(1R,1aβ,7aβ)-Decahydro-1,6β,6aβ-trimethyl-1α,2aα-methano-2aH-cyclopropa[b]naphthalene

Base Information

Chemical Name:(1R,1aβ,7aβ)-Decahydro-1,6β,6aβ-trimethyl-1α,2aα-methano-2aH-cyclopropa[b]naphthalene
CAS No.:26620-70-2
Molecular Formula:C₁₅H₂₄
Molecular Weight:204.356
Hs Code.:
Mol file:26620-70-2.mol

Synonyms:1,2a-Methano-2aH-cyclopropa[b]naphthalene,decahydro-1,6,6a-trimethyl-, (1R,1aR,2aR,6R,6aS,7aS)-(-)- (8CI);1,2a-Methano-2aH-cyclopropa[b]naphthalene, decahydro-1,6,6a-trimethyl-, [1R-(1a,1ab,2aa,6b,6ab,7ab)]-; (-)-Ishwarane; Ishwaran; Ishwarane

Suppliers and Price of (1R,1aβ,7aβ)-Decahydro-1,6β,6aβ-trimethyl-1α,2aα-methano-2aH-cyclopropa[b]naphthalene

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (1R,1aβ,7aβ)-Decahydro-1,6β,6aβ-trimethyl-1α,2aα-methano-2aH-cyclopropa[b]naphthalene

Chemical Property:

PSA：0.00000
LogP:4.24890

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Technology Process of (1R,1aβ,7aβ)-Decahydro-1,6β,6aβ-trimethyl-1α,2aα-methano-2aH-cyclopropa[b]naphthalene

There total 42 articles about (1R,1aβ,7aβ)-Decahydro-1,6β,6aβ-trimethyl-1α,2aα-methano-2aH-cyclopropa[b]naphthalene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 81.0%

: 22471-56-3,29126-71-4
(+/-)-ishwarone

: 26620-70-2,29126-70-3
(+/-)-ishwarane

Guidance literature:: With sodium; hydrazine hydrate; diethylene glycol; 1.) 180 deg C, 18 h, 2.) 210 deg C, 6 h;

Reference yield: 43.0%

: 74285-36-2
C₁₇H₂₈O₆S₂

: 26620-70-2,29126-70-3
(+/-)-ishwarane

Guidance literature:: With lithium aluminium tetrahydride; In diethyl ether; 1.) room temperature, 30 min, 2.) reflux, 30 min;

Reference yield:

: 66245-21-4
(3R,4R)-3-(4-Hydroxy-but-2-ynyl)-3,4-dimethyl-cyclohexanone

: 26620-70-2,29126-70-3
(+/-)-ishwarane

Guidance literature:: Multi-step reaction with 13 steps

1: 95 percent / hydrogen, quinoline / 5percent palladium on barium sulfate / ethanol / Ambient temperature

2: 96 percent / triethylamine / CH₂Cl₂ / 0.5 h / 0 °C

3: 1.56 g / potassium tert-butoxide / 2-methyl-propan-2-ol / 2.5 h / Ambient temperature

4: 85 percent / p-toluenesulfonic acid / benzene / 20 h / Heating

5: 64 percent / copper bronze / 1.5 h / 130 - 140 °C

6: 94 percent / lithium aluminum hydride / diethyl ether / 20 h / Ambient temperature

7: 84 percent / water, 4 N hydrochloric acid / acetone / 3 h / Ambient temperature

8: 370 mg / triethylamine / CH₂Cl₂ / 0.5 h / 0 °C

9: 242 mg / lithium chloride, hexamethylphosphoramide / diethyl ether

10: 141 mg / potassium tert-butoxide / tetrahydrofuran / 1.5 h / Ambient temperature

11: 88 percent / lithium triethylborohydride / tetrahydrofuran / 20 h / Ambient temperature

12: 73 percent / chromium trioxide, pyridinium hydrochloride / CH₂Cl₂ / 2 h / Ambient temperature

13: 81 percent / diethylene glycol, sodium, hydrazine hydrate / 1.) 180 deg C, 18 h, 2.) 210 deg C, 6 h

With quinoline; chromium(VI) oxide; hydrogenchloride; N,N,N,N,N,N-hexamethylphosphoric triamide; lithium aluminium tetrahydride; potassium tert-butylate; water; hydrogen; pyridine hydrochloride; sodium; copper; lithium triethylborohydride; toluene-4-sulfonic acid; hydrazine hydrate; triethylamine; lithium chloride; diethylene glycol; Pd-BaSO₄; In tetrahydrofuran; diethyl ether; ethanol; dichloromethane; acetone; tert-butyl alcohol; benzene;