4-Nitrobenzyltriphenylphosphonium chloride

Base Information

• Chemical Name: 4-Nitrobenzyltriphenylphosphonium chloride
• CAS No.: 1530-42-3
• Molecular Formula: C25H21 N O2 P . Cl
• Molecular Weight: 433.874
• DSSTox Substance ID: DTXSID20934651
• NSC Number: 116691
• Mol file: 1530-42-3.mol

Synonyms:1530-42-3;NSC116691;4-nitrobenzyltriphenylphosphonium chloride;SCHEMBL5427779;SCHEMBL11511018;DTXSID20934651;WRXNAQRUFGEKSK-UHFFFAOYSA-M;NSC-116691;p-nitrobenzyltriphenylphosphonium chloride;[(4-Nitrophenyl)methyl](triphenyl)phosphanium chloride

Chemical Property of 4-Nitrobenzyltriphenylphosphonium chloride

Chemical Property:

• Boiling Point: °Cat760mmHg
• Flash Point: °C
• Density: g/cm³
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 3
• Rotatable Bond Count: 5
• Exact Mass: 433.0998436
• Heavy Atom Count: 30
• Complexity: 462

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC=C(C=C1)[P+](CC2=CC=C(C=C2)[N+](=O)[O-])(C3=CC=CC=C3)C4=CC=CC=C4.[Cl-]

Technology Process of 4-Nitrobenzyltriphenylphosphonium chloride

There total 2 articles about 4-Nitrobenzyltriphenylphosphonium chloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

4-nitrobenzyl chloride (100-14-1) + triphenylphosphine (603-35-0) → (4-nitrobenzyl)triphenylphosphonium chloride (1530-42-3)

Guidance literature:

In para-xylene; at 150 ℃; for 2h;

DOI:10.1016/j.dyepig.2015.12.031

Reference yield:

→ (4-nitrobenzyl)triphenylphosphonium chloride (1530-42-3)

Guidance literature:

Reference yield: 82.0%

4-(diphenylamino)benzaldehyde (4181-05-9) + (4-nitrobenzyl)triphenylphosphonium chloride (1530-42-3) → 4-(2-(4-nitrophenyl)ethenyl)-N,N-diphenylaniline (142677-07-4)

Guidance literature:

(4-nitrobenzyl)triphenylphosphonium chloride; With potassium tert-butylate; In tetrahydrofuran; for 1h; Cooling with ice;

4-(diphenylamino)benzaldehyde; In tetrahydrofuran; at 70 ℃;

DOI:10.1016/j.dyepig.2015.12.031

upstream raw materials:

4-nitrobenzyl chloride

triphenylphosphine

Downstream raw materials:

3-methyl-4-(4-nitro-cis-styryl)-sydnone

3-methyl-4-(4-nitro-trans-styryl)-sydnone

3-(4-methoxy-phenyl)-4-(4-nitro-cis-styryl)-sydnone

3-(4-methoxy-phenyl)-4-(4-nitro-trans-styryl)-sydnone