[1-(Methoxymethoxy)cyclohexyl](trimethyl)stannane

Base Information

Chemical Name:[1-(Methoxymethoxy)cyclohexyl](trimethyl)stannane
CAS No.:89727-02-6
Molecular Formula:C11H24O2Sn
Molecular Weight:307.02
Hs Code.:
DSSTox Substance ID:DTXSID70533234
Wikidata:Q82406404

Synonyms:89727-02-6;[1-(Methoxymethoxy)cyclohexyl](trimethyl)stannane;DTXSID70533234

Suppliers and Price of [1-(Methoxymethoxy)cyclohexyl](trimethyl)stannane

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of [1-(Methoxymethoxy)cyclohexyl](trimethyl)stannane

Chemical Property:

Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:2
Rotatable Bond Count:4
Exact Mass:308.079833
Heavy Atom Count:14
Complexity:169

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Canonical SMILES:COCOC1(CCCCC1)[Sn](C)(C)C

Technology Process of [1-(Methoxymethoxy)cyclohexyl](trimethyl)stannane

There total 1 articles about [1-(Methoxymethoxy)cyclohexyl](trimethyl)stannane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 84.0%

: 109-72-8,29786-93-4
n-butyllithium

: 661-69-8
hexamethyldistannane

: 108-94-1,11119-77-0,9003-41-2,9075-99-4
cyclohexanone

: 107-30-2
chloromethyl methyl ether

: 89727-02-6
O-(methoxymethyl)-1-(trimethylstannyl)cyclohexanol

Guidance literature:: With N,N-dimethyl-aniline; In tetrahydrofuran; Ar; Me3SnLi prepared at 0°C in THF; cooled (-78 °C); substrate added (1 min) in THF; stirred (15 min); quenched (NH4Cl-soln.); pouring in NH4Cl-soln.; extn. (petroleum ether); org. layer dried; filtered; concd.; CH2Cl2 added;; addn. of ClCH2OCH3 and aniline (18 h, room temp.); poured into petroleum ether; washed (0,5N HCl, water, Na2CO3-soln.); drying of org. layer; filtered; concd.; chromd. (silica gel; ethyl acetate/petroleum ether 0.5:99.5);;
DOI:10.1021/ja00211a024

Reference yield: 90.0%

: 109-72-8,29786-93-4
n-butyllithium

: 89727-02-6
O-(methoxymethyl)-1-(trimethylstannyl)cyclohexanol

: 89727-03-7
O-(methoxymethyl)-1-(tri-n-butylstannyl)cyclohexanol

Guidance literature:: In tetrahydrofuran; under argon; tin-compound in THF was cooled to -78 °C; nBuLi was added over 1 min; stirring 15 min; quenching with NH4Cl-soln. (gas evolution);; poured into water; extn. (petroleum ether); org. layer dried (Na2SO4), filtered, concd. (vacuo); chromy. (silica gel; petroleum ether);;
DOI:10.1021/ja00211a024

Reference yield:

: 89727-02-6
O-(methoxymethyl)-1-(trimethylstannyl)cyclohexanol

: 594-27-4
tetramethylstannane

Guidance literature:: With methyllithium; In not given; byproducts: CH3OCH2OC6H10Li; Sn-compd. was reacted with MeLi in THF or DME at -60°C for 10 min; equil. react.; analysed by (1)H and (13)C NMR spectra;
DOI:10.1021/ja00323a065