10-epi-gamma-Eudesmol

Base Information

• Chemical Name: 10-epi-gamma-Eudesmol
• CAS No.: 15051-81-7
• Molecular Formula: C15H26O
• Molecular Weight: 222.371
• Hs Code.: 2906199090
• European Community (EC) Number: 866-515-5
• Nikkaji Number: J498.759D
• Wikidata: Q27131975
• Metabolomics Workbench ID: 62255
• Mol file: 15051-81-7.mol

Synonyms:10-epi-gamma-Eudesmol;epi-Eudesmol;15051-81-7;10-epi-eudesm-4-en-11-ol;2-[(2R,4aS)-4a,8-dimethyl-2,3,4,5,6,7-hexahydro-1H-naphthalen-2-yl]propan-2-ol;10alpha-Eudesm-4-en-11-ol;(2R-trans)-1,2,3,4,4a,5,6,7-Octahydro-alpha,alpha,4a,8-tetramethyl-2-naphthalenemethanol;2-((2R,4AS)-4a,8-dimethyl-1,2,3,4,4a,5,6,7-octahydronaphthalen-2-yl)propan-2-ol;2-[(2R,4aS)-4a,8-dimethyl-1,2,3,4,4a,5,6,7-octahydronaphthalen-2-yl]propan-2-ol;2-Naphthalenemethanol, 1,2,3,4,4a,5,6,7-octahydro-alpha,alpha,4a,8-tetramethyl-, (2R-trans)-;epi-10- .gamma.-Eudesmol;10-Eudesm-4-en-11-ol;SCHEMBL310948;CHEBI:62514;WMOPMQRJLLIEJV-DOMZBBRYSA-N;(-)-10-epi- .gamma.-eudesmol;AKOS032948531;C19893;Q27131975;(-)-10-epi--Eudesmol;10-epi--Eudesmol

Chemical Property of 10-epi-gamma-Eudesmol

Chemical Property:

• Vapor Pressure: 0.000103mmHg at 25°C
• Refractive Index: 1.505
• Boiling Point: 301.464 °C at 760 mmHg
• PKA: 15.11±0.29(Predicted)
• Flash Point: 108.502 °C
• PSA: 20.23000
• Density: 0.965 g/cm³
• LogP: 4.06410
• XLogP3: 3.4
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 1
• Exact Mass: 222.198365449
• Heavy Atom Count: 16
• Complexity: 313

Purity/Quality:

99%, ^*data from raw suppliers

epi-Eudesmol ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC1=C2CC(CCC2(CCC1)C)C(C)(C)O
• Isomeric SMILES: CC1=C2C[C@@H](CC[C@@]2(CCC1)C)C(C)(C)O

Technology Process of 10-epi-gamma-Eudesmol

There total 28 articles about 10-epi-gamma-Eudesmol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 82.0%

11,12-Oxido-α-cyperone (263860-43-1) → eudesm-4-en-11-ol (13902-07-3,15051-81-7,72173-98-9,98683-12-6,117066-77-0,1209-71-8,6710-66-3)

Guidance literature:

11,12-Oxido-α-cyperone; With lithium aluminium tetrahydride; In diethyl ether; at 20 ℃; for 7h;

With dichloroalane; In diethyl ether; at 0 ℃; for 6h;

Reference yield:

eudesobovatol A (125196-77-2) → obovatol (83864-78-2) + eudesm-4-en-11-ol (13902-07-3,15051-81-7,72173-98-9,98683-12-6,117066-77-0,1209-71-8,6710-66-3)

Guidance literature:

With trifluoroacetic acid; In benzene; for 10h; Ambient temperature;

DOI:10.1016/S0040-4020(01)89002-5

Reference yield:

eudesmagnolol (126654-54-4) → Magnolol (528-43-8) + eudesm-4-en-11-ol (13902-07-3,15051-81-7,72173-98-9,98683-12-6,117066-77-0,1209-71-8,6710-66-3)

Guidance literature:

With trifluoroacetic acid; In benzene; for 10h; Ambient temperature;

DOI:10.1016/S0040-4020(01)89002-5

upstream raw materials:

Epi-Carrisone

7-epi-cyperone

11,12-epoxycyperon

2-((3E,8E)-4,8-Dimethyl-cyclodeca-3,8-dienyl)-propan-2-ol

Downstream raw materials:

11-hydroxy-4,5-seco-endesmane-4,5-dione

4-epi-trans-dihydroagarofuran

(1R,4S,8S,9R)-2,2,4,8-Tetramethyl-3-oxa-tricyclo[6.2.2.0^4,9]dodecane

Refernces

• 1、 Xiong, Zhaoming,Zhou, Gang,Yang, Jiong,Chen, Yonggang,Li, Yulin. "An efficient stereocontrolled synthesis of (-)-10-epi-5β,11- dihydroxyeudesmane and (-)-4,10-epi-5β,11-dihydroxyeudesmane". . p. 1525 - 1530. Retrieved 1998.
• 2、 Minnaard, Adriaan J.,Stork, Gerrit A.,Wijnberg, Joannes B.P.A.,De Groot, Aede. "Total synthesis of neohedycaryol. Its possible role in the biosynthesis of eudesmane sesquiterpenes". . p. 2344 - 2349. Retrieved 2007/10/03.