Propanedioic acid, (phenylseleno)-, diethyl ester

Base Information

Chemical Name:Propanedioic acid, (phenylseleno)-, diethyl ester
CAS No.:89046-37-7
Molecular Formula:C13H16O4Se
Molecular Weight:315.228
Hs Code.:
DSSTox Substance ID:DTXSID90464894
Nikkaji Number:J545.926E
Wikidata:Q82290435

Synonyms:Propanedioic acid, (phenylseleno)-, diethyl ester;89046-37-7;DTXSID90464894

Suppliers and Price of Propanedioic acid, (phenylseleno)-, diethyl ester

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 1 raw suppliers

Chemical Property of Propanedioic acid, (phenylseleno)-, diethyl ester

Chemical Property:

Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:4
Rotatable Bond Count:8
Exact Mass:316.02138
Heavy Atom Count:18
Complexity:256

Purity/Quality:: 85.0-99.8% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CCOC(=O)C(C(=O)OCC)[Se]C1=CC=CC=C1

Technology Process of Propanedioic acid, (phenylseleno)-, diethyl ester

There total 3 articles about Propanedioic acid, (phenylseleno)-, diethyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 65.0%

: 1666-13-3
diphenyl diselenide

: 685-87-0
Diethyl 2-bromomalonate

: 89046-37-7
diethyl α-(phenylseleno) malonate

Guidance literature:: With dipotassium hydrogenphosphate; acridine orange hemi(zinc chloride) salt; In acetonitrile; at 20 ℃; for 24h; Sealed tube; Inert atmosphere; UV-irradiation;
DOI:10.1002/adsc.202101053

Reference yield: 58.0%

: 5256-74-6
1,3-diethyl 2-diazopropanedioate

: 112238-64-9
phenylselenyl triflate

: 89046-37-7
diethyl α-(phenylseleno) malonate

: diethyl 2,2-di(phenylseleno)propanedioate

Guidance literature:: In dichloromethane; at 0 ℃; for 0.0833333h; Further Variations:; Temperatures; Product distribution;

Reference yield:

: 105-53-3
diethyl malonate

: 89046-37-7
diethyl α-(phenylseleno) malonate

Guidance literature:: Multi-step reaction with 2 steps

1: copper(ll) bromide / ethyl acetate / 20 °C

2: acridine orange hemi(zinc chloride) salt; dipotassium hydrogenphosphate / acetonitrile / 24 h / 20 °C / Sealed tube; Inert atmosphere; UV-irradiation

With dipotassium hydrogenphosphate; acridine orange hemi(zinc chloride) salt; copper(ll) bromide; In ethyl acetate; acetonitrile;
DOI:10.1002/adsc.202101053