1)H-NMR;A 92%
B 100%
ytterbium di-tert-butyl dicarbonate

ytterbium di-tert-butyl dicarbonate

A

ytterbium hydroxide

ytterbium hydroxide

B

carbon dioxide
124-38-9

carbon dioxide

C

tert-butyl alcohol
75-65-0

tert-butyl alcohol

Conditions
ConditionsYield
With water In pentane addn. of a mixture (1:3) of water and pentane under Ar at room temperature; removing solvent and volatile compounds (t-BuOH) by vac. condensation;;A 93.2%
B 100%
C 100%
1,4,7-tris(tert-butoxycarbonylmethyl)-1,4,7,10-tetraazacyclododecane-10-acetic acid
137076-54-1

1,4,7-tris(tert-butoxycarbonylmethyl)-1,4,7,10-tetraazacyclododecane-10-acetic acid

A

1,4,7,10-tetrakis(carboxymethyl)-1,4,7,10-tetraazacyclododecane
60239-18-1

1,4,7,10-tetrakis(carboxymethyl)-1,4,7,10-tetraazacyclododecane

B

tert-butyl alcohol
75-65-0

tert-butyl alcohol

Conditions
ConditionsYield
With chlorotriisopropylsilane; water; trifluoroacetic acid for 3h; Time; Reagent/catalyst; Solvent;A 100%
B 100%
(3-(tert-butylperoxy)pentane-3yl)benzene

(3-(tert-butylperoxy)pentane-3yl)benzene

A

1-phenyl-propan-1-one
93-55-0

1-phenyl-propan-1-one

B

acetone
67-64-1

acetone

C

tert-butyl alcohol
75-65-0

tert-butyl alcohol

Conditions
ConditionsYield
With air In [D3]acetonitrile at 22℃; for 1h; UV-irradiation; Inert atmosphere;A 100%
B 41.9%
C 25.9%
ammonium cerium (IV) nitrate
16774-21-3

ammonium cerium (IV) nitrate

sodium t-butanolate
865-48-5

sodium t-butanolate

A

sodium nitrate
7631-99-4

sodium nitrate

B

Ce(OCMe3)(NO3)3(THF)2
121314-35-0

Ce(OCMe3)(NO3)3(THF)2

C

tert-butyl alcohol
75-65-0

tert-butyl alcohol

Conditions
ConditionsYield
In tetrahydrofuran byproducts: NH3; exclusion of air and water, stirred for 2 h; filtered (NaNO3), removal of solvent from filtrate, extn. (toluene), removal of solvent; elem. anal.;A 99%
B 56%
C n/a
tert-butoxytrimethylsilane
13058-24-7

tert-butoxytrimethylsilane

tert-butyl alcohol
75-65-0

tert-butyl alcohol

Conditions
ConditionsYield
With methanol; 1,3-disulfonic acid imidazolium hydrogen sulfate at 20℃; for 0.0833333h; Green chemistry;99%
With (NH4)8[CeW10O36]*20H2O In acetonitrile at 20℃; for 0.5h;80 %Chromat.
tert.-butylhydroperoxide
75-91-2

tert.-butylhydroperoxide

2,2'-azinobis-(3-ethyl-2,3-dihydrobenzothiazole-6-sulphonate) diammonium salt
30931-67-0

2,2'-azinobis-(3-ethyl-2,3-dihydrobenzothiazole-6-sulphonate) diammonium salt

A

methanol
67-56-1

methanol

B

formaldehyd
50-00-0

formaldehyd

C

C18H18N4O6S4(1+)*2H3N

C18H18N4O6S4(1+)*2H3N

D

acetone
67-64-1

acetone

E

tert-butyl alcohol
75-65-0

tert-butyl alcohol

Conditions
ConditionsYield
Fe(III)T4MPyP In water at 30℃; Rate constant; Kinetics; Mechanism; the catalyst Fe(III)T4MPyP is 5,10,15,20-tetra(N-methyl-4-pyridyl)-porphyrinatoiron(III) pentachloride; pH 9.2; investigation of the dependence of velocity constant on ionic strength, pH and t-butyl hydroperoxide concentration;A 3%
B n/a
C 72%
D 4%
E 98%
tert-butyl methyl ether
1634-04-4

