Cyclohexanol, 2-[[(1,1-dimethylethyl)dimethylsilyl]oxy]-4-[[(1,1-dimethylethyl)diphenylsil yl]oxy]-1-[(2-phenyl-1,3-dithian-2-yl)methyl]-6-[(trimethylsilyl)oxy]-, (1R,2R,4R,6R)-

Base Information

Chemical Name:Cyclohexanol, 2-[[(1,1-dimethylethyl)dimethylsilyl]oxy]-4-[[(1,1-dimethylethyl)diphenylsil yl]oxy]-1-[(2-phenyl-1,3-dithian-2-yl)methyl]-6-[(trimethylsilyl)oxy]-, (1R,2R,4R,6R)-
CAS No.:874350-09-1
Molecular Formula:C42H64O4S2Si3
Molecular Weight:781.356
Hs Code.:

Cyclohexanol,
2-[[(1,1-dimethylethyl)dimethylsilyl]oxy]-4-[[(1,1-dimethylethyl)diphenylsil
yl]oxy]-1-[(2-phenyl-1,3-dithian-2-yl)methyl]-6-[(trimethylsilyl)oxy]-,
(1R,2R,4R,6R)-

Synonyms:

Suppliers and Price of Cyclohexanol, 2-[[(1,1-dimethylethyl)dimethylsilyl]oxy]-4-[[(1,1-dimethylethyl)diphenylsil yl]oxy]-1-[(2-phenyl-1,3-dithian-2-yl)methyl]-6-[(trimethylsilyl)oxy]-, (1R,2R,4R,6R)-

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Chemical Property of Cyclohexanol, 2-[[(1,1-dimethylethyl)dimethylsilyl]oxy]-4-[[(1,1-dimethylethyl)diphenylsil yl]oxy]-1-[(2-phenyl-1,3-dithian-2-yl)methyl]-6-[(trimethylsilyl)oxy]-, (1R,2R,4R,6R)-

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Technology Process of Cyclohexanol, 2-[[(1,1-dimethylethyl)dimethylsilyl]oxy]-4-[[(1,1-dimethylethyl)diphenylsil yl]oxy]-1-[(2-phenyl-1,3-dithian-2-yl)methyl]-6-[(trimethylsilyl)oxy]-, (1R,2R,4R,6R)-

There total 3 articles about Cyclohexanol, 2-[[(1,1-dimethylethyl)dimethylsilyl]oxy]-4-[[(1,1-dimethylethyl)diphenylsil yl]oxy]-1-[(2-phenyl-1,3-dithian-2-yl)methyl]-6-[(trimethylsilyl)oxy]-, (1R,2R,4R,6R)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

: 874350-08-0
(3R,4R,6R,8R)-8-(tert-butyldimethylsilyloxy)-6-(tert-butyldiphenylsilyloxy)-4-(trimethylsilyloxy)-1-oxaspiro[2.5]octane

: 5425-44-5
2-Phenyl-[1,3]dithiane

: 874350-09-1
(1R,2R,4R,6R)-2-(tert-butyldimethylsilyloxy)-4-(tert-butyldiphenylsilyloxy)-1-[(2-phenyl-1,3-dithian-2-yl)methyl]-6-(trimethylsilyloxy)-cyclohexan-1-ol

Guidance literature:: 2-Phenyl-[1,3]dithiane; With n-butyllithium; In tetrahydrofuran; hexane; at -40 ℃; for 2h;

(3R,4R,6R,8R)-8-(tert-butyldimethylsilyloxy)-6-(tert-butyldiphenylsilyloxy)-4-(trimethylsilyloxy)-1-oxaspiro[2.5]octane; In tetrahydrofuran; hexane; at -78 - -45 ℃; for 1.75h;
DOI:10.1002/chem.200500640

Reference yield:

: (4R,6R,8R)-8-(tert-butyldimethylsilyloxy)-6-(tert-butyldiphenylsilyloxy)-1-oxaspiro[2.5]octan-4-ol

: 874350-09-1
(1R,2R,4R,6R)-2-(tert-butyldimethylsilyloxy)-4-(tert-butyldiphenylsilyloxy)-1-[(2-phenyl-1,3-dithian-2-yl)methyl]-6-(trimethylsilyloxy)-cyclohexan-1-ol

Guidance literature:: Multi-step reaction with 2 steps

1.1: 99 percent / imidazole / dimethylformamide / 3 h / 20 °C

2.1: n-BuLi / tetrahydrofuran; hexane / 2 h / -40 °C

2.2: 90 percent / tetrahydrofuran; hexane / 1.75 h / -78 - -45 °C

With 1H-imidazole; n-butyllithium; In tetrahydrofuran; hexane; N,N-dimethyl-formamide;
DOI:10.1002/chem.200500640

Reference yield:

: 633294-28-7
(1R,3R,5R)-3-(tert-butyldimethylsilyloxy)-5-(tert-butyldiphenylsilyloxy)-2-methylenecyclohexanol

: 874350-09-1
(1R,2R,4R,6R)-2-(tert-butyldimethylsilyloxy)-4-(tert-butyldiphenylsilyloxy)-1-[(2-phenyl-1,3-dithian-2-yl)methyl]-6-(trimethylsilyloxy)-cyclohexan-1-ol

Guidance literature:: Multi-step reaction with 3 steps

1.1: 89 percent / VO(acac)2; tert-butylhydroperoxide / decane; CH₂Cl₂ / 15 h / 20 °C

2.1: 99 percent / imidazole / dimethylformamide / 3 h / 20 °C

3.1: n-BuLi / tetrahydrofuran; hexane / 2 h / -40 °C

3.2: 90 percent / tetrahydrofuran; hexane / 1.75 h / -78 - -45 °C

With 1H-imidazole; tert.-butylhydroperoxide; n-butyllithium; bis(acetylacetonate)oxovanadium; In tetrahydrofuran; decane; hexane; dichloromethane; N,N-dimethyl-formamide;
DOI:10.1002/chem.200500640