Methanone, (2-chlorophenyl)(3-chlorophenyl)-, oxime, (Z)-

Base Information

Chemical Name:Methanone, (2-chlorophenyl)(3-chlorophenyl)-, oxime, (Z)-
CAS No.:87999-69-7
Molecular Formula:C13H9Cl2NO
Molecular Weight:266.127
Hs Code.:

Synonyms:

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of Methanone, (2-chlorophenyl)(3-chlorophenyl)-, oxime, (Z)-

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
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MSDS Files:: SDS file from LookChem

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Technology Process of Methanone, (2-chlorophenyl)(3-chlorophenyl)-, oxime, (Z)-

There total 9 articles about Methanone, (2-chlorophenyl)(3-chlorophenyl)-, oxime, (Z)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

: 77008-58-3
2,3'-dichloro-benzophenone

: 87999-69-7,126517-31-5
2,3'-Dichlorobenzophenone Oxime

Guidance literature:: With pyridine; hydroxylamine hydrochloride; for 48h; Heating;

Reference yield: 81.0%

: 87999-68-6
2',5-Dichloro-2-iodobenzophenone (E)-Oxime

: 87999-69-7
2,3'-Dichlorobenzophenone (Z)-Oxime

Guidance literature:: With triethylamine; bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide; In dichloromethane; Heating;
DOI:10.1021/jo00176a015

Reference yield:

: 2958-36-3,53960-29-5
(2-amino-5-chloro-phenyl)-(2-chloro-phenyl)-methanone

: 87999-69-7
2,3'-Dichlorobenzophenone (Z)-Oxime

Guidance literature:: Multi-step reaction with 5 steps

1: 1) NaNO₂/HCl/aq. CH₃COOH, 2) aq. KI

2: 27.4 percent / NH₂OH*HCl, piperidine / pyridine / 20 h / Heating

3: 83 percent / NaNO₂, 1 N HCl / ethanol; H₂O / 0.25 h / ice bath

4: 58.6 percent / KI / acetic anhydride / 48 h / Ambient temperature

5: 81 percent / Et₃N / cuprous iodide, bis(triphenylphosphine)palladium(II)chloride / CH₂Cl₂ / Heating

With piperidine; hydrogenchloride; hydroxylamine hydrochloride; acetic acid; triethylamine; potassium iodide; sodium nitrite; bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide; In pyridine; ethanol; dichloromethane; water; acetic anhydride;
DOI:10.1021/jo00176a015