1,4,7,10,13-Benzopentaoxacyclopentadecin, 2,3,5,6,8,9,11,12-octahydro-15-bromo-

Base Information

Chemical Name:1,4,7,10,13-Benzopentaoxacyclopentadecin, 2,3,5,6,8,9,11,12-octahydro-15-bromo-
CAS No.:60835-72-5
Molecular Formula:C14H19 Br O5
Molecular Weight:347.206
Hs Code.:29092000
European Community (EC) Number:678-080-7
DSSTox Substance ID:DTXSID50209687
Nikkaji Number:J328.341K
Wikidata:Q72451587
Mol file:60835-72-5.mol

Synonyms:60835-72-5;m-Bromobenzo-15-crown-5;4'-Bromobenzo-15-crown 5-Ether;1,4,7,10,13-Benzopentaoxacyclopentadecin, 2,3,5,6,8,9,11,12-octahydro-15-bromo-;BRN 1587587;15-Bromo-2,3,5,6,8,9,11,12-octahydrobenzo[b][1,4,7,10,13]pentaoxacyclopentadecine;4-BROMOBENZO-15-CROWN 5-ETHER;17-bromo-2,5,8,11,14-pentaoxabicyclo[13.4.0]nonadeca-1(15),16,18-triene;2,3-(4-Bromobenzo)-1,4,7,10,13-pentaoxacyclopentadec-2-ene;2,3,5,6,8,9,11,12-Octahydro-15-bromo-1,4,7,10,13-benzopentaoxacyclopentadecin;15-bromo-2,3,5,6,8,9,11,12-octahydro-1,4,7,10,13-benzopentaoxacyclopentadecine;KUROMANINCHLORIDE;C14H19BrO5;YSCK0329;C14-H19-Br-O5;DTXSID50209687;CCG-53509;MFCD00143270;STL089786;AKOS001083442;BS-52283;LS-38792;B2189;CS-0197318;T71120;SR-01000395834;1,2-[Oxybis(ethyleneoxyethyleneoxy)]-4-bromobenzene;SR-01000395834-1;SR-01000395834-2;Z57035386

Suppliers and Price of 1,4,7,10,13-Benzopentaoxacyclopentadecin, 2,3,5,6,8,9,11,12-octahydro-15-bromo-

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

TRC
4'-Bromobenzo-15-crown 5-Ether
100mg
$ 75.00

TCI Chemical
4'-Bromobenzo-15-crown 5-Ether >93.0%(GC)
5g
$ 823.00

TCI Chemical
4'-Bromobenzo-15-crown 5-Ether >93.0%(GC)
1g
$ 239.00

Biosynth Carbosynth
4'-Bromobenzo-15-crown 5-ether
5 g
$ 570.00

Biosynth Carbosynth
4'-Bromobenzo-15-crown 5-ether
2 g
$ 285.00

Biosynth Carbosynth
4'-Bromobenzo-15-crown 5-ether
250 mg
$ 55.00

Biosynth Carbosynth
4'-Bromobenzo-15-crown 5-ether
1 g
$ 164.00

Biosynth Carbosynth
4'-Bromobenzo-15-crown 5-ether
500 mg
$ 95.00

American Custom Chemicals Corporation
4'-BROMOBENZO-15-CROWN-5 95.00%
1G
$ 753.00

Ambeed
15-Bromo-2,3,5,6,8,9,11,12-octahydrobenzo[b][1,4,7,10,13]pentaoxacyclopentadecine 98%
1g
$ 127.00

Total 15 raw suppliers

Chemical Property of 1,4,7,10,13-Benzopentaoxacyclopentadecin, 2,3,5,6,8,9,11,12-octahydro-15-bromo-

Chemical Property:

Melting Point:68-71 °C
Refractive Index:1.4490 (estimate)
Boiling Point:440.6±45.0 °C(Predicted)
Flash Point:182.9oC
PSA：46.15000
Density:1.298
LogP:2.27010
XLogP3:1.1
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:5
Rotatable Bond Count:0
Exact Mass:346.04159
Heavy Atom Count:20
Complexity:254

Purity/Quality:

98%,99%, ^*data from raw suppliers

4'-Bromobenzo-15-crown 5-Ether ^*data from reagent suppliers

Safty Information:

Pictogram(s): Xi
Hazard Codes:Xi
Statements: 36/37/38
Safety Statements: 24/25

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:C1COCCOC2=C(C=C(C=C2)Br)OCCOCCO1

Technology Process of 1,4,7,10,13-Benzopentaoxacyclopentadecin, 2,3,5,6,8,9,11,12-octahydro-15-bromo-

There total 4 articles about 1,4,7,10,13-Benzopentaoxacyclopentadecin, 2,3,5,6,8,9,11,12-octahydro-15-bromo- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

: 14098-44-3
2,3,5,6,8,9,11,12-octahydro-1,4,7,10,13-benzopentaoxacyclopentadecin

: 60835-72-5
4'-bromobenzo-15-crown-5-ether

Guidance literature:: With bromine; In tetrahydrofuran; 1,4-dioxane; at 0 ℃;
DOI:10.3987/COM-06-10831

Reference yield:

: 638-56-2,27252-69-3
1,11-dichloro-3,6,9-trioxaundecane

: 60835-72-5
4'-bromobenzo-15-crown-5-ether

Guidance literature:: Multi-step reaction with 2 steps

1: 52 percent / aq. NaOH / butan-1-ol / Heating

2: 80 percent / bromine / dioxane; tetrahydrofuran / 0 °C

With sodium hydroxide; bromine; In tetrahydrofuran; 1,4-dioxane; butan-1-ol;
DOI:10.3987/COM-06-10831

Reference yield:

: 112-60-7
Tetraethylene glycol

: 60835-72-5
4'-bromobenzo-15-crown-5-ether

Guidance literature:: Multi-step reaction with 3 steps

1: 81 percent / SOCl₂; pyridine / benzene / Heating

2: 52 percent / aq. NaOH / butan-1-ol / Heating

3: 80 percent / bromine / dioxane; tetrahydrofuran / 0 °C

With pyridine; sodium hydroxide; thionyl chloride; bromine; In tetrahydrofuran; 1,4-dioxane; butan-1-ol; benzene;
DOI:10.3987/COM-06-10831