1,1'-{[(Butan-2-yl)oxy]methylene}dibenzene

Base Information

• Chemical Name: 1,1'-{[(Butan-2-yl)oxy]methylene}dibenzene
• CAS No.: 87946-61-0
• Molecular Formula: C17H20O
• Molecular Weight: 240.345
• DSSTox Substance ID: DTXSID80520670
• Mol file: 87946-61-0.mol

Synonyms:87946-61-0;1,1'-{[(Butan-2-yl)oxy]methylene}dibenzene;SCHEMBL13813820;DTXSID80520670

Chemical Property of 1,1'-{[(Butan-2-yl)oxy]methylene}dibenzene

Chemical Property:

• XLogP3: 4.6
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 5
• Exact Mass: 240.151415257
• Heavy Atom Count: 18
• Complexity: 196

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CCC(C)OC(C1=CC=CC=C1)C2=CC=CC=C2

Technology Process of 1,1'-{[(Butan-2-yl)oxy]methylene}dibenzene

There total 8 articles about 1,1'-{[(Butan-2-yl)oxy]methylene}dibenzene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

diazodiphenylmethane (908093-98-1) + iso-butanol (78-92-2,15892-23-6) → (sec-butoxymethylene)dibenzene (87946-61-0)

Guidance literature:

Ambient temperature; Irradiation; xanthone, as triplet sensit. Var_. temp.;

DOI:10.1016/S0040-4039(00)94510-6

Reference yield: 78.0%

1,1-Diphenylmethanol (91-01-0) + iso-butanol (78-92-2,15892-23-6) → (sec-butoxymethylene)dibenzene (87946-61-0)

Guidance literature:

iso-butanol; With pentafluorophenylboronic acid; oxalic acid; In nitromethane; at 20 ℃; for 0.0833333h;

1,1-Diphenylmethanol; In nitromethane; at 20 ℃; for 16h;

DOI:10.1002/chem.201806057

Reference yield: 6.0%

diazodiphenylmethane (908093-98-1) + iso-butanol (78-92-2,15892-23-6) → (sec-butoxymethylene)dibenzene (87946-61-0) + 1,1-diphenyl-2-methyl-2-butanol (87946-62-1) + 5,5-diphenyl-2-pentanone (63797-58-0) + 1,1-diphenyl-3-pentanol (98855-11-9) + (2R*,3R*)-3-methyl-4,4-diphenyl-2-butanol + (2S*,3R*)-3-methyl-4,4-diphenyl-2-butanol

Guidance literature:

at -196.1 ℃; for 6h; Product distribution; Rate constant; Irradiation; var. temp.;

DOI:10.1021/ja00310a050

upstream raw materials:

acrylonitrile

diazodiphenylmethane

iso-butanol

(S)-2-butanol