tert-butyl methyl ether

tert-butyl alcohol
75-65-0

tert-butyl alcohol

Conditions
ConditionsYield
With methyltrifluoromethyldioxirane In tetrachloromethane at 0℃; for 0.166667h;98%
With oxygen; 3,3-dimethyldioxirane In acetone at 25℃; Kinetics;60 % Chromat.
With hydrogenchloride at 60℃; for 5h; pH=0; Kinetics;
With octane at 30℃; for 60h; Kinetics; Sealed tube;
(HOCO2)Cu((CH3)3CNC)3
73202-89-8

(HOCO2)Cu((CH3)3CNC)3

tert-butylisonitrile
119072-55-8, 7188-38-7

tert-butylisonitrile

copper (I) tert-butoxide
35342-67-7, 35342-68-8

copper (I) tert-butoxide

A

2Cu(1+)*CO3(2-)*99((CH3)3CNC) = Cu2CO3*99((CH3)3CNC)

2Cu(1+)*CO3(2-)*99((CH3)3CNC) = Cu2CO3*99((CH3)3CNC)

B

tert-butyl alcohol
75-65-0

tert-butyl alcohol

Conditions
ConditionsYield
In tetrahydrofuran N2; 0°C; equiv. amts. in presence of 3 equiv. (CH3)3CNC; GLC;A n/a
B 98%
((CH3)3COCO2)Cu(P(C2H5)3)3
72950-99-3

((CH3)3COCO2)Cu(P(C2H5)3)3

A

(HOCO2)Cu(P(C2H5)3)3
73233-55-3

(HOCO2)Cu(P(C2H5)3)3

B

tert-butyl alcohol
75-65-0

tert-butyl alcohol

Conditions
ConditionsYield
With water In pentane N2; mixt. of ((CH3)3CO)CO2Cu(P(C2H5)3)3 and 1.2 equiv. of H2O stirred for 6 h at 0°C; solvent evapd. in vacuo; crystd. (pentane, -78°C); elem. anal. GLC;A n/a
B 98%
tert.-butylhydroperoxide
75-91-2

tert.-butylhydroperoxide

diphenylsilanediol
947-42-2

diphenylsilanediol

triphenylantimony
603-36-1

triphenylantimony

A

Sb2O4Si2(C6H5)10

Sb2O4Si2(C6H5)10

B

water
7732-18-5

water

C

tert-butyl alcohol
75-65-0

tert-butyl alcohol

Conditions
ConditionsYield
In 1,4-dioxane dissoln., cooling (5°C), soln. of peroxo compd. addn. under stirring, stirring (2 h), volatile product sepn. in cooled trap (reduced pressure); elem. anal.;A 98%
B 89%
C 96%
octanol
111-87-5

octanol

benzoic acid tert-butyl ester
774-65-2

benzoic acid tert-butyl ester

A

n-octyl benzoate
94-50-8

n-octyl benzoate

B

tert-butyl alcohol
75-65-0

tert-butyl alcohol

Conditions
ConditionsYield
With cerium(IV) oxide at 180℃; for 15h;A 98%
B n/a
carbon dioxide
124-38-9

carbon dioxide

tert-butyl alcohol
75-65-0

tert-butyl alcohol

Conditions
ConditionsYield
With FeAl2O3; water under 15.0015 Torr; for 2h; Pressure; Time; Heating;97.5%
1-Bicyclo[2.2.1]hept-1-yl-1-bicyclo[2.2.2]oct-1-yl-2,2-dimethyl-propan-1-ol
89849-37-6

