Silanol, (1,1-dimethylethyl)dimethyl-, 4-methylbenzenesulfonate

Base Information

Chemical Name:Silanol, (1,1-dimethylethyl)dimethyl-, 4-methylbenzenesulfonate
CAS No.:89902-45-4
Molecular Formula:C13H22O3SSi
Molecular Weight:286.467
Hs Code.:

Synonyms:

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of Silanol, (1,1-dimethylethyl)dimethyl-, 4-methylbenzenesulfonate

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
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MSDS Files:: SDS file from LookChem

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Technology Process of Silanol, (1,1-dimethylethyl)dimethyl-, 4-methylbenzenesulfonate

There total 2 articles about Silanol, (1,1-dimethylethyl)dimethyl-, 4-methylbenzenesulfonate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 70.0%

: 103872-45-3
1-(tert-butyldimethylsilyl)-1H-pyrrole

: 104-15-4
toluene-4-sulfonic acid

: 89902-45-4
tert-butyldimethylsilyl trifluoromethanesulfonate

Guidance literature:: In toluene; for 24h; Heating;
DOI:10.1002/jhet.5570340511

Reference yield:

: 16836-95-6
silver(I) 4-methylbenzenesulfonate

: 18162-48-6
tert-butyldimethylsilyl chloride

: 89902-45-4
tert-butyldimethylsilyl trifluoromethanesulfonate

Guidance literature:: In acetonitrile; Ambient temperature;
DOI:10.1039/P29840000077

Reference yield:

: 89902-45-4
tert-butyldimethylsilyl trifluoromethanesulfonate

: N-(2-((tert-butyldimethylsilyl)oxy)-3-(naphthalen-1-yloxy)propyl)-N-isopropyl-4-(2-methyl-4-phenylbutanoyl)benzamide

Guidance literature:: Multi-step reaction with 5 steps

1: triethylamine / dichloromethane / 12 h / 20 °C

2: N-[(dimethylamino)-3-oxo-1H-1,2,3-triazolo[4,5-b]pyridin-1-yl-methylene]-N-methylmethanaminium hexafluorophosphate; N-ethyl-N,N-diisopropylamine / acetonitrile / 12 h / 20 °C

3: triethylamine / acetone / 2 h / Reflux

4: Dess-Martin periodane / dichloromethane / 2 h / 20 °C

5: tert.-butylhydroperoxide; phenylsilane; [(S,S)-N,N’-bis(3,5-di-tertbutylsalicylidene)-1,2-cyclohexanediaminato(2-)]cobalt(II); Selectfluor / isopropyl alcohol; decane / 12 h / 20 °C / Sealed tube; Inert atmosphere

With tert.-butylhydroperoxide; [(S,S)-N,N’-bis(3,5-di-tertbutylsalicylidene)-1,2-cyclohexanediaminato(2-)]cobalt(II); phenylsilane; Dess-Martin periodane; Selectfluor; triethylamine; N-ethyl-N,N-diisopropylamine; N-[(dimethylamino)-3-oxo-1H-1,2,3-triazolo[4,5-b]pyridin-1-yl-methylene]-N-methylmethanaminium hexafluorophosphate; In decane; dichloromethane; isopropyl alcohol; acetone; acetonitrile; 4: |Dess-Martin Oxidation;
DOI:10.1021/jacs.1c02629