Ferrugine

Base Information

Chemical Name:Ferrugine
CAS No.:58471-11-7
Molecular Formula:C15H19NO
Molecular Weight:229.322
Hs Code.:

Synonyms:(+)-2alfa-benzoyltropane;(+)-endo-2-benzoyltropane;Ferrugine;(+)-ferrugine;(+)-2α-benzoyltropane;

Suppliers and Price of Ferrugine

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 3 raw suppliers

Chemical Property of Ferrugine

Chemical Property:

PSA：20.31000
LogP:2.68000

Purity/Quality:: 99% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Description A tropane alkaloid, this base has recently been discovered in the basic extract of Darlingia ferruginea where it occurs in the leaves and stems. The structure has been determined from chemical analysis and spectroscopic investigation.

Technology Process of Ferrugine

There total 5 articles about Ferrugine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 56.0%

: 1397719-01-5
(1S,2R,1'S,5S)-2-(1'-hydroxybenzyl)-tropane

: 58471-11-7
(+)-endo-2-benzoyltropane

Guidance literature:: With pyridine; Dess-Martin periodane; In dichloromethane; at 20 ℃; for 22h;
DOI:10.1016/j.tet.2012.07.061

Reference yield:

: (+)-(1S, 2R, 1'S)-2-(1'-hydroxybenzyl)-8-methyl-8-azabicyclo<3.2.1>octan-3-one

: 58471-11-7
(+)-endo-2-benzoyltropane

Guidance literature:: Multi-step reaction with 3 steps

1: titanium(IV) isopropylate / ethanol / 120 h / 20 °C

2: diisobutylaluminium hydride / hexane; dichloromethane / 96 h / 0 °C

3: pyridine; Dess-Martin periodane / dichloromethane / 22 h / 20 °C

With pyridine; titanium(IV) isopropylate; diisobutylaluminium hydride; Dess-Martin periodane; In ethanol; hexane; dichloromethane;
DOI:10.1016/j.tet.2012.07.061

Reference yield:

: (1S,2S,1'S,5R)-2-(1'-hydroxybenzyl)-tropinone N'-tosylhydrazone

: 58471-11-7
(+)-endo-2-benzoyltropane

Guidance literature:: Multi-step reaction with 2 steps

1: diisobutylaluminium hydride / hexane; dichloromethane / 96 h / 0 °C

2: pyridine; Dess-Martin periodane / dichloromethane / 22 h / 20 °C

With pyridine; diisobutylaluminium hydride; Dess-Martin periodane; In hexane; dichloromethane;
DOI:10.1016/j.tet.2012.07.061