Tributyl[1-(methoxymethoxy)cyclohexyl]stannane

Base Information

Chemical Name:Tributyl[1-(methoxymethoxy)cyclohexyl]stannane
CAS No.:89727-03-7
Molecular Formula:C20H42O2Sn
Molecular Weight:433.262
Hs Code.:
DSSTox Substance ID:DTXSID30533235

Synonyms:89727-03-7;TRIBUTYL[1-(METHOXYMETHOXY)CYCLOHEXYL]STANNANE;DTXSID30533235

Suppliers and Price of Tributyl[1-(methoxymethoxy)cyclohexyl]stannane

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 1 raw suppliers

Chemical Property of Tributyl[1-(methoxymethoxy)cyclohexyl]stannane

Chemical Property:

Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:2
Rotatable Bond Count:13
Exact Mass:434.220683
Heavy Atom Count:23
Complexity:266

Purity/Quality:: 99% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Canonical SMILES:CCCC[Sn](CCCC)(CCCC)C1(CCCCC1)OCOC

Technology Process of Tributyl[1-(methoxymethoxy)cyclohexyl]stannane

There total 2 articles about Tributyl[1-(methoxymethoxy)cyclohexyl]stannane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

: 109-72-8,29786-93-4
n-butyllithium

: 89727-02-6
O-(methoxymethyl)-1-(trimethylstannyl)cyclohexanol

: 89727-03-7
O-(methoxymethyl)-1-(tri-n-butylstannyl)cyclohexanol

Guidance literature:: In tetrahydrofuran; under argon; tin-compound in THF was cooled to -78 °C; nBuLi was added over 1 min; stirring 15 min; quenching with NH4Cl-soln. (gas evolution);; poured into water; extn. (petroleum ether); org. layer dried (Na2SO4), filtered, concd. (vacuo); chromy. (silica gel; petroleum ether);;
DOI:10.1021/ja00211a024

Reference yield: 60.0%

: 4226-01-1
tri-n-butyltin lithium

: 108-94-1,11119-77-0,9003-41-2,9075-99-4
cyclohexanone

: 107-30-2
chloromethyl methyl ether

: 89727-03-7
O-(methoxymethyl)-1-(tri-n-butylstannyl)cyclohexanol

Guidance literature:: With N,N-dimethyl-aniline; In tetrahydrofuran; Ar; Bu3SnLi THF cooled to -40 °C; substrate added (30 s) in THF; stirred (15 min); poured in NH4Cl-soln. and petroleum ether; org. layer washed (brine), dried (Na2SO4); filtered; concd.; CH2Cl2 added; addn. ClCH2OCH3, aniline (16h, room temp.); poured into petroleum ether; washed (0.5 N HCl, water, Na2CO3-soln.); drying of org. layer (Na2SO4); filtered; concd.; chromd. (silica gel; ethyl acetate/petroleum ether 0.5:99.5);;
DOI:10.1021/ja00211a024

Reference yield: 95.0%

: 109-72-8,29786-93-4
n-butyllithium

: 89727-03-7
O-(methoxymethyl)-1-(tri-n-butylstannyl)cyclohexanol

: 42604-09-1
(methoxymethoxy)cyclohexane

: 1461-25-2
tetra-n-butyltin(IV)

Guidance literature:: With methanol; In tetrahydrofuran; under argon; tin-compound in THF cooled to -78 °C; LiBu was added over 10 s; colorless solution after additional 10 s; after 2 min solution was quenched with MeOH;; poured into NH4Cl-soln. and petroleum ether, shaked 1 min, organic layer separated, washed (brine), dried (Na2SO4), filtered, concentrated (vacuo); chromatography (silica gel; ethyl acetate/petroleum ether 0.5:99.5); (1)H- and (13)C-NMR;;
DOI:10.1021/ja00211a024