1,4-Dimethoxy-2-[(E)-1-methyl-1-propenyl]benzene

Base Information

Chemical Name:1,4-Dimethoxy-2-[(E)-1-methyl-1-propenyl]benzene
CAS No.:89556-66-1
Molecular Formula:C₁₂H₁₆O₂
Molecular Weight:192.258
Hs Code.:
DSSTox Substance ID:DTXSID501215782
Nikkaji Number:J694.126E,J694.127C

Synonyms:DTXSID501215782;1,4-Dimethoxy-2-[(E)-1-methyl-1-propenyl]benzene;1,4-Dimethoxy-2-[(Z)-1-methyl-1-propenyl]benzene;BENZENE, 1,4-DIMETHOXY-2-(1-METHYL-1-PROPENYL)-, (Z)-;89556-66-1

Suppliers and Price of 1,4-Dimethoxy-2-[(E)-1-methyl-1-propenyl]benzene

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of 1,4-Dimethoxy-2-[(E)-1-methyl-1-propenyl]benzene

Chemical Property:

XLogP3:3.5
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:2
Rotatable Bond Count:3
Exact Mass:192.115029749
Heavy Atom Count:14
Complexity:199

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CC=C(C)C1=C(C=CC(=C1)OC)OC
Isomeric SMILES:C/C=C(/C)\C1=C(C=CC(=C1)OC)OC

Technology Process of 1,4-Dimethoxy-2-[(E)-1-methyl-1-propenyl]benzene

There total 1 articles about 1,4-Dimethoxy-2-[(E)-1-methyl-1-propenyl]benzene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 1201-38-3
2',5'-dimethoxyacetophenone

: 1530-32-1
ethyltriphenylphosphonium bromide

: 89556-66-1
(Z)-1,4-dimethoxy-2-(1-methyl-1-propenyl)benzene

: (E)-1,4-dimethoxy-2-(1-methyl-1-propenyl)benzene

Guidance literature:: With n-butyllithium; Yield given. Multistep reaction. Yields of byproduct given; 1.) THF, hexane, 20 min, 2.) THF, hexane, RT, 61 h;
DOI:10.1021/jm00018a019

Reference yield:

: 89556-66-1
(Z)-1,4-dimethoxy-2-(1-methyl-1-propenyl)benzene

: 2-[4-((S)-sec-Butyl)-2,5-dimethoxy-phenyl]-1-methyl-ethylamine

Guidance literature:: Multi-step reaction with 6 steps

1: 1.) (+)-monoisopinocampheylborane, 2.) 6 N NaOH, 30percent H₂O₂ / 1.) Et₂O, -35 deg C, 60 h, 2.) Et₂O, from 0 deg C, to 50 deg C, 1 h

2: 69 percent / pyridine / CHCl₃ / 3 h

3: 60 percent / LiAlH₄ / diethyl ether; tetrahydrofuran / 5 h / Heating

4: 87 percent / SnCl₄ / CH₂Cl₂ / 0.17 h

5: 92 percent / NH₄OAc / 4 h / Heating

6: LiAlH₄ / diethyl ether; tetrahydrofuran / 2.5 h / Heating

With pyridine; sodium hydroxide; lithium aluminium tetrahydride; (+)-monoisopinocampheylborane; ammonium acetate; dihydrogen peroxide; tin(IV) chloride; In tetrahydrofuran; diethyl ether; dichloromethane; chloroform;
DOI:10.1021/jm00018a019

Reference yield:

: 89556-66-1
(Z)-1,4-dimethoxy-2-(1-methyl-1-propenyl)benzene

: 166446-87-3
(S)-(+)-2,5-dimethoxy-4-(1-methylpropyl)benzaldehyde

Guidance literature:: Multi-step reaction with 4 steps

1: 1.) (+)-monoisopinocampheylborane, 2.) 6 N NaOH, 30percent H₂O₂ / 1.) Et₂O, -35 deg C, 60 h, 2.) Et₂O, from 0 deg C, to 50 deg C, 1 h

2: 69 percent / pyridine / CHCl₃ / 3 h

3: 60 percent / LiAlH₄ / diethyl ether; tetrahydrofuran / 5 h / Heating

4: 87 percent / SnCl₄ / CH₂Cl₂ / 0.17 h

With pyridine; sodium hydroxide; lithium aluminium tetrahydride; (+)-monoisopinocampheylborane; dihydrogen peroxide; tin(IV) chloride; In tetrahydrofuran; diethyl ether; dichloromethane; chloroform;
DOI:10.1021/jm00018a019