Silane, (1,1-dimethylethyl)diphenyl(2-propynyloxy)-

Base Information

• Chemical Name: Silane, (1,1-dimethylethyl)diphenyl(2-propynyloxy)-
• CAS No.: 88159-06-2
• Molecular Formula: C19H22OSi
• Molecular Weight: 294.469
• Mol file: 88159-06-2.mol

Synonyms:Prop-2-yn-1-yl tert-butyldiphenylsilyl ether;propargylalcohol-OTBDPS;

Chemical Property of Silane, (1,1-dimethylethyl)diphenyl(2-propynyloxy)-

Chemical Property:

• PSA: 9.23000
• LogP: 3.19620

Purity/Quality:

99% ^*data from raw suppliers

tert-butyldiphenyl(prop-2-yn-1-yloxy)silane ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Silane, (1,1-dimethylethyl)diphenyl(2-propynyloxy)-

There total 1 articles about Silane, (1,1-dimethylethyl)diphenyl(2-propynyloxy)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

propargyl alcohol (107-19-7) + tert-butylchlorodiphenylsilane (58479-61-1) → tert-butyl(diphenyl)(2-propynyloxy)silane (88159-06-2)

Guidance literature:

With 1H-imidazole; In N,N-dimethyl-formamide; at 20 ℃; for 5h;

DOI:10.1021/ol016792z DOI:10.1021/jo0484169

Reference yield: 97.0%

(((1R,4S)-4-(azidomethyl)cyclobut-2-enyl)methoxy)(tert-butyl)diphenylsilane + tert-butyl(diphenyl)(2-propynyloxy)silane (88159-06-2) → 4-(((tert-butyldiphenylsilyl)oxy)methyl)-1-(((1S,4R)-4-(((tert-butyldiphenylsilyl)oxy)methyl) cyclobut-2-en-1-yl)methyl)-1H-1,2,3-triazole

Guidance literature:

With copper(ll) sulfate pentahydrate; sodium L-ascorbate; In water; tert-butyl alcohol; at 20 ℃; for 12h; Inert atmosphere;

DOI:10.1002/bkcs.10270

Reference yield: 96.0%

chloroformic acid ethyl ester (541-41-3) + tert-butyl(diphenyl)(2-propynyloxy)silane (88159-06-2) → ethyl 4-[tert-butyl(diphenyl)silyl]oxybut-2-ynoate (916433-74-4)

Guidance literature:

tert-butyl(diphenyl)(2-propynyloxy)silane; With n-butyllithium; In tetrahydrofuran; Petroleum ether; at -78 ℃; for 1h;

chloroformic acid ethyl ester; In tetrahydrofuran; Petroleum ether; at 20 ℃; for 2h;

DOI:10.1021/ja0662671

upstream raw materials:

propargyl alcohol

tert-butylchlorodiphenylsilane

Downstream raw materials:

methyl (2Z)-6-<(tert-butyldiphenylsilyl)oxy>-2-hexen-4-yn-1-oate

4-isopropyl-3-<1-(tert-butyldiphenylsiloxy)-2-propen-3-yl>cyclohexanone

2-[3-(tert-Butyl-diphenyl-silanyloxy)-prop-1-ynyl]-1-(4-hydroxy-but-2-ynyl)-cyclopent-2-enol

c-3-<3-(tert-butyldiphenylsilyloxy)prop-1-ynyl>-1,4-bis-O-trimethylsilylcyclohexane-r-1,t-2,c-4-triol