1-Bicyclo[2.2.1]hept-1-yl-1-bicyclo[2.2.2]oct-1-yl-2,2-dimethyl-propan-1-ol

A

bicyclo[2.2.2]octan-1-ol
20534-58-1

bicyclo[2.2.2]octan-1-ol

B

tert-butyl alcohol
75-65-0

tert-butyl alcohol

Conditions
ConditionsYield
With n-butyllithium In N,N,N,N,N,N-hexamethylphosphoric triamide; hexane at 20℃; Product distribution;A 2.6%
B 97.4%
tert.-butylhydroperoxide
75-91-2

tert.-butylhydroperoxide

1,1-Diphenylmethanol
91-01-0

1,1-Diphenylmethanol

A

benzophenone
119-61-9

benzophenone

B

tert-butyl alcohol
75-65-0

tert-butyl alcohol

Conditions
ConditionsYield
With 4 A molecular sieve In tetrachloromethane; 2,2,4-trimethylpentane at 50℃; for 156h; Mechanism; other saturated and unsaturated alcohols, various reaction time, other reagents: molecular sieves 3A, molecular sieves 13X, molecular sieves absence, microwave irradiation presence or absence;A 97%
B n/a
rac-octan-2-ol
4128-31-8

rac-octan-2-ol

benzoic acid tert-butyl ester
774-65-2

benzoic acid tert-butyl ester

A

2-octyl benzoate
6938-51-8

2-octyl benzoate

B

tert-butyl alcohol
75-65-0

tert-butyl alcohol

Conditions
ConditionsYield
With cerium(IV) oxide at 180℃; for 18h;A 97%
B n/a
tert-butyl acetoacetate
1694-31-1

tert-butyl acetoacetate

glycerol
56-81-5

glycerol

A

glyceryl-1,2,3-triacetoacetate
6079-98-7

glyceryl-1,2,3-triacetoacetate

B

tert-butyl alcohol
75-65-0

tert-butyl alcohol

Conditions
ConditionsYield
at 115℃; for 21h; Product distribution / selectivity;A 96.6%
B n/a
tert-Butoxybis(dimethylamino)methane
5815-08-7

tert-Butoxybis(dimethylamino)methane

3-Dimethylamino-2-(formylaminomethyl)acrylsaeure-ethylester
74119-34-9

3-Dimethylamino-2-(formylaminomethyl)acrylsaeure-ethylester

A

ethyl 3-(dimethylamino)acrylate
924-99-2, 1117-37-9, 114894-59-6

ethyl 3-(dimethylamino)acrylate

B

dimethyl amine
124-40-3

dimethyl amine

C

tert-butyl alcohol
75-65-0

tert-butyl alcohol

Conditions
ConditionsYield
at 160℃; for 3h;A 96%
B n/a
C n/a
acetic anhydride
108-24-7

acetic anhydride

tert-butyl alcohol
75-65-0

tert-butyl alcohol

acetic acid tert-butyl ester
540-88-5

acetic acid tert-butyl ester

Conditions
ConditionsYield
at 200℃; under 22502.3 Torr; for 0.166667h; Product distribution / selectivity;100%
With Cp2Ti(OSO2C8F17)2 at 100℃; for 0.0833333h; Neat (no solvent);99%
With bismuth(lll) trifluoromethanesulfonate In acetonitrile at 20℃; for 0.166667h;98%
acetonitrile
75-05-8

acetonitrile

tert-butyl alcohol
75-65-0

tert-butyl alcohol

N-tert-butylacetamide
762-84-5

N-tert-butylacetamide

Conditions
ConditionsYield
With Selectfluor; Diphenylphosphine oxide at 60℃; for 24h; Ritter Amidation;100%
With 1-methyl-3-(4-sulfonylbutyl)-1H-imidazol-3-ium trifluoromethanesulfonate at 70℃; for 8h; Ritter reaction; Inert atmosphere; Ionic liquid;95%
With HClO4-functionalized silica-coated magnetic nanoparticles [γ-Fe2O3@SiO2-HClO4] at 20℃; for 4h; Ritter reaction; Neat (no solvent);94%
tert-butyl alcohol
75-65-0

