MN(III)TETRAKIS(1-METHYL-4-PYRIDYL)PORPHYRIN PENTACHLORIDE

Base Information

• Chemical Name: MN(III)TETRAKIS(1-METHYL-4-PYRIDYL)PORPHYRIN PENTACHLORIDE
• CAS No.: 72924-08-4
• Molecular Formula: C₄₄H₃₆MnN₈
• Molecular Weight: 731.761
• Mol file: 72924-08-4.mol

Synonyms:Manganese(4+),((4,4',4'',4'''-(21H,23H-porphine-5,10,15,20-tetrayl-kappaN21,kappaN22,kappaN23,kappaN24)tetrakis(1-methylpyridiniumato))(2-))-,(SP-4-1);Mn(III) 5,10,15,20-tetrakis(N-methylpyridinium-2-yl)porphyrin;manganese meso-tetrakis[4-N-methypyridinium]porphophine;Mn(meso-tetrakis(4-N-methylpyridinium)porphophine);manganese(II) 5,10,15,20-tetrakis(N-methyl-4-pyridyl) porphyrin;5,15-bis(1-methylpyridin-1-ium-3-yl)-10-(1-methylpyridin-1-ium-4-yl)-20-(1-methylpyridin-4-ylidene)porphyrin-22-ide;manganese(III) meso-tetrakis(1-methylpyridinium-4-yl)porphyrin;manganese(II) tetrakis(N-methylpyridyl)porphyrin;Mn(tetrakis(N-methyl-4'-pyridyl)porphyrin);manganese(II) tetrakis(N-methyl-4-pyridiniumyl)porphyrin(4+);

Chemical Property of MN(III)TETRAKIS(1-METHYL-4-PYRIDYL)PORPHYRIN PENTACHLORIDE

Chemical Property:

• PSA: 66.54000
• LogP: 2.87070

Purity/Quality:

99% ^*data from raw suppliers

Mn(III)TMPyP ≥95% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of MN(III)TETRAKIS(1-METHYL-4-PYRIDYL)PORPHYRIN PENTACHLORIDE

There total 4 articles about MN(III)TETRAKIS(1-METHYL-4-PYRIDYL)PORPHYRIN PENTACHLORIDE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

manganese(II) 5,10,15,20-tetrakis(4-pyridyl)porphyrin (14948-43-7) + methyl p-toluene sulfonate (80-48-8) → manganese(III) meso-tetrakis(1-methylpyridinium-4-yl)porphyrin (72924-08-4)

Guidance literature:

In N,N-dimethyl-formamide; at 90 ℃; for 12h;

DOI:10.1142/S1088424612500721

Reference yield:

manganese(III) meso-tetrakis(1-methyl-4-pyridyl)porphyrin (70649-54-6) → manganese(III) meso-tetrakis(1-methylpyridinium-4-yl)porphyrin (72924-08-4)

Guidance literature:

With SO₂^(1-); In hydrogenchloride; byproducts: SO2; SO2(1-) radical generated by reaction with CO2(1-) or with the 2-hydroxy-2-propyl radical (these radicals were generated by radiolysis of isopropanol or CO2 containing acidic solns.), reaction in presence and absence of excess SO2; detn. by UV absorption; Kinetics;

DOI:10.1021/j100290a063

Reference yield:

pyridine-4-carbaldehyde (872-85-5) → manganese(III) meso-tetrakis(1-methylpyridinium-4-yl)porphyrin (72924-08-4)

Guidance literature:

Multi-step reaction with 3 steps

1: propionic acid / 1 h / Reflux

2: N,N-dimethyl-formamide / 6 h / Reflux; Inert atmosphere

3: N,N-dimethyl-formamide / 12 h / 90 °C

In propionic acid; N,N-dimethyl-formamide;

DOI:10.1142/S1088424612500721

upstream raw materials:

manganese(II) 5,10,15,20-tetrakis(4-pyridyl)porphyrin

methyl p-toluene sulfonate

manganese(III) meso-tetrakis(1-methyl-4-pyridyl)porphyrin

pyridine-4-carbaldehyde