Samarium, iodophenyl-

Base Information

• Chemical Name: Samarium, iodophenyl-
• CAS No.: 88020-61-5
• Molecular Formula: C6H5ISm
• Molecular Weight: 354.37
• Mol file: 88020-61-5.mol

Synonyms:

Chemical Property of Samarium, iodophenyl-

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Samarium, iodophenyl-

There total 1 articles about Samarium, iodophenyl- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

samarium (7440-19-9) + iodobenzene (591-50-4) + diiodomethane (75-11-6) → C6H5ISm (88020-61-5)

Guidance literature:

In tetrahydrofuran; Ar atmosphere; alkylation of metal with CH2I2 in THF, then reaction with PhI; not isolated;

DOI:10.1007/BF00957447

Reference yield: 70.0%

C6H5ISm (88020-61-5) + 1,3-diphenyl-propen-3-one (614-47-1) → (E)-1,1,3-triphenylprop-2-en-1-ol (71832-02-5)

Guidance literature:

In tetrahydrofuran; at -40 ℃; for 0.666667h;

DOI:10.1007/BF00954722

Reference yield: 28.0%

C6H5ISm (88020-61-5) + trimethylsilyltriphenyltin → tetraphenyltin(IV) (595-90-4)

Guidance literature:

With water; In tetrahydrofuran; byproducts: trimethylhydroxosilane, hexamethyldisiloxane; under Ar; addn. of freshly prepd. THF soln. of PhSmI to mixt. of THF and Ph3SnSiMe3, mixing at 25°C for 3 h, decompn. of react. mixt. with water acidified with HCl; thin layer chromy.;

upstream raw materials:

samarium

iodobenzene

diiodomethane

Downstream raw materials:

1,1,3,-triphenyl-1-propene

(E)-1,1,3-triphenylprop-2-en-1-ol

tetraphenyltin(IV)

triphenyltin(IV) hydroxide