tert-Butyl{3-[chloro(dimethyl)stannyl]propyl}phenylphosphane

Base Information

Chemical Name:tert-Butyl{3-[chloro(dimethyl)stannyl]propyl}phenylphosphane
CAS No.:90127-40-5
Molecular Formula:C₁₅H₂₆ClPSn
Molecular Weight:391.508
Hs Code.:
DSSTox Substance ID:DTXSID50522601

Synonyms:90127-40-5;DTXSID50522601;tert-Butyl{3-[chloro(dimethyl)stannyl]propyl}phenylphosphane

Suppliers and Price of tert-Butyl{3-[chloro(dimethyl)stannyl]propyl}phenylphosphane

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of tert-Butyl{3-[chloro(dimethyl)stannyl]propyl}phenylphosphane

Chemical Property:

Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:0
Rotatable Bond Count:6
Exact Mass:392.048268
Heavy Atom Count:18
Complexity:241

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CC(C)(C)P(CCC[Sn](C)(C)Cl)C1=CC=CC=C1

Technology Process of tert-Butyl{3-[chloro(dimethyl)stannyl]propyl}phenylphosphane

There total 1 articles about tert-Butyl{3-[chloro(dimethyl)stannyl]propyl}phenylphosphane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 78.0%

: 76637-79-1
3-t-bityl(phenyl)phosphinipropyltrimethylstannane

: 1066-45-1
trimethyltin(IV)chloride

: 90127-40-5
3-t-butyl-phenylphosphinopropyl-dimethylzinnchlorid

Guidance literature:: In neat (no solvent); byproducts: Me4Sn; heating of the react. mixt. at ca 60°C, then 1-2 d at room temp., treatment with hexane, filtration, evapg. of filtrate, adding of Me3SnCl, repeating of procedure; crystn. from benzene/hexane or ppn. with H2O from EtOH soln.; elem. anal.;
DOI:10.1016/S0022-328X(00)99156-3

Reference yield: 53.0%

: 16853-85-3
lithium aluminium tetrahydride

: 90127-40-5
3-t-butyl-phenylphosphinopropyl-dimethylzinnchlorid

: 90127-49-4
3-t-butyl-phenylphosphinopropyl-dimethylzinnhydrid

Guidance literature:: In diethyl ether; soln. of tin compd. was added dropwise to suspn. of LiAlH4 in ether, stirring at room temp., addind of water, filtration; distn. in vac.; elem. anal.;
DOI:10.1016/S0022-328X(00)99156-3