1,3,5-TRIBENZOYLBENZENE

Base Information

• Chemical Name: 1,3,5-TRIBENZOYLBENZENE
• CAS No.: 25871-69-6
• Molecular Formula: C27H18O3
• Molecular Weight: 390.438
• Hs Code.: 2914399090
• Mol file: 25871-69-6.mol

Synonyms:Benzene,1,3,5-tribenzoyl- (6CI,7CI,8CI);1,3,5-Tribenzoylbenzene;Benzene-1,3,5-triyltris(phenylmethanone);

Chemical Property of 1,3,5-TRIBENZOYLBENZENE

Chemical Property:

• Vapor Pressure: 4.14E-14mmHg at 25°C
• Melting Point: 118-119 °C
• Refractive Index: 1.632
• Boiling Point: 594.7 °C at 760 mmHg
• Flash Point: 254.6 °C
• PSA: 51.21000
• Density: 1.205 g/cm³
• LogP: 5.37960
• Storage Temp.: Inert atmosphere,Room Temperature

Purity/Quality:

99% ^*data from raw suppliers

1,3,5-Tribenzoylbenzene ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xi
• Hazard Codes: Xi
• Safety Statements: S22:Do not inhale dust.; S24/25:Avoid contact with skin and eyes.

MSDS Files:

SDS file from LookChem

Useful:

• Uses: It is used as a ligand in the synthesis and characterization of three new coordination polymers from the tritopic ligand.

Technology Process of 1,3,5-TRIBENZOYLBENZENE

There total 59 articles about 1,3,5-TRIBENZOYLBENZENE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

1-phenyl-3-dimethylaminoprop-2-enone (1201-93-0) → 1,3,5-tribenzoylbenzene (25871-69-6)

Guidance literature:

With pyridine; acetic acid; for 2h; Heating;

DOI:10.1055/s-2003-41056

Reference yield: 98.0%

phenyl propargyl ketone (3623-15-2) → 1,3,5-tribenzoylbenzene (25871-69-6)

Guidance literature:

dmap; acetylacetone; In dichloromethane; at 20 ℃; for 2h;

DOI:10.1055/s-2007-967997

Reference yield: 95.0%

(E)-3-(N,N-dimethylamino)-1-phenyl-2-propen-1-one (1131-80-2,1201-93-0,31919-75-2) → 1,3,5-tribenzoylbenzene (25871-69-6)

Guidance literature:

With hydrogenchloride; In acetonitrile; Heating;

DOI:10.1246/cl.1984.1419

upstream raw materials:

benzoic acid methyl ester

1,3,5-tris-(α-hydroxy-benzyl)-benzene

benzoylacetaldehyde sodium salt

acetic acid

Downstream raw materials:

1,3,5-tris(1-phenylethenyl)benzene

1,3,5-trisbenzoylbenzene thiosemicarbazone

C₆H₃(CLi(CH₂C₄H₉)C₆H₅)3

1-[3,5-bis(1-hydroxy-1-phenylprop-2-ynyl)phenyl]1-phenylpropynol

Refernces

• 1、 Doll, Julianna S.,Eichelmann, Robert,Hertwig, Leif E.,Bender, Thilo,Kohler, Vincenz J.,Bill, Eckhard,Wadepohl, Hubert,Ro?ca, Drago?-Adrian. "Iron-catalyzed trimerization of terminal alkynes enabled by pyrimidinediimine ligands: A regioselective method for the synthesis of 1,3,5-substituted arenes". . p. 5593 - 5600. Retrieved 2021/05/31.
• 2、 Fang, Guichun,Liu, Jianquan,Shang, Weidong,Liu, Qun,Bi, Xihe. "Silver(I)-Promoted Radical Sulfonylation of Allyl/Propargyl Alcohols: Efficient Synthesis of γ-Keto Sulfones". . p. 3334 - 3338. Retrieved 2016/12/14.