Copper(1+);bromide

Base Information

• Chemical Name: Copper(1+);bromide
• CAS No.: 7787-70-4
• Molecular Formula: CuBr
• Molecular Weight: 143.45
• Hs Code.: 28275900
• UNII: R8V209A5G0
• Nikkaji Number: J95.203F
• Mol file: 7787-70-4.mol

Synonyms:copper(1+);bromide;CUPROUS BROMIDE [MI];COPPER(I) BROMIDE [HSDB];C2161;FT-0624140;J-520122

Chemical Property of Copper(1+);bromide

Chemical Property:

• Appearance/Colour: white powder or crystal
• Melting Point: 492 °C, 765 K, 918 °F
• Boiling Point: 1345 °C, 1618 K, 2453 °F
• Flash Point: 1345°C
• PSA: 0.00000
• Density: 4.71 g/mL at 25 °C(lit.)
• LogP: 0.84310
• Storage Temp.: Keep in dark place,Inert atmosphere,Room temperature
• Sensitive.: Air Sensitive
• Water Solubility.: Soluble in hydrogen bromide, hydrochloric acid, and ammonium hydroxide. Slightly soluble in water. Insoluble in acetone.
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 0
• Exact Mass: 141.84793
• Heavy Atom Count: 2
• Complexity: 0

Purity/Quality:

98% ^*data from raw suppliers

Copper(I) bromide ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xi
• Hazard Codes: Xi
• Statements: 36/37/38-22
• Safety Statements: 22-24/25-26-37/39

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: [Cu+].[Br-]
• Uses: Copper bromide is also known as cupric bromide, this substance was made by double decomposition when mixing aqueous solutions of copper sulfate and potassium bromide. This greenish blue solution was used as the bleaching step for intensifying collodion and gelatin negatives. It is used as effective catalyst for tetrahydropyranylation of alcohols. It can also be used in combination with palladium in catalytic synthesis of 3-haloindoles through annulation process. It is widely used in the synthesis of organic fine chemicals. The compound is widely used in the synthesis of organic compounds. It is also useful for copper-mediated coupling reactions. A silica gel support copper bromide hexa methyltriethylenetetramine complex has shown useful application for the atom transfer radical polymerization of methyl methacrylate in toluene.

Technology Process of Copper(1+);bromide

There total 126 articles about Copper(1+);bromide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.0%

copper(ll) bromide (7789-45-9) → copper(I) bromide (7787-70-4)

Guidance literature:

With sodium sulfite; In water; for 0.416667h;

DOI:10.15227/orgsyn.084.0001

Reference yield: 87.0%

(η5-C5H5)(CO)2FeCH2CH2C(CH3)3 + copper(ll) bromide (7789-45-9) → dicarbonylcyclopentadienylbromoiron(II) + copper(I) bromide (7787-70-4)

Guidance literature:

In dichloromethane; byproducts: Me3CCh2CH2Br; room temp. (N2); not isolated, detected spectroscopically;

Reference yield: 83.0%

dicarbonyl(η5-cyclopentadienyl)iron(II)(ethyl) + copper(ll) bromide (7789-45-9) → dicarbonylcyclopentadienylbromoiron(II) + copper(I) bromide (7787-70-4)

Guidance literature:

In dichloromethane; byproducts: EtBr; room temp.(N2); not isolated, detected spectroscopically;

upstream raw materials:

copper(ll) bromide

copper(II) sulfate

sodium bromide

iodine

Downstream raw materials:

1-bromo-3-ethylbenzene

2,3-dibromo-5-methylbenzoic acid

(+/-)-{4-[1-(4-chlorophenyl)ethyl]-7-fluoro-5-(methanesulfonyl)-1,2,3,4-tetrahydrocyclopenta[b]indol-3-yl}acetic acid

2-(4-Hydroxy-phenyl)-4-methoxy-benzofuran-5-ol

Refernces

Luminescent monomeric and polymeric cuprous halide complexes with 1,2-bis(3,5-dimethylpyrazol-1-ylmethyl)-benzene as ligand

10.1016/j.inoche.2015.06.014

The research focuses on the synthesis and characterization of luminescent monomeric and polymeric copper(I) halides complexes with 1,2-bis(3,5-dimethylpyrazol-1-ylmethyl)-benzene (dpb) as a ligand. The experiments involved reacting copper(I) bromide and copper(I) iodide with equimolar amounts of dpb in dry toluene to yield the mononuclear complex [CuBr(dpb)] (F2) and the polymeric compound [Cu2I2(dpb)]n (F1), respectively. The complexes were characterized by elemental analysis, 1H NMR spectroscopy, and MALDI-TOF spectroscopy, with crystal structures determined by single-crystal X-ray diffraction methods. The complexes were further analyzed for their UV–vis absorption spectra in CH2Cl2 solution and their photoluminescence properties in the solid state at ambient temperature. Thermogravimetric analysis was also conducted to assess their thermal stability.

Design and synthesis of cyclic depsipeptides containing triazole (CDPT) rings

10.1039/c3ra45100c

The research focuses on the design and synthesis of cyclic depsipeptides containing triazole (CDPT) rings using click chemistry. The key chemicals involved in this research include Boc-protected amino acids such as Boc–Leu–OH and Boc–Phe–OH, propargyl alcohol, 1,10-carbonyl diimidazole (CDI), trifluoroacetic acid (TFA), 3-azido propionic acid, EDC$HCl, HOBt, and copper(I) bromide. These chemicals play crucial roles in the synthesis process. For instance, CDI is used for esterification, TFA for deprotection, and EDC$HCl/HOBt for peptide coupling. Copper(I) bromide is essential for the Cu-catalyzed alkyne–azide cycloaddition, which forms the triazole ring. The synthesis involves several steps, including the formation of propargyl ester containing dipeptides, linear azido–alkyne depsipeptides, and finally the desired cyclic depsipeptides containing triazole rings. The methodology was optimized and applied to synthesize a library of CDPTs, with yields ranging from 58% to 64%. The synthesized compounds were characterized using various techniques such as 1H-NMR, 13C-NMR, FT-IR, ESI-MS, and HPLC, and the crystal structure of one of the compounds was determined by X-ray diffraction.