Benzeneacetaldehyde, 3-(1,3-dioxolan-2-yl)-

Base Information

Chemical Name:Benzeneacetaldehyde, 3-(1,3-dioxolan-2-yl)-
CAS No.:88679-83-8
Molecular Formula:C11H12O3
Molecular Weight:192.214
Hs Code.:
DSSTox Substance ID:DTXSID90473744

Synonyms:Benzeneacetaldehyde, 3-(1,3-dioxolan-2-yl)-;88679-83-8;SCHEMBL9262464;DTXSID90473744;FT-0715253

Suppliers and Price of Benzeneacetaldehyde, 3-(1,3-dioxolan-2-yl)-

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 2 raw suppliers

Chemical Property of Benzeneacetaldehyde, 3-(1,3-dioxolan-2-yl)-

Chemical Property:

XLogP3:0.7
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:3
Rotatable Bond Count:3
Exact Mass:192.078644241
Heavy Atom Count:14
Complexity:187

Purity/Quality:: 85.0-99.8% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:C1COC(O1)C2=CC=CC(=C2)CC=O

Technology Process of Benzeneacetaldehyde, 3-(1,3-dioxolan-2-yl)-

There total 6 articles about Benzeneacetaldehyde, 3-(1,3-dioxolan-2-yl)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 17789-14-9
3-(1,3-dioxolan-2-yl)-phenylbromide

: 88679-82-7
3-Allylbenzaldehydeethylene ketal

: 7787-70-4
copper(I) bromide

: 88679-83-8
2-[3-(1,3-dioxolan-2-yl)phenyl]acetaldehyde

Guidance literature:: With acetic acid; In dichloromethane; water;

Reference yield:

: 115104-32-0
2-<3-(2-hydroxyethyl)phenyl>-1,3-dioxolane

: 88679-83-8
2-[3-(1,3-dioxolan-2-yl)phenyl]acetaldehyde

Guidance literature:: With pyridine; chromium(VI) oxide; Celite; In dichloromethane; for 0.333333h;
DOI:10.1021/jm00099a011

Reference yield:

: 626-19-7
Isophthalaldehyde

: 88679-83-8
2-[3-(1,3-dioxolan-2-yl)phenyl]acetaldehyde

Guidance literature:: Multi-step reaction with 4 steps

1: 1.) n-BuLi / 1.) THF, hexane, 0 deg C, 30 min, 2.) THF, hexane, a) from -50 deg C to RT, b) RT, 3.5 h

2: 92 percent / p-TsOH*H₂O / benzene / 6 h / Heating

3: 60 percent / borane-tetrahydrofuran complex, 3 N aq. NaOH, 30percent aq. H₂O₂ / tetrahydrofuran / 0.5 h / Ambient temperature

4: 0.85 g / pyridine, chromium trioxide, Celite / CH₂Cl₂ / 0.33 h

With pyridine; chromium(VI) oxide; sodium hydroxide; n-butyllithium; borane-THF; Celite; dihydrogen peroxide; toluene-4-sulfonic acid; In tetrahydrofuran; dichloromethane; benzene;
DOI:10.1021/jm00099a011