1-nitro-4-(phenylselanyl)benzene

Base Information

• Chemical Name: 1-nitro-4-(phenylselanyl)benzene
• CAS No.: 6343-83-5
• Molecular Formula: C12H9 N O2 Se
• Molecular Weight: 278.169
• Mol file: 6343-83-5.mol

Synonyms:Selenide,p-nitrophenyl phenyl (7CI,8CI); 1-Nitro-4-(phenylseleno)benzene; 4-Nitrophenylphenyl selenide; NSC 49761; Phenyl p-nitrophenyl selenide; p-Nitrophenyl phenylselenide

Chemical Property of 1-nitro-4-(phenylselanyl)benzene

Chemical Property:

• Vapor Pressure: 9.54E-06mmHg at 25°C
• Boiling Point: 383.7°Cat760mmHg
• Flash Point: 185.8°C
• Density: g/cm³

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 1-nitro-4-(phenylselanyl)benzene

There total 34 articles about 1-nitro-4-(phenylselanyl)benzene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 97.0%

iodobenzene (591-50-4) + dimethyl 2-((4-nitrophenyl)(trifluoromethyl)-λ4-selanylidene)malonate → 4-nitrophenyl(phenyl)selenide (6343-83-5)

Guidance literature:

With copper (I) acetate; In dimethyl sulfoxide; at 100 ℃; for 20h; Inert atmosphere; Glovebox; Sealed tube;

DOI:10.1039/c9ob01506j

Reference yield: 96.0%

diphenyl diselenide (1666-13-3) + 4-nitrophenylboronic acid (24067-17-2) → 4-nitrophenyl(phenyl)selenide (6343-83-5)

Guidance literature:

With C₂₈H₂₀CuN₄O₂; In dimethyl sulfoxide; at 100 ℃; for 10h; Green chemistry;

DOI:10.1016/j.mcat.2018.02.028

Reference yield: 96.0%

phenyl tributylstannyl selenide (41924-21-4) + 4-nitro-benzenediazonium; tetrachlorozincate → 4-nitrophenyl(phenyl)selenide (6343-83-5)

Guidance literature:

In methanol; at 20 ℃; for 0.166667h;

DOI:10.1016/S0022-328X(00)00265-5

upstream raw materials:

Benzeneselenol

para-nitrophenyl bromide

lithium phenylselenide

C₁₅H₁₆N₂O₄S

Downstream raw materials:

dibromo-(4-nitro-phenyl)-phenyl-λ⁴-selane

Cy-PSe

methyl(4-(phenylselanyl)phenyl)sulfane

4-aminophenyl phenyl selenide