4-methoxy-N-phenyliminobenzamide

Base Information

• Chemical Name: 4-methoxy-N-phenyliminobenzamide
• CAS No.: 30410-44-7
• Molecular Formula: C14H12 N2 O2
• Molecular Weight: 240.2573
• NSC Number: 98042
• DSSTox Substance ID: DTXSID30294773
• Mol file: 30410-44-7.mol

Synonyms:30410-44-7;4-methoxy-N-phenyliminobenzamide;NSC98042;DTXSID30294773;NSC-98042

Chemical Property of 4-methoxy-N-phenyliminobenzamide

Chemical Property:

• Vapor Pressure: 4.23E-06mmHg at 25°C
• Boiling Point: 384°Cat760mmHg
• Flash Point: 175.8°C
• Density: 1.12g/cm³
• XLogP3: 3.6
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 3
• Rotatable Bond Count: 3
• Exact Mass: 240.089877630
• Heavy Atom Count: 18
• Complexity: 290

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: COC1=CC=C(C=C1)C(=O)N=NC2=CC=CC=C2

Technology Process of 4-methoxy-N-phenyliminobenzamide

There total 2 articles about 4-methoxy-N-phenyliminobenzamide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

4-methoxy-N'-phenylbenzohydrazide (15089-03-9) → (4-methoxy-benzoyl)-phenyl-diazene (30410-44-7)

Guidance literature:

With diethyl ether; mixture of gaseous nitrogen oxides;

Reference yield:

diethyl ether (60-29-7,927820-24-4) + 4-methoxy-N'-phenylbenzohydrazide (15089-03-9) → (4-methoxy-benzoyl)-phenyl-diazene (30410-44-7)

Guidance literature:

Reference yield: 80.0%

5-phenyl-penta-2,3-dienoic acid ethyl ester (935254-77-6) + (4-methoxy-benzoyl)-phenyl-diazene (30410-44-7) → (Z)-ethyl 2-(5-benzyl-2-(4-methoxyphenyl)-4-phenyl-4H-1,3,4-oxadiazin-6(5H)-ylidene)acetate

Guidance literature:

With dmap; In toluene; at 20 ℃; for 48h;

DOI:10.1021/acs.orglett.5b01237

upstream raw materials:

4-methoxy-N'-phenylbenzohydrazide

diethyl ether

Downstream raw materials:

4-methoxy-N'-phenylbenzohydrazide

Refernces

• 1、 Huang, Zhengyan,Zhang, Qianqian,Zhao, Qiongli,Yu, Wenquan,Chang, Junbiao. "Synthesis of 2-Imino-1,3,4-Thiadiazoles from Hydrazides and Isothiocyanates via Sequential Oxidation and P(NMe2)3-Mediated Annulation Reactions". supporting information. p. 4378 - 4382. Retrieved 2020/06/03.