Dichloro(hydrido)iridium;triphenylphosphane

Base Information

Chemical Name:Dichloro(hydrido)iridium;triphenylphosphane
CAS No.:16971-01-0
Molecular Formula:C₅₄H₄₆Cl₂IrP₃
Molecular Weight:1051.01
Hs Code.:
Mol file:16971-01-0.mol

Synonyms:

Suppliers and Price of Dichloro(hydrido)iridium;triphenylphosphane

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
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price

Total 11 raw suppliers

Chemical Property of Dichloro(hydrido)iridium;triphenylphosphane

Chemical Property:

Vapor Pressure:4.74E-05mmHg at 25°C
Boiling Point:360°Cat760mmHg
Flash Point:181.7°C
PSA：40.77000
Density:g/cm³
LogP:12.27260
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:0
Rotatable Bond Count:9
Exact Mass:1050.18187
Heavy Atom Count:60
Complexity:204

Purity/Quality:: 99%, ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=CC=CC=C3.C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=CC=CC=C3.C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=CC=CC=C3.Cl[IrH]Cl

Technology Process of Dichloro(hydrido)iridium;triphenylphosphane

There total 5 articles about Dichloro(hydrido)iridium;triphenylphosphane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

: iridium(III) chloride trihydrate

: 603-35-0
triphenylphosphine

: 67-63-0,8013-70-5
isopropyl alcohol

: 16971-01-0,24846-85-3,28060-70-0,77448-67-0
mer-IrHCl₂(PPh₃)3

Guidance literature:: In isopropyl alcohol; byproducts: HCl, acetone, H2O; under Ar, standard Schlenk techniques; i-PrOH added to IrCl3*3H2O and P(i-Pr)3 (molar ratio 1:6); refluxed for 1.5 d; cooled to room temp.; extd. with Et2O; filtered; ppt. washed with Et2O; dried under vac.; elem. anal.; mainly or exclusively cis,mer isomer obtained;
DOI:10.1021/ic0255149

Reference yield: 77.0%

: 7647-01-0,15364-23-5
hydrogenchloride

: iridium(III) chloride trihydrate

: 603-35-0
triphenylphosphine

: 16971-01-0,24846-85-3,28060-70-0,77448-67-0
mer-IrHCl₂(PPh₃)3

Guidance literature:: In ethanol; Ar-atmosphere; addn. of excess concd. HCl to IrCl3 (stirring), refluxingfor 5 h, cooling to room temp., addn. of 3 equiv. PPh3, refluxing for 1 2 h (pptn.); cooling to 0°C, collection (filtration; in air), washing (cold EtOH), drying (vac.); contg unspecified impurity;
DOI:10.1021/ic950438d

Reference yield: 35.0%

: ammonium hexachloroiridium(IV)

: 603-35-0
triphenylphosphine

: 16971-01-0,24846-85-3,28060-70-0,77448-67-0
mer-IrHCl₂(PPh₃)3

Guidance literature:: In isopropyl alcohol; using Schlenk techniques; reflux of mixt. of (IrCl6)(NH4)2 and PPh3 in isopropanol for 3 ds; cooling to ambient temp., extn. with 3 portions of Et2O; combining of 3 fractions; filtration, washing with ether; drying in vac., recrystn. from CH2Cl2/hexane;
DOI:10.1021/om900655k