Mnt4MPyP

Base Information

• Chemical Name: Mnt4MPyP
• CAS No.: 70649-54-6
• Molecular Formula: C₄₄H₃₆MnN₈*5Cl
• Molecular Weight: 909.026
• Mol file: 70649-54-6.mol

Synonyms:manganese (III) tetrakis(1-methyl-4-pyridyl)porphyrin pentachloride;manganese(III)-tetrakis(4-N-methylpyridyl)porphyrin;meso-tetrakis(N-methyl-4-pyridinium-yl)porphine Mn;Mn(III)-tetrakis(4-N-methylpyridyl)porphine;Mn(III)TMPyP;MnT4MPyP;tetrakis(N-methyl-4-pyridiniumyl)porphine manganese(III) complex;tetrakis-(4-N-methylpyridyl)porphyrinatomanganese (III)

Chemical Property of Mnt4MPyP

Chemical Property:

• PSA: 38.32000
• LogP: 1.73580
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 5
• Rotatable Bond Count: 3
• Exact Mass: 731.244336
• Heavy Atom Count: 53
• Complexity: 1500

Purity/Quality:

98.5% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CN1C=CC(=C2C3=NC(=C(C4=NC(=C(C5=CC=C([N-]5)C(=C6C=CC2=N6)C7=CC=[N+](C=C7)C)C8=CC=[N+](C=C8)C)C=C4)C9=CC=[N+](C=C9)C)C=C3)C=C1.[Mn+3]

Technology Process of Mnt4MPyP

There total 1 articles about Mnt4MPyP which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

μ-oxo-(PMn(6+)-O(2-)-MnP(6+)) (114595-73-2) → MnTMPyP (70649-54-6)

Guidance literature:

With water; In water; 0.1 M sodium phosphate, pH 9.1, after extensive preelectrolysis of buffer; observation by visible spectrum, monitoring oxygen levels, HPLC (ODS-column,H2O/CH3CN/CF3COOH); Kinetics;

Reference yield:

manganese(III) meso-tetrakis(1-methyl-4-pyridyl)porphyrin (70649-54-6) → manganese(III) meso-tetrakis(1-methylpyridinium-4-yl)porphyrin (72924-08-4)

Guidance literature:

With SO₂^(1-); In hydrogenchloride; byproducts: SO2; SO2(1-) radical generated by reaction with CO2(1-) or with the 2-hydroxy-2-propyl radical (these radicals were generated by radiolysis of isopropanol or CO2 containing acidic solns.), reaction in presence and absence of excess SO2; detn. by UV absorption; Kinetics;

DOI:10.1021/j100290a063

upstream raw materials:

μ-oxo-(PMn(6+)-O(2-)-MnP(6+))

Downstream raw materials:

manganese(III) meso-tetrakis(1-methylpyridinium-4-yl)porphyrin

Refernces