Iodotrifluoroethylene

Base Information

• Chemical Name: Iodotrifluoroethylene
• CAS No.: 359-37-5
• Molecular Formula: C2F3I
• Molecular Weight: 207.922
• Hs Code.: 2903799090
• European Community (EC) Number: 206-629-9
• NSC Number: 174158
• UNII: LKV2XT37FH
• DSSTox Substance ID: DTXSID0073166
• Nikkaji Number: J28.338J
• Wikipedia: Iodotrifluoroethylene
• Wikidata: Q11395726
• Mol file: 359-37-5.mol

Synonyms:Iodotrifluoroethylene;359-37-5;Trifluoroiodoethylene;Ethene, trifluoroiodo-;1,1,2-trifluoro-2-iodoethene;iodotrifluoroethene;LKV2XT37FH;EINECS 206-629-9;NSC-174158;C2F3I;1,1,2-Trifluoro-2-iodoethylene;trifluorovinyl iodide;Perfluorovinyl iodide;UNII-LKV2XT37FH;SCHEMBL52382;DTXSID0073166;C2-F3-I;Ethene, 1,1,2-trifluoro-2-iodo-;MFCD00042137;NSC174158;AKOS015853676;NSC 174158;1,1,2-tris(fluoranyl)-2-iodanyl-ethene;AS-57525;FT-0627273;A823052;Q11395726

Chemical Property of Iodotrifluoroethylene

Chemical Property:

• Vapor Pressure: 636mmHg at 25°C
• Refractive Index: 1.4143
• Boiling Point: 30 °C at 760 mmHg
• Flash Point: 30°C
• PSA: 0.00000
• Density: 2.311 g/cm³
• LogP: 2.45650
• Storage Temp.: Keep Cold
• Sensitive.: Light Sensitive
• XLogP3: 1.7
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 3
• Rotatable Bond Count: 0
• Exact Mass: 207.89968
• Heavy Atom Count: 6
• Complexity: 72.9

Purity/Quality:

99%, ^*data from raw suppliers

Iodotrifluoroethylene ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xi
• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26-36/37/39

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C(=C(F)I)(F)F
• Uses: Iodotrifluoroethylene is used in preparation method of peroxide-curable fluorine-containing elastomer.

Technology Process of Iodotrifluoroethylene

There total 13 articles about Iodotrifluoroethylene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.0%

1,2,2-trifluorovinyl tri-n-butylstannane (1426-65-9) → Iodotrifluoroethylene (359-37-5)

Guidance literature:

With iodine;

DOI:10.1016/j.jfluchem.2009.07.009

Reference yield: 69.0%

1-bromo-1,2,2-trifluoroethene (598-73-2,55157-25-0) → Iodotrifluoroethylene (359-37-5)

Guidance literature:

1-bromo-1,2,2-trifluoroethene; With zinc;

With iodine; at 5 - 20 ℃;

DOI:10.1016/S0022-1139(02)00246-4

Reference yield: 59.0%

1,1,1,2-tetrafluoroethane (811-97-2) → Iodotrifluoroethylene (359-37-5)

Guidance literature:

With n-butyllithium; iodine; In diethyl ether; hexane; 1.) -78 deg C;

DOI:10.1039/cc9960000049

upstream raw materials:

1-chloro-2-iodo-1,1,2-trifluoroethane

1,2-diiodotetrafluoroethane

trifluorovinyllithium

1,1,1,2-tetrafluoroethane

Downstream raw materials:

1,1,2,4-tetrafluoro-4-iodo-but-1-ene

3-chloro-1,1,2,4,4-pentafluoro-4-iodo-but-1-ene

Hexafluor-4,4-diiod-buten-(1)

hexafluorocyclobut-1-ene

Refernces

• 1、 Ramachandran, P. Veeraraghavan,Reddy, G. Venkat. "Preparative-scale one-pot syntheses of hexafluoro-1,3-butadiene". . p. 443 - 446. Retrieved 2008.
• 2、 Frohn,Bardin. "Trifluorovinylxenon(II) tetrafluoroborate". . p. 919 - 920. Retrieved 1999.
• 3、 Frohn, Hermann-Josef,Bardin, Vadim V.. "Reaction of organylxenonium(II)salts, [RXe][Y], with organyl iodides, R'I, in anhydrous HF: Scope and limitation of a new synthetic approach to iodonium salts, [RR'I][Y]". experimental part. p. 2616 - 2620. Retrieved 2012/05/31.