5-deoxy-1-O-phosphono-D-xylulose

Base Information

• Chemical Name: 5-deoxy-1-O-phosphono-D-xylulose
• CAS No.: 16709-34-5
• Molecular Formula: C5H11 O7 P
• Molecular Weight: 214.112
• Mol file: 16709-34-5.mol

Synonyms:D-threo-Pentulose,5-deoxy-, 1-(dihydrogen phosphate) (8CI); 5-Deoxy-D-xylulose 1-phosphate

Chemical Property of 5-deoxy-1-O-phosphono-D-xylulose

Chemical Property:

• Vapor Pressure: 6.21E-12mmHg at 25°C
• Boiling Point: 496.4°Cat760mmHg
• Flash Point: 254°C
• Density: 1.653g/cm³

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 5-deoxy-1-O-phosphono-D-xylulose

There total 5 articles about 5-deoxy-1-O-phosphono-D-xylulose which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

fructose 1,6-diphosphate (34693-15-7) + acetaldehyde (75-07-0,9002-91-9) → 5-deoxy-D-threo-pent-2-ulose 1-phosphate (16709-34-5) + Phosphoric acid mono-((3S,4S)-3,4-dihydroxy-2-oxo-pentyl) ester

Guidance literature:

With fructose 1,6-bisphosphate aldolase from S_. carnosus; triose phosphate isomerase from rabbit muscle [EC 5.3.1.1]; In water; at 20 ℃; pH=6.8; Title compound not separated from byproducts; Enzymatic reaction;

DOI:10.1002/(SICI)1521-3765(19990604)5:6<1882::AID-CHEM1882>3.0.CO;2-C

Reference yield:

dihydroxyacetone (96-26-4,26776-70-5) + acetaldehyde (75-07-0,9002-91-9) → 5-deoxy-D-threo-pent-2-ulose 1-phosphate (16709-34-5) + C5H11O7P (160705-75-9)

Guidance literature:

With acetylphosphoric acid; acetate kinase; fructose 1,6-bisphosphate aldolase from rabbit muscle; recombinant dihydroxyacetone kinase from Citrobacter freundii; magnesium sulfate; ATP; pH=7.5; optical yield given as %ee; enantioselective reaction; HEPES buffer; Enzymatic reaction;

DOI:10.1002/adsc.200900603

Reference yield:

fructose-1,6-bisphosphate (488-69-7,55529-38-9,87932-52-3) → 5-deoxy-D-threo-pent-2-ulose 1-phosphate (16709-34-5)

Guidance literature:

With aldolase-substances from rabbit-muscle; sodium hydrogencarbonate; acetaldehyde; Reagens 4: Kohlendioxid;

upstream raw materials:

fructose-1,6-bisphosphate

acetaldehyde

fructose 1,6-diphosphate

dihydroxyacetone phosphate

Downstream raw materials:

2-phosphoglycolic acid

acetaldehyde

methylammonium carbonate

formic acid

Refernces

• 1、 Zannetti, Maria Teresa,Walter, Christiane,Knorst, Marion,Fessner, Wolf-Dieter. "Fructose 1,6-bisphosphate aldolase from Staphylococcus carnosus: Overexpression, structure prediction, stereoselectivity, and application in the synthesis of bicyclic sugars". . p. 1882 - 1890. Retrieved 2007/10/03.