2,4-Dichloro-1-(fluoromethoxy)benzene

Base Information

Chemical Name:2,4-Dichloro-1-(fluoromethoxy)benzene
CAS No.:87453-28-9
Molecular Formula:C7H5Cl2FO
Molecular Weight:195.021
Hs Code.:
DSSTox Substance ID:DTXSID20526474
Nikkaji Number:J2.512.430H

Synonyms:2,4-Dichloro-1-(fluoromethoxy)benzene;87453-28-9;SCHEMBL12360711;DTXSID20526474

Suppliers and Price of 2,4-Dichloro-1-(fluoromethoxy)benzene

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 4 raw suppliers

Chemical Property of 2,4-Dichloro-1-(fluoromethoxy)benzene

Chemical Property:

XLogP3:4.1
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:2
Rotatable Bond Count:2
Exact Mass:193.9701483
Heavy Atom Count:11
Complexity:123

Purity/Quality:: 99% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:C1=CC(=C(C=C1Cl)Cl)OCF

Technology Process of 2,4-Dichloro-1-(fluoromethoxy)benzene

There total 4 articles about 2,4-Dichloro-1-(fluoromethoxy)benzene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 86.0%

: 94-75-7,89300-30-1
2,4-Dichlorophenoxyacetic acid

: 87453-28-9
2,4-dichloro-1-(fluoromethoxy)benzene

Guidance literature:: 2,4-Dichlorophenoxyacetic acid; With sodium hydroxide; In water; acetonitrile; for 0.416667h; Inert atmosphere;

With Selectfluor; In water; acetonitrile; for 1.5h; Inert atmosphere; UV-irradiation;
DOI:10.1002/anie.201206352

Reference yield: 86.0%

: 593-70-4
R₃₂

: 120-83-2,40477-79-0
2,4-dichlorophenol

: 87453-28-9
2,4-dichloro-1-(fluoromethoxy)benzene

Guidance literature:: With sodium hydride; In N,N-dimethyl-formamide; at 80 ℃; for 3h;
DOI:10.1016/j.tet.2007.08.043

Reference yield:

: 120-83-2,40477-79-0
2,4-dichlorophenol

: 87453-28-9
2,4-dichloro-1-(fluoromethoxy)benzene

Guidance literature:: Multi-step reaction with 3 steps

1: potassium carbonate / N,N-dimethyl-formamide / 12 h / 20 °C

2: sodium hydroxide / water; methanol / 1 h

3: N-fluorobis(benzenesulfon)imide; 2,6-di-tert-butyl-pyridine / acetone / 3 h / Inert atmosphere; Irradiation

With 2,6-di-tert-butyl-pyridine; potassium carbonate; N-fluorobis(benzenesulfon)imide; sodium hydroxide; In methanol; water; N,N-dimethyl-formamide; acetone;
DOI:10.1002/ejoc.201500038