1,1-Dichloro-11,11-dimethyl-4,10-dioxadispiro[2.1.4~5~.2~3~]undecane

Base Information

Chemical Name:1,1-Dichloro-11,11-dimethyl-4,10-dioxadispiro[2.1.4~5~.2~3~]undecane
CAS No.:89995-48-2
Molecular Formula:C₁₁H₁₆Cl₂O₂
Molecular Weight:251.153
Hs Code.:
DSSTox Substance ID:DTXSID70527597

Synonyms:89995-48-2;DTXSID70527597;1,1-Dichloro-11,11-dimethyl-4,10-dioxadispiro[2.1.4~5~.2~3~]undecane

Suppliers and Price of 1,1-Dichloro-11,11-dimethyl-4,10-dioxadispiro[2.1.4~5~.2~3~]undecane

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of 1,1-Dichloro-11,11-dimethyl-4,10-dioxadispiro[2.1.4~5~.2~3~]undecane

Chemical Property:

XLogP3:2.7
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:2
Rotatable Bond Count:0
Exact Mass:250.0527351
Heavy Atom Count:15
Complexity:308

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CC1(C2(CC2(Cl)Cl)OC3(O1)CCCC3)C

Technology Process of 1,1-Dichloro-11,11-dimethyl-4,10-dioxadispiro[2.1.4~5~.2~3~]undecane

There total 4 articles about 1,1-Dichloro-11,11-dimethyl-4,10-dioxadispiro[2.1.4~5~.2~3~]undecane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

: 67-66-3,8013-54-5
chloroform

: 79033-02-6
5',5'-Dimethyl-4'-methylenspirodioxolan>

: 89995-48-2
1,1-Dichloro-11,11-dimethyl-4,10-dioxa-dispiro[2.1.4.2]undecane

Guidance literature:: With sodium hydroxide; N-benzyl-N,N,N-triethylammonium chloride; Ambient temperature;
DOI:10.1007/BF00842826

Reference yield:

: 1120-79-2
1-bromomethyl-2,2-dimethyloxirane

: 89995-48-2
1,1-Dichloro-11,11-dimethyl-4,10-dioxa-dispiro[2.1.4.2]undecane

Guidance literature:: Multi-step reaction with 3 steps

1: 57 percent / BF₃*etherate / Heating

2: 82 percent / natrium diethylene glycolate / 3 h / 60 - 70 °C

3: 80 percent / 50percent aq. NaOH, TEBA / Ambient temperature

With sodium hydroxide; boron trifluoride diethyl etherate; N-benzyl-N,N,N-triethylammonium chloride; diethylene glycol monosodium salt;
DOI:10.1007/BF00842826

Reference yield:

: 79033-18-4
4'-Brommethyl-5',5'-dimethylspirodioxolan>

: 89995-48-2
1,1-Dichloro-11,11-dimethyl-4,10-dioxa-dispiro[2.1.4.2]undecane

Guidance literature:: Multi-step reaction with 2 steps

1: 82 percent / natrium diethylene glycolate / 3 h / 60 - 70 °C

2: 80 percent / 50percent aq. NaOH, TEBA / Ambient temperature

With sodium hydroxide; N-benzyl-N,N,N-triethylammonium chloride; diethylene glycol monosodium salt;
DOI:10.1007/BF00842826