tert-butyl alcohol

tertiary butyl chloride
507-20-0

tertiary butyl chloride

Conditions
ConditionsYield
With bismuth(III) chloride In tetrachloromethane at 25℃; for 0.0833333h;100%
With phenylphosphorus tetrachloride In chloroform at 50℃; for 12h;97%
With acetic acid; calcium chloride at 55℃; for 8h; Reagent/catalyst; Temperature;96.2%
tert-butyl alcohol
75-65-0

tert-butyl alcohol

isobutene
115-11-7

isobutene

Conditions
ConditionsYield
With air oxidized carbon nanotubes at 120℃; Kinetics; Reagent/catalyst; Temperature; Flow reactor; Inert atmosphere; chemoselective reaction;100%
With aminosulfonic acid In acetic anhydride at 80℃; for 0.5h; Dehydration;98%
niobium silicate at 250℃;98.9%
di(4-isocyanatophenyl)methane
101-68-8

di(4-isocyanatophenyl)methane

tert-butyl alcohol
75-65-0

tert-butyl alcohol

O,O'-di-tert-butyl 4,4'-methylenebis(4,1-phenylene)dicarbamate
59255-81-1

O,O'-di-tert-butyl 4,4'-methylenebis(4,1-phenylene)dicarbamate

Conditions
ConditionsYield
With MoCl2O2(dmf)2 In dichloromethane at 20℃; for 1h; Inert atmosphere;100%
In toluene at 85℃; for 3h; Inert atmosphere;96%
In toluene at 85℃; for 3h; Inert atmosphere;96%
diethoxyphosphoryl isocyanate
20039-33-2

diethoxyphosphoryl isocyanate

tert-butyl alcohol
75-65-0

tert-butyl alcohol

diethyl N-(tert-butoxycarbonyl)phosphoramidate
85232-02-6

diethyl N-(tert-butoxycarbonyl)phosphoramidate

Conditions
ConditionsYield
In tetrachloromethane for 1h; Ambient temperature;100%
9H-carbazole
86-74-8

9H-carbazole

tert-butyl alcohol
75-65-0

tert-butyl alcohol

1,3,6,8-tetra-tert-butyl-9H-carbazole
34601-54-2

1,3,6,8-tetra-tert-butyl-9H-carbazole

Conditions
ConditionsYield
With trifluoroacetic acid Heating;100%
methanesulfonyl chloride
124-63-0

methanesulfonyl chloride

tert-butyl alcohol
75-65-0

tert-butyl alcohol

tert-butyl mesylate
16427-41-1

tert-butyl mesylate

Conditions
ConditionsYield
With triethylamine In dichloromethane at -15℃; for 1h; Green chemistry;100%
1,1'-carbonyldiimidazole
530-62-1

1,1'-carbonyldiimidazole

tert-butyl alcohol
75-65-0

tert-butyl alcohol

tert-butyl 1H-imidazole-1-carboxylate
49761-82-2

tert-butyl 1H-imidazole-1-carboxylate

Conditions
ConditionsYield
potassium hydroxide In toluene at 60℃;100%
In toluene at 20 - 60℃; for 6h; Inert atmosphere;95%
With potassium hydroxide In toluene at 60℃; for 4h;92%
benzoic acid methyl ester
93-58-3

benzoic acid methyl ester

tert-butyl alcohol
75-65-0

tert-butyl alcohol

benzoic acid tert-butyl ester
774-65-2

benzoic acid tert-butyl ester

Conditions
ConditionsYield
With n-butyllithium In tetrahydrofuran; hexane for 18h; Ambient temperature;100%
With (1-ethyl-3-methylimidazol-2-ylidene)silver(I) chloride In toluene at 70℃; for 48h;
isocyanate de chlorosulfonyle
1189-71-5

isocyanate de chlorosulfonyle

tert-butyl alcohol
75-65-0

tert-butyl alcohol

N-tert-butyloxycarbonylsulfamoyl chloride
147000-89-3

N-tert-butyloxycarbonylsulfamoyl chloride

Conditions
ConditionsYield
In dichloromethane100%
In diethyl ether at -78 - 20℃; for 1h;95%
In hexane at 0℃; for 1h;91%
diethylphosphonoacetic acid
3095-95-2

