628-08-0

Basic information

• Product Name: TRANS-2-BUTENYL ACETATE
• Synonyms: CROTYL ACETATE;TRANS-2-BUTENYL ACETATE;(2E)-2-Butenyl acetate;Acetic acid trans-2-butenyl ester;2-Butene-1-ol acetate;2-Butenyl acetate;Acetic acid 2-butenyl ester;WNHXJHGRIHUOTG-UHFFFAOYSA-N
• CAS NO: 628-08-0
• Molecular Formula: C₆H₁₀O₂
• Molecular Weight: 114.14
• EINECS: -0
• Mol File: 628-08-0.mol
• Article Data: 2

Chemical Properties

• Melting Point: 37.22°C (estimate)
• Boiling Point: 128-130°C
• Flash Point: 31°C
• Appearance: /
• Density: 0,919 g/cm3
• Vapor Pressure: 9.04mmHg at 25°C
• Refractive Index: 1.4200
• BRN: 1720994
• CAS DataBase Reference: TRANS-2-BUTENYL ACETATE(CAS DataBase Reference)
• NIST Chemistry Reference: TRANS-2-BUTENYL ACETATE(628-08-0)
• EPA Substance Registry System: TRANS-2-BUTENYL ACETATE(628-08-0)

Safety Data

• Statements: 10
• Safety Statements: 16-23
• RIDADR: 3272
• HazardClass: 3
• PackingGroup: III
• Hazardous Substances Data: 628-08-0(Hazardous Substances Data)

Usage

InChI:InChI=1/C6H10O2/c1-3-4-5-8-6(2)7/h3-4H,5H2,1-2H3/b4-3+

Upstream product

• 64-19-7 acetic acid 
• 106-99-0 buta-1,3-diene 
• 614-45-9 tert-Butyl peroxybenzoate 
• 624-64-6 trans-2-Butene 

Downstream Products

• 135019-04-4 2-(But-2-enyl)-2-isopropylcyclohexane-1,3-dione 
• 133967-39-2 (E)-methyl 2-phenylhex-4-enoate 
• 133967-40-5 3-Methyl-2-phenyl-pent-4-enoic acid methyl ester 
• 18435-35-3 3-methyl-non-1-ene 
• 20063-97-2 2-decene 
• 92-52-4 biphenyl 
• 934-10-1 3-phenylbut-1-ene 
• 1560-06-1 1-phenyl-2-butene 
• 6117-91-5 (E/Z)-2-buten-1-ol 
• 71-36-3 butan-1-ol 
• 584-03-2 1,2-dihydroxybutane 
• 598-32-3 2-hydroxy-3-butene 
• 18826-95-4 1.3-butanediol 
• 513-85-9 2.3-butanediol 

Relevant articles and documents

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PROCESS FOR MAKING BUTENYL ESTERS FROM BUTADIENE

A process for making a butenyl ester from butadiene by reacting butadiene or a hydrocarbon fraction containing butadiene with a saturated aliphatic monocarboxylic acid, wherein the catalyst is rhenium (VII) oxide or an organic sulphonic acid containing at least (2) sulphonic acid groups per molecule wherein the ratio of the number of carbon atoms to the number of sulphonic acid groups in the organic sulphonic acid is in the range 1 : 1 to 1 : 0.15. Preferred catalysts are organic disulphonic acids for example ethane-1,2-disulphonic acid. The process can be used for making unsaturated esters, or, by hydrogenation of the product, for making saturated esters such as for example butyl acetate. Catalyst can be purified and recycled to the reactor.