(1-Bromo-2,2-diphenylcyclopropyl)(trimethyl)silane

Base Information

Chemical Name:(1-Bromo-2,2-diphenylcyclopropyl)(trimethyl)silane
CAS No.:88056-68-2
Molecular Formula:C18H21BrSi
Molecular Weight:345.354
Hs Code.:
DSSTox Substance ID:DTXSID40529907

Synonyms:(1-Bromo-2,2-diphenylcyclopropyl)(trimethyl)silane;88056-68-2;DTXSID40529907

Suppliers and Price of (1-Bromo-2,2-diphenylcyclopropyl)(trimethyl)silane

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (1-Bromo-2,2-diphenylcyclopropyl)(trimethyl)silane

Chemical Property:

Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:0
Rotatable Bond Count:3
Exact Mass:344.05959
Heavy Atom Count:20
Complexity:329

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:C[Si](C)(C)C1(CC1(C2=CC=CC=C2)C3=CC=CC=C3)Br

Technology Process of (1-Bromo-2,2-diphenylcyclopropyl)(trimethyl)silane

There total 3 articles about (1-Bromo-2,2-diphenylcyclopropyl)(trimethyl)silane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 59.0%

: 88082-48-8
2,2-Diphenyl-1-trimethylsilanyl-cyclopropanecarboxylic acid

: 88056-68-2
1-bromo-2,2-diphenyl-1-(trimethylsilyl)cyclopropane

Guidance literature:: With bromine; mercury(II) oxide; In tetrachloromethane; for 6h; Heating;
DOI:10.1021/ja00314a014

Reference yield: 43.0%

: Silver; 2,2-diphenyl-1-trimethylsilanyl-cyclopropanecarboxylate

: 88056-68-2
1-bromo-2,2-diphenyl-1-(trimethylsilyl)cyclopropane

Guidance literature:: With bromine; In tetrachloromethane; for 0.333333h;
DOI:10.1021/ja00314a014

Reference yield:

: 7150-12-1
2,2-diphenyl-cyclopropanecarboxylic acid

: 88056-68-2
1-bromo-2,2-diphenyl-1-(trimethylsilyl)cyclopropane

Guidance literature:: Multi-step reaction with 2 steps

1: 1.) LDA / 1.) THF, hexane, 0 deg C, 3 h; 2.) THF, overnight, r.t.

2: 59 percent / red mercuric oxide, Br₂ / CCl₄ / 6 h / Heating

With bromine; mercury(II) oxide; lithium diisopropyl amide; In tetrachloromethane;
DOI:10.1021/ja00314a014