{3-[(Trimethylsilyl)methyl]cyclohex-3-en-1-yl}acetaldehyde

Base Information

Chemical Name:{3-[(Trimethylsilyl)methyl]cyclohex-3-en-1-yl}acetaldehyde
CAS No.:88354-72-7
Molecular Formula:C₁₂H₂₂OSi
Molecular Weight:210.392
Hs Code.:
DSSTox Substance ID:DTXSID70526484

Synonyms:88354-72-7;DTXSID70526484;{3-[(Trimethylsilyl)methyl]cyclohex-3-en-1-yl}acetaldehyde

Suppliers and Price of {3-[(Trimethylsilyl)methyl]cyclohex-3-en-1-yl}acetaldehyde

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of {3-[(Trimethylsilyl)methyl]cyclohex-3-en-1-yl}acetaldehyde

Chemical Property:

Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:1
Rotatable Bond Count:4
Exact Mass:210.143991855
Heavy Atom Count:14
Complexity:225

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:C[Si](C)(C)CC1=CCCC(C1)CC=O

Technology Process of {3-[(Trimethylsilyl)methyl]cyclohex-3-en-1-yl}acetaldehyde

There total 7 articles about {3-[(Trimethylsilyl)methyl]cyclohex-3-en-1-yl}acetaldehyde which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 88354-77-2
5-[2-(tert-Butyl-dimethyl-silanyloxy)-ethyl]-1-trimethylsilanylmethyl-cyclohexene

: 88354-72-7
(3-Trimethylsilanylmethyl-cyclohex-3-enyl)-acetaldehyde

Guidance literature:: With tetrabutyl ammonium fluoride; dipyridine chromium trioxide; Yield given. Multistep reaction; 1.) 25 deg C; 2.) 25 deg C;
DOI:10.1002/hlca.19830660604

Reference yield:

: 930-68-7
cyclohexenone

: 88354-72-7
(3-Trimethylsilanylmethyl-cyclohex-3-enyl)-acetaldehyde

Guidance literature:: Multi-step reaction with 7 steps

1: 1.) LDA / 1.) -12 deg C

2: -70 °C

3: 1.) 60 deg C; 2.) HOAc, 85 deg C

4: KOt-amyl / 25 °C

5: 1.) LiAlH₄ / 1.) 0 deg C; 2.) imid, 25 deg C

6: Li / 0 °C

7: 1.) nBu₄N(+)F(-); 2.) CrO₃*2py / 1.) 25 deg C; 2.) 25 deg C

With lithium aluminium tetrahydride; tetrabutyl ammonium fluoride; lithium; dipyridine chromium trioxide; potassium 2-methylbutan-2-olate; lithium diisopropyl amide;
DOI:10.1002/hlca.19830660604

Reference yield:

: 92735-08-5,54725-71-2
3-trimethylsiloxycyclohexene

: 88354-72-7
(3-Trimethylsilanylmethyl-cyclohex-3-enyl)-acetaldehyde

Guidance literature:: Multi-step reaction with 6 steps

1: -70 °C

2: 1.) 60 deg C; 2.) HOAc, 85 deg C

3: KOt-amyl / 25 °C

4: 1.) LiAlH₄ / 1.) 0 deg C; 2.) imid, 25 deg C

5: Li / 0 °C

6: 1.) nBu₄N(+)F(-); 2.) CrO₃*2py / 1.) 25 deg C; 2.) 25 deg C

With lithium aluminium tetrahydride; tetrabutyl ammonium fluoride; lithium; dipyridine chromium trioxide; potassium 2-methylbutan-2-olate;
DOI:10.1002/hlca.19830660604