TRIS(3-METHOXYPROPYL)PHOSPHINE

Base Information

• Chemical Name: TRIS(3-METHOXYPROPYL)PHOSPHINE
• CAS No.: 83622-85-9
• Molecular Formula: C₁₂H₂₇O₃P
• Molecular Weight: 250.318
• Hs Code.: 2909199090
• Mol file: 83622-85-9.mol

Synonyms:MP 1515;Trifosmin; Tris(3-methoxypropyl)phosphine

Chemical Property of TRIS(3-METHOXYPROPYL)PHOSPHINE

Chemical Property:

• Vapor Pressure: 0.000959mmHg at 25°C
• Boiling Point: 312.7°C at 760 mmHg
• Flash Point: 173.7°C
• PSA: 41.28000
• LogP: 2.57780

Purity/Quality:

95+% ^*data from raw suppliers

TRIFOSMIN 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of TRIS(3-METHOXYPROPYL)PHOSPHINE

There total 2 articles about TRIS(3-METHOXYPROPYL)PHOSPHINE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

dichloroethoxy-phosphonite + 1-Chloro-3-methoxypropane (36215-07-3) → tris(3-methoxy-1-propyl)phosphine (83622-85-9)

Guidance literature:

Reference yield:

1-Chloro-3-methoxypropane (36215-07-3) → tris(3-methoxy-1-propyl)phosphine (83622-85-9)

Guidance literature:

With magnesium; phosphorus trichloride; Multistep reaction;

DOI:10.1246/cl.1982.977

Reference yield: 74.0%

C20H30ClN2O5Re + tris(3-methoxy-1-propyl)phosphine (83622-85-9) → C44H84N2O10P2Re(1+)*Cl(1-)

Guidance literature:

In ethanol; at 105 ℃; for 0.1h; under 12751.3 Torr; Inert atmosphere; Schlenk technique; Microwave irradiation;

DOI:10.1021/acs.inorgchem.8b02156

upstream raw materials:

1-Chloro-3-methoxypropane

Refernces

• 1、 Okano, Tamon,Yamamoto, Manabu,Noguchi, Takeo,Konishi, Hisatoshi. "TRANSITION METAL PHOSPHINE COMPLEXES POSSESING A PHASE TRANSFER FUNCTION. PREPARATION AND PROPERTIES OF POLYETHER-SUBSTITUED PHOSPHINES AND THEIR PALLADIUM COMPLEXES". . p. 977 - 980. Retrieved 2007/10/02.