diethylphosphonoacetic acid

tert-butyl alcohol
75-65-0

tert-butyl alcohol

tert-butyl diethylphosphonoacetate
27784-76-5

tert-butyl diethylphosphonoacetate

Conditions
ConditionsYield
With dicyclohexyl-carbodiimide In dichloromethane at 25℃; for 0.25h;100%
With dicyclohexyl-carbodiimide In dichloromethane at 25℃; for 0.25h; Product distribution; Further Variations:; Reaction partners; Reagents; Solvents;100%
With sulfuric acid In various solvent(s) for 12h;90%
With dicyclohexyl-carbodiimide In acetonitrile at 25℃; for 1h;
ethyl 2-hydroxypyrrolidine-1-carboxylate
69352-25-6

ethyl 2-hydroxypyrrolidine-1-carboxylate

tert-butyl alcohol
75-65-0

tert-butyl alcohol

2-tert-Butoxy-pyrrolidine-1-carboxylic acid ethyl ester
110910-78-6

2-tert-Butoxy-pyrrolidine-1-carboxylic acid ethyl ester

Conditions
ConditionsYield
With acetic acid100%
1-(dichlorophosphoryl)-ethenyl isocyanate
73984-98-2

1-(dichlorophosphoryl)-ethenyl isocyanate

tert-butyl alcohol
75-65-0

tert-butyl alcohol

tert-butyl <1-(dichlorophosphinyl)vinyl>carbamate
73993-27-8

tert-butyl <1-(dichlorophosphinyl)vinyl>carbamate

Conditions
ConditionsYield
In hexane at 0℃; for 1h;100%
3-(2-vinyloxyethoxy)-1,2-propylene carbonate
54107-24-3

3-(2-vinyloxyethoxy)-1,2-propylene carbonate

tert-butyl alcohol
75-65-0

tert-butyl alcohol

4-[2-(1-tert-Butoxy-ethoxy)-ethoxymethyl]-[1,3]dioxolan-2-one
126867-32-1

4-[2-(1-tert-Butoxy-ethoxy)-ethoxymethyl]-[1,3]dioxolan-2-one

Conditions
ConditionsYield
With heptafluorobutyric Acid at 20 - 45℃; for 5h;100%
2-(pentamethyldisilanyl)-5-tert-butyl-1,4-benzoquinone
131904-60-4

2-(pentamethyldisilanyl)-5-tert-butyl-1,4-benzoquinone

tert-butyl alcohol
75-65-0

tert-butyl alcohol

5-(tert-Butoxy-dimethyl-silanyl)-2-tert-butyl-4-trimethylsilanyloxy-phenol
131904-67-1

5-(tert-Butoxy-dimethyl-silanyl)-2-tert-butyl-4-trimethylsilanyloxy-phenol

Conditions
ConditionsYield
In hexane for 0.166667h; Ambient temperature; Irradiation;100%
carbonyl isocyanate isocyanide dichloride
78476-62-7

carbonyl isocyanate isocyanide dichloride

tert-butyl alcohol
75-65-0

tert-butyl alcohol

4-(Dichlormethylen)allophansaeure-tert-butylester
78476-68-3

4-(Dichlormethylen)allophansaeure-tert-butylester

Conditions
ConditionsYield
In Petroleum ether; pentane at 0℃; for 2h;100%
4,4a-dihydro-3,3-dimethyl-1-phenyl-4,4-bis(trimethylsilyl)-3H-2-oxa-3-silanaphthaline
80431-42-1

4,4a-dihydro-3,3-dimethyl-1-phenyl-4,4-bis(trimethylsilyl)-3H-2-oxa-3-silanaphthaline

tert-butyl alcohol
75-65-0

tert-butyl alcohol

A

benzophenone
119-61-9

benzophenone

B

tert-Butoxydimethylsilyl-bis(trimethylsilyl)methan
87161-31-7

tert-Butoxydimethylsilyl-bis(trimethylsilyl)methan

Conditions
ConditionsYield
In benzene at 90℃; for 1.5h; Rate constant; half live time;A n/a
B 100%

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