Silane, [(5-bromo-2-chlorophenyl)methoxy](1,1-dimethylethyl)dimethyl-

Base Information

Chemical Name:Silane, [(5-bromo-2-chlorophenyl)methoxy](1,1-dimethylethyl)dimethyl-
CAS No.:873782-26-4
Molecular Formula:C13H20BrClOSi
Molecular Weight:335.744
Hs Code.:

Synonyms:3-tert-butyldimethylsilyloxymethyl-4-chlorobromobenzene;(5-bromo-2-chloro-benzyloxy)-tert-butyl-dimethyl-silane;[(5-bromo-2-chlorobenzyl)oxy](tert-butyl)dimethylsilane;(5-bromo-2-chlorobenzyloxy)-tert-butyldimethylsilane;

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of Silane, [(5-bromo-2-chlorophenyl)methoxy](1,1-dimethylethyl)dimethyl-

Chemical Property:

PSA：9.23000
LogP:5.62430

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of Silane, [(5-bromo-2-chlorophenyl)methoxy](1,1-dimethylethyl)dimethyl-

There total 3 articles about Silane, [(5-bromo-2-chlorophenyl)methoxy](1,1-dimethylethyl)dimethyl- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

: 18162-48-6
tert-butyldimethylsilyl chloride

: 149965-40-2
5-bromo-2-chlorobenzyl alcohol

: 873782-26-4
((5-bromo-2-chlorobenzyl)oxy)(tert-butyl)dimethylsilane

Guidance literature:: With 1H-imidazole; In dichloromethane; at 0 - 20 ℃; for 14h; Inert atmosphere;
DOI:10.1021/jacs.6b02240

Reference yield:

: 21739-92-4
5-bromo-2-chlorobenzoic acid

: 873782-26-4
((5-bromo-2-chlorobenzyl)oxy)(tert-butyl)dimethylsilane

Guidance literature:: Multi-step reaction with 2 steps

1: 2-bromo-5-chlorobenzoic acid / tetrahydrofuran / 16 h / 0 - 10 °C

2: 1H-imidazole / N,N-dimethyl-formamide / 16 h / 10 °C

With 1H-imidazole; 2-bromo-5-chlorobenzoic acid; In tetrahydrofuran; N,N-dimethyl-formamide;

Reference yield:

: 76008-73-6
5-Bromo-2-chloro-benzoic acid ethyl ester

: 873782-26-4
((5-bromo-2-chlorobenzyl)oxy)(tert-butyl)dimethylsilane

Guidance literature:: Multi-step reaction with 2 steps

1: diisobutylaluminium hydride / tetrahydrofuran / 2 h / -78 - 20 °C

2: 1H-imidazole / N,N-dimethyl-formamide / 3 h / 20 °C

With 1H-imidazole; diisobutylaluminium hydride; In tetrahydrofuran; N,N-dimethyl-formamide;