Dimethyl [(benzoyloxy)methylidene]propanedioate

Base Information

Chemical Name:Dimethyl [(benzoyloxy)methylidene]propanedioate
CAS No.:88456-31-9
Molecular Formula:C₁₃H₁₂O₆
Molecular Weight:264.235
Hs Code.:
DSSTox Substance ID:DTXSID00559806

Synonyms:88456-31-9;Dimethyl [(benzoyloxy)methylidene]propanedioate;DTXSID00559806

Suppliers and Price of Dimethyl [(benzoyloxy)methylidene]propanedioate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

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Chemical Property of Dimethyl [(benzoyloxy)methylidene]propanedioate

Chemical Property:

XLogP3:1.8
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:6
Rotatable Bond Count:7
Exact Mass:264.06338810
Heavy Atom Count:19
Complexity:361

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:COC(=O)C(=COC(=O)C1=CC=CC=C1)C(=O)OC

Technology Process of Dimethyl [(benzoyloxy)methylidene]propanedioate

There total 1 articles about Dimethyl [(benzoyloxy)methylidene]propanedioate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 27931-91-5
hydroxymethylenemalonic acid dimethyl ester

: 98-88-4
benzoyl chloride

: 88456-31-9
dimethyl ((benzyloxy)methylene)malonate

Guidance literature:: With triethylamine; In diethyl ether; for 1h;
DOI:10.1021/jo00277a039

Reference yield: 88.0%

: 53973-73-2
sodium p-nitrophenyl selenolate

: 88456-31-9
dimethyl ((benzyloxy)methylene)malonate

: 121865-40-5
2,2-bis(methoxycarbonyl)vinyl p-nitrophenyl selenide

Guidance literature:: In methanol; dichloromethane;
DOI:10.1021/jo00277a039

Reference yield:

: 88456-31-9
dimethyl ((benzyloxy)methylene)malonate

: 121865-49-4
3,3-bis(methoxycarbonyl)-1-tert-butylallyl p-nitrophenyl selenide

Guidance literature:: Multi-step reaction with 2 steps

1: 88 percent / CH₂Cl₂; methanol

2: 90 percent / CH₂Cl₂; diethyl ether / -10 °C

In methanol; diethyl ether; dichloromethane;
DOI:10.1021/jo